EuO and Eu on metal crystals and graphene: interface effects and epitaxial films

Growth of the ferromagnetic semiconductor EuO was studied on the metal crystals Ni(100) and Ir(111) and on graphene. Primarily, characterisation was done by means of in-situ scanning tunnelling microscopy (STM) and low energy electron diffraction. The epitaxy on the metal crystals is strongly influenced by interface effects which lead to a complicated growth behaviour in the sub-monolayer regime, especially on Ni(100). Therefore, also films of sub-monolayer thickness were analysed in detail for these substrates. Eu oxide on Ni(100) shows a variety of different surface phases in the sub-monolayer regime, depending on the growth temperature and the ratio of the Eu and O fluxes. Hence, a careful selection of the initial growth parameters is decisive to obtain a surface oxide suitable for subsequent epitaxy of single phase EuO(100). After creation of a 3 layer thick coalesced oxide film, for subsequent growth a distillation technique can be applied. Ex-situ X-ray adsorption spectroscopy and magneto-optical Kerr effect microscopy measurements of thicker films on Ni(100) are consistent with stoichiometric single phase EuO with bulk properties. On Ir(111) initially only islands of polar EuO(111) grow, but formation of EuO(100) sets in before the first oxide layer is completed. The ratio of EuO(100) to EuO(111) is thereby influenced by the ratio of the Eu and O fluxes. Thus, the EuO films on Ir(111) consist of a phase mixture of EuO(111) and three rotational domains of EuO(100). The thinnest structure of the EuO(111) is a bilayer. Field emission resonances revealed a work function increase of 6 eV for this structure compared to EuO(100). Despite the polarity, the bilayer shows no obvious reconstruction which could reduce the high electric field. Triangular reconstruction motifs were found for the third EuO(111) layer. On graphene EuO can be grown as thin film of distinct, {100}-faceted grains which are oriented to the substrate at a sufficiently high growth temperature. As the EuO on graphene is not affected by interface effects, the initial growth stage is not crucial. Thus, the growth of these grains is far less sensitive to the ratio of Eu and O fluxes than the EuO growth on Ni(100). Appropriate annealing of EuO(100) films generates sufficient conductivity for STM and electron spectroscopies, even for films of 100 nm thickness. Oxygen vacancies were directly imaged by STM. They are of decisive importance for the metal-to-insulator transition of EuO around the temperature of the ferromagnetic-to-paramagnetic transition. Tunnelling spectra of EuO were recorded for the first time. For EuO(100) with 1% O vacancies in the topmost layer they exhibit states about 500 meV above the Fermi level which are most probably related to O vacancies. On all substrates, monolayer high EuO(100) films have a contracted lattice which expands with increasing film thickness. Even if the substrate applies compressive biaxial stress, the EuO bulk lattice constant is almost reached for 5 nm film thickness. This leaves little hope for an increase of the Curie temperature through epitaxial compression. During the investigation of the EuO on graphene, intercalation of Eu between the graphene and its Ir(111) substrate was observed and analysed further. For Eu deposition at 720 K a variety of equilibrium intercalate structures occur, dependent on the deposited Eu amount, all of which have a height of one monolayer. The dimensions and orientations of these structures are determined by binding energy differences within the unit cell of the graphene moiré on Ir(111). The energetically preferred lattice of the intercalated Eu is a p(2x2) structure, but intercalation continues until a denser (1.73x1.73)R30° structure is saturated. Angular resolved photoemission spectroscopy finds a shift of the graphene's Dirac cone by -1.5 eV for both of these structures. For closed graphene films, intercalation is hindered by a penetration barrier for temperatures below 400 K. The adsorption and equilibrium surface phases of Eu on graphene were investigated in the temperature range from 35 K to 400 K and for coverages ranging from a small fraction of a saturated monolayer to the second layer. Using density functional theory, including the 4f-shell Coulomb interactions and modelling of the electronic interactions, excellent agreement with the experimental results for the equilibrium adsorbate phase, adsorbate diffusion, and work function was obtained. Most remarkable, at 300 K in an intermediate coverage range a phase of uniformly distributed Eu clusters coexists in two dimensional equilibrium with large Eu-islands in a (1.73x1.73)R30° structure. The formation of the cluster phase is driven by the interplay of three effects: First, the metallic Eu-Eu binding leads to the local stability of (1.73x1.73)R30° structures. Second, electrons lower their kinetic energy by leaving the Eu clusters, thereby doping graphene. Third, the Coulomb energy penalty associated with the charge transfer from Eu to graphene is strongly reduced for smaller clusters

The Mirror Alignment and Control System for CT5 of the H.E.S.S. experiment

The High Energy Stereoscopic System (H.E.S.S.) experiment is one of the largest observatories for gamma-ray astronomy. It consists of four telescopes with a reflecting dish diameter of 12m (CT1 to CT4) and a newer large telescope (CT5) with a reflecting dish diameter of 28m. On CT5 876 mirror facets are mounted, all of them equipped with a computerised system for their alignment. The design of the mirror alignment and control system and the performance of the hardware installed to the telescope are presented. Furthermore the achieved point spread function of the telescope over the full operational elevation range as well as the stability of the alignment over an extended period of time are shown

MoleNet: An Underground Sensor Network for Soil Monitoring

With the increasing digitalization worldwide, the demand of information also increases in all areas. MoleNet is a low-power sensing platform which is easy to assemble and use. It offers several options to monitor, for example, the soil moisture and temperature and visualize the data. Several researchers from different countriesare currently working and improving MoleNet for different applications. This demoshows the main application of MoleNet: Monitoring soil conditions in a remote area,transmitting the data and visualizing the current status

Systemauslegung autarker Hybridantriebe unter Berücksichtigung kundenspezifischer Randbedingungen

Zur Erfüllung gesetzlicher Anforderungen müssen Fahrzeughersteller konventionelle Antriebe hinsichtlich ihrer Effizienz weiterentwickeln und die CO2-Emissionen ihrer Fahrzeugflotten sukzessive reduzieren. Eine wesentliche Maßnahme ist die Elektrifizierung von Antrieben durch Hybridsysteme. Diese ermöglichen unter anderem durch Bremskraftrückgewinnung und Betriebspunktoptimierung eine signifikante Verbrauchsreduktion konventioneller Antriebe. Eine Herausforderung besteht darin, Hybridsysteme zielgenau für ihren Einsatzzweck auszulegen und damit den Zielkonflikt aus Nutzen und Aufwand optimal zu lösen. Autark-Hybridsysteme ohne externe Lademöglichkeit können durch ein hohes Nutzen/Aufwand-Verhältnis überzeugen. In dieser Arbeit wird eine Methode vorgestellt, um Autark-Hybridsysteme optimal auszulegen. Dabei werden verschiedene Hybrid-Topologien untersucht, die wesentlichen Komponenten des Hybridsystems dimensioniert und die Nutzung der verfügbaren Ressourcen durch eine Fahrstrategie optimiert. Ein wesentlicher Fokus der Arbeit liegt auf einer umfassenden Betrachtung der Randbedingungen des Hybridsystems im Kundenbetrieb. Diese werden durch charakteristische Fahrzyklen für Fahrumgebungen und Fahrstile sowie durch segmentspezifische Fahrzeugparameter modelliert. Weiterhin werden statistische Häufigkeitsverteilungen dieser Randbedingungen identifiziert. Nach einer Analyse der Einflüsse von Auslegungsparametern und Randbedingungen werden die entwickelten Modelle in einen ganzheitlichen Optimierungsansatz für das Hybridsystem integriert und dessen Ergebnisse diskutiert

Unprecedented Retention Capabilities of Extensive Green Roofs—New Design Approaches and an Open-Source Model

Green roofs are a proven measure to increase evapotranspiration at the expense of runoff, thus complementing contemporary stormwater management efforts to minimize pluvial flooding in cities. This effect has been quantified by numerous studies, ranging from experimental field campaigns to modeling experiments and even combinations of both. However, up until now, most green roof studies consider standard types of green roof dimensions, thus neglecting varying flow length in the substrate. For the first time, we present a comprehensive investigation of green roofs that involves artificial rainfall experiments under laboratory conditions (42 experiments in total). We consider varying flow length and slope. The novelty lies especially in the consideration of flow lengths beyond 5 m and non-declined roofs. This experimental part is complemented by numerical modeling, employing the open-source Catchment Modeling Framework (CMF). This is set-up for Darcy and Richards flow in the green roof and calibrated utilizing a multi-objective approach, considering both runoff and hydraulic head. The results demonstrate that through maximizing flow length and minimizing slope, the runoff coefficient (i.e., percentage of rainfall that becomes runoff) for a 100 years design rainfall is significantly decreased: from ~30% to values below 10%. These findings are confirmed through numerical modeling, which proves its value in terms of achieved model skill (Kling-Gupta Efficiency ranging from 0.5 to 0.95 with a median of 0.78). Both the experimental data and the numerical model are published as open data and open-source software, respectively. Thus, this study provides new insights into green roof design with high practical relevance, whilst being reproducible

Review on Experimental and Theoretical Investigations of Ultra-Short Pulsed Laser Ablation of Metals with Burst Pulses

Laser processing with ultra-short double pulses has gained attraction since the beginning of the 2000s. In the last decade, pulse bursts consisting of multiple pulses with a delay of several 10 ns and less found their way into the area of micromachining of metals, opening up completely new process regimes and allowing an increase in the structuring rates and surface quality of machined samples. Several physical effects such as shielding or re-deposition of material have led to a new understanding of the related machining strategies and processing regimes. Results of both experimental and numerical investigations are placed into context for different time scales during laser processing. This review is dedicated to the fundamental physical phenomena taking place during burst processing and their respective effects on machining results of metals in the ultra-short pulse regime for delays ranging from several 100 fs to several microseconds. Furthermore, technical applications based on these effects are reviewed

Robust vegetation parameterization for green roofs in the epa stormwater management model (SWMM)

In increasingly expanding cities, roofs are still largely unused areas to counteract the neg-ative impacts of urbanization on the water balance and to reduce flooding. To estimate the effect of green roofs as a sustainable low impact development (LID) technique on the building scale, different approaches to predict the runoff are carried out. In hydrological modelling, representing vegetation feedback on evapotranspiration (ET) is still considered challenging. In this research article, the focus is on improving the representation of the coupled soil–vegetation system of green roofs. Relevant data to calibrate and validate model representations were obtained from an existing field campaign comprising several green roof test plots with different characteristics. A coupled model, utilizing both the Penman–Monteith equation to estimate ET and the software EPA stormwater management model (SWMM) to calculate the runoff, was set up. Through the application of an automatic calibration procedure, we demonstrate that this coupled modelling approach (Kling–Gupta efficiency KGE = 0.88) outperforms the standard ET representation in EPA SWMM (KGE = −0.35), whilst providing a consistent and robust parameter set across all green roof configurations. Moreover, through a global sensitivity analysis, the impact of changes in model parameters was quantified in order to aid modelers in simplifying their parameterization of EPA SWMM. Finally, an improved model using the Penman–Monteith equation and various recommendations are presented

Five Fractions versus Seven Fractions SBRT for Intermediate- and High-Risk Prostate Cancer: A Propensity Score Matched Pair Analysis.

PURPOSE To compare two stereotactic body radiotherapy (SBRT) regimens in patients with intermediate- or high-risk prostate cancer with regards toxicity and efficacy. METHODS/MATERIAL We retrospectively collected data from 198 patients treated with SBRT for prostate cancer at two different institutions. Patients received either 35-36.25 Gy in five fractions (group A) using Cyberknife robotic platform or 42.7 Gy in seven fractions (group B) using a C-arm LINAC (image-guided). Propensity score matching was done (2:1 nearest neighbor matching without replacement), resulting in 120 patients (80 patients for group A, 40 patients for group B). Toxicity, PSA nadir, biochemical failure and disease-free survival (DFS) were analyzed. RESULTS Median follow up of all patients was 13 months (range 1-91 months). Overall, 23.3% of patients had ≥G2 acute GU toxicity (21.1% group A versus 30% group B (p = 0.222)) and 6.6% of patients ≥G2 GI toxicity (2.5% versus 15% (p = 0.010)). There was one acute G3 GU toxicity in arm A and one acute G4 rectal bleeding in group B (anticoagulated patient). Regarding late toxicity, 14.1% of patients had ≥G2 late GU toxicity (17.4% versus 6.6% (p = 0.159)) and 5.0% of patients had ≥G2 late GI toxicity (1.4% versus 13.3% (p = 0.013)). There was one G3 late GU toxicity in arm B and two G3 late GI toxicities, one in each arm. Relative median PSA reduction was 92.4% (-53.9-99.9%) from baseline PSA (93.7% (-53.9-99.9%) in group A versus 87.7% (39.8-99.9%) in group B (p = 0.043). In total, 4.2% of patients had biochemical relapse, 5.0% in group A and 2.5% in group B (p = 0.518). One-year DFS in the overall cohort was 97.3%, 98.8% in group A and 94.3% in group B (p = 0.318). CONCLUSION Both SBRT regimens have acceptable acute and late toxicity and good efficacy. There are significantly more GI toxicities in the seven-fraction regimen. Longer follow-up is warranted for better comparison of long-term efficacy