Environmental exposure effects on composite materials for commercial aircraft

A study was conducted to determine the effects of long term flight and ground exposure on three commercially available graphite-epoxy material systems: T300/5208, T300/5209, and T300/934. Sets of specimens were exposed on commercial aircraft and ground racks for 1, 2, 3, 5, and 10 years. Inflight specimen sites included both the interior and exterior of aircraft based in Hawaii, Texas, and New Zealand. Ground racks were located at NASA-Dryden and the above mentioned states. Similar specimens were exposed to controlled lab conditions for up to 2 years. After each exposure, specimens were tested for residual strength and a dryout procedure was used to measure moisture content. Both room and high temperature residual strengths were measured and expressed as a pct. of the unexposed strength. Lab exposures included the effects of time alone, moisture, time on moist specimens, weatherometer, and simulated ground-air-ground cycling. Residual strengths of the long term specimens were compared with residual strengths of the lab specimens. Strength retention depended on the exposure condition and the material system. Results showed that composite materials can be successfully used on commercial aircraft if environmental effects are considered

Quantum Dynamics of Skyrmions in Chiral Magnets

We study the quantum propagation of a Skyrmion in chiral magnetic insulators by generalizing the micromagnetic equations of motion to a finite-temperature path integral formalism, using field theoretic tools. Promoting the center of the Skyrmion to a dynamic quantity, the fluctuations around the Skyrmionic configuration give rise to a time-dependent damping of the Skyrmion motion. From the frequency dependence of the damping kernel, we are able to identify the Skyrmion mass, thus providing a microscopic description of the kinematic properties of Skyrmions. When defects are present or a magnetic trap is applied, the Skyrmion mass acquires a finite value proportional to the effective spin, even at vanishingly small temperature. We demonstrate that a Skyrmion in a confined geometry provided by a magnetic trap behaves as a massive particle owing to its quasi-one-dimensional confinement. An additional quantum mass term is predicted, independent of the effective spin, with an explicit temperature dependence which remains finite even at zero temperature.Comment: 14 pages, 10 figure

Topological Phase Detection in Rashba Nanowires with a Quantum Dot

We study theoretically the detection of the topological phase transition occurring in Rashba nanowires with proximity-induced superconductivity using a quantum dot. The bulk states lowest in energy of such a nanowire have a spin polarization parallel or antiparallel to the applied magnetic field in the topological or trivial phase, respectively. We show that this property can be probed by the quantum dot created at the end of the nanowire by external gates. By tuning one of the two spin-split levels of the quantum dot to be in resonance with nanowire bulk states, one can detect the spin polarization of the lowest band via transport measurement. This allows one to determine the topological phase of the Rashba nanowire independently of the presence of Majorana bound states

Superconducting Gap Renormalization around two Magnetic Impurities: From Shiba to Andreev Bound States

We study the renormalization of the gap of an s-wave superconductor in the presence of two magnetic impurities. For weakly bound Shiba states, we analytically calculate the part of the gap renormalization that is sensitive to the relative orientation of the two impurity spins. For impurities with a strong exchange coupling to the conduction electrons, we solve the gap equation self-consistently by numerics and find that the sub-gap Shiba state turns into a supra-gap Andreev state when the local gap parameter changes sign under the impurities.Comment: 6 pages, 4 figures - final versio

Pyrolysis of Wastewater Biosolids Significantly Reduces Estrogenicity

Most wastewater treatment processes are not specifically designed to remove micropollutants. Many micropollutants are hydrophobic so they remain in the biosolids and are discharged to the environment through land-application of biosolids. Micropollutants encompass a broad range of organic chemicals, including estrogenic compounds (natural and synthetic) that reside in the environment, a.k.a. environmental estrogens. Public concern over land application of biosolids stemming from the occurrence of micropollutants hampers the value of biosolids which are important to wastewater treatment plants as a valuable by-product. This research evaluated pyrolysis, the partial decomposition of organic material in an oxygen-deprived system under high temperatures, as a biosolids treatment process that could remove estrogenic compounds from solids while producing a less hormonally active biochar for soil amendment. The estrogenicity, measured in estradiol equivalents (EEQ) by the yeast estrogen screen (YES) assay, of pyrolyzed biosolids was compared to primary and anaerobically digested biosolids. The estrogenic responses from primary solids and anaerobically digested solids were not statistically significantly different, but pyrolysis of anaerobically digested solids resulted in a significant reduction in EEQ; increasing pyrolysis temperature from 100 °C to 500 °C increased the removal of EEQ with greater than 95% removal occurring at or above 400 °C. This research demonstrates that biosolids treatment with pyrolysis would substantially decrease (removal \u3e 95%) the estrogens associated with this biosolids product. Thus, pyrolysis of biosolids can be used to produce a valuable soil amendment product, biochar, that minimizes discharge of estrogens to the environment