Effect of Land Application of Poultry Waste on Pesticide Loss

The poultry industry in Arkansas is a large, concentrated, growing industry that produces a high volume of fecal waste. Most of this waste is surface applied as pasture fertilizer. Pesticides are commonly used in the poultry industry for fly and litter beetle contro land are often a component of the surface-applied poultry waste. No information exists in the scientific literature regarding the transport of this pesticide component to nearby water supplies.Our research focused on cyromazine, a feed-through larvicide used to control flies in caged-layer hen houses. Tetrachlorvinphos and carbaryl are also used in poultry waste, but these pesticides have a relatively low solubility in water and rapid decomposition rate. Cyromazine, however, is highly soluble and stable in water. Since it may be readily washed from the pasture by heavy rainfall and may persist in surface and soil water, cyromazine appears to be potentially a much greater long-term threat to water quality than either carbaryl or tetrachlorvinphos. Therefore, the objective of this investigation was to examine the extent of cyromazine loss as a result of land application of caged layer manure. To quantify cyromazine loss from pasture plots treated with caged layer manure,research was conducted at the University of Arkansas Agricultural Experiment Station at Fayetteville. Plots of uniform slope were bordered to isolate surface runoff, fitted with runoff collectors, and established in fescue pasture. Suction lysimeters were placed at the 60 cm depth to sample soil water in the unsaturated zone. Caged layer manure was analyzed for cyromazine concentration and applied to the plots at three different rates. Rainfall was applied by simulator at two intensities. Surface runoff and lysimeter samples were measured and analyzed for cyromazine concentration. A solid phase extraction procedure was used to separate the cyromazine from the water samples and analysis was done by high performance liquid chromatography (HPLC). Results showed that a heavier manure application increased both the runoff and cyromazine concentration. Higher rainfall intensity also increased total cyromazine loss in the runoff, but provided enough runoff volume to decrease the cyromazine concentration. Soil water from the unsaturated zone was monitored for a year following the manure application, but neither cyromazine nor its metabolite, melamine, were detected

An Atypical Presentation of Cystic Echinococcosis

Cystic echinococcosis (CE) is an infection caused by the Echinococcus granulosus tapeworm. CE generally manifests in the liver, but it may present in any organ. These patients often first present to the emergency department. Mortality over 10 years is significant for those who go undiagnosed. We report the case of a 34-year-old patient who immigrated from Yemen six years earlier. She presented with acute onset dysuria, suprapubic pain, and fever. Imaging revealed a primary multicystic mass on the right renal pole with a secondary lesion in the right hepatic lobe. On further investigation, the patient’s serum was positive for echinococcus antibodies

Exclusion zone phenomena in water -- a critical review of experimental findings and theories

The existence of the exclusion zone (EZ), a layer of water in which plastic microspheres are repelled from hydrophilic surfaces, has now been independently demonstrated by several groups. A better understanding of the mechanisms which generate EZs would help with understanding the possible importance of EZs in biology and in engineering applications such as filtration and microfluidics. Here we review the experimental evidence for EZ phenomena in water and the major theories that have been proposed. We review experimental results from birefringence, neutron radiography, nuclear magnetic resonance, and other studies. Pollack and others have theorized that water in the EZ exists has a different structure than bulk water, and that this accounts for the EZ. We present several alternative explanations for EZs and argue that Schurr's theory based on diffusiophoresis presents a compelling alternative explanation for the core EZ phenomenon. Among other things, Schurr's theory makes predictions about the growth of the EZ with time which have been confirmed by Florea et al. and others. We also touch on several possible confounding factors that make experimentation on EZs difficult, such as charged surface groups, dissolved solutes, and adsorbed nanobubbles.Comment: 14 pg

Assessment of Effectiveness of Buffer Zones in Removing Impurities in Runoff from Areas Treated with Poultry Litter. Part II: Source Areas to Buffer Areas Ratio Effects

Vegetative filter strips (VFS) are known to reduce runoff losses of nutrients. solids. and other materials from land areas treated with fertilizers . Although VFS effectiveness is known to depend partially on the relative lengths of filter and pollutant source areas. there is little experimental evidence available to quantify this dependence. This is particularly the case when VFS are implemented down-slope of pasture areas treated with animal manures such as poultry litter. This study assessed the influences of pollutant source area (treated with poultry litter) and VFS lengths on VFS removal of total Kjeldahl nitrogen (TKN). ammonia nitrogen (NH3 -N ). nitrate nitrogen (N03-N). ortho-phosphorus (P04-P). total phosphorus (TP). total organic carbon (TOC). total suspended solids (TSS). and fecal coliform (FC) fromincoming runoff for a silt loam soil with fescue cover. Litter-treated lengths of 6.1. 12.2. and 18.3 m with corresponding VFS lengths of up to 18.3 m. 12.2 m. and 6.1 m. respectively, were examined. Runoff was produced from simulated rainfall applied at 50 mm/h for 1 h of runoff. Concentrations of the parameters analyzed were unaffected by litter treated length but demonstrated a first-order decrease with increasing VFS length except in the cases of TSS and FC. Mass transport of TKN. NH3-N. P04-P. and TP increased with increasing litter-treated length (due to increased runoff) and decreased (approximately first-order) with increasing VFS length. Effectiveness of the VFS in terms of TKN. NH3-N. P04 -P. and TP removal from runoff ranged from 6.5 to 96.3% depending on the particular parameter. litter-treated length. and VFS length. The data collected during this study can be helpful in developing and testing simulation models of VFS performance and can thus aid in design of VFS for pasture areas treated with poultry litter

A physical-space version of the stretched-vortex subgrid-stress model for large-eddy simulation

A physical-space version of the stretched-vortex subgrid-stress model is presented and applied to large-eddy simulations of incompressible flows. This version estimates the subgrid-kinetic energy required for evaluation of the subgrid-stress tensor using local second-order structure-function information of the resolved velocity field at separations of order the local cell size. A relation between the structure function and the energy spectrum is derived using the kinematic assumptions of the stretched-vortex model for locally homogeneous anisotropic turbulence. Results of large-eddy simulations using this model are compared to experimental and direct numerical simulation data. Comparisons are shown for the decay of kinetic energy and energy spectra of decaying isotropic turbulence and for mean velocities, root-mean-square velocity fluctuations and turbulence-kinetic energy balances of channel flow at three different Reynolds numbers

IMPLICATION OF IMPROVED IRRIGATION PUMPING EFFICIENCY FOR FARMER PROFIT AND ENERGY USE

Resource /Energy Economics and Policy,

TEMPORAL IMPLICATIONS OF LIMITATIONS ON ANNUAL IRRIGATION WATER PUMPED FROM AN EXHAUSTIBLE AQUIFER

Economic losses caused by uncontrolled pumping of groundwater is of major concern on the Texas High Plains. A recursive linear programming model is used to evaluate various annual limitations on aquifer depletion. Results indicate that, especially under furrow irrigation, some limitations on groundwater withdrawal could be beneficial to society as well as the producers.Resource /Energy Economics and Policy,

Carbon-13 nuclear magnetic resonance spectra and mechanism of bridge–terminal carbonyl exchange in di-µ-carbonyl-bis[carbonyl(η-cyclopentadienyl)iron](Fe–Fe)[{(η-C5H5)Fe(CO)2}2]; cd-di-µ-carbonyl-f-carbonyl-ae-di(η-cyclopentadienyl)-b-(triethyl -phosphite)di-iron(Fe–Fe)[(η-C5H5)2Fe2(CO)3P(OEt)3], and some related complexes

A mechanism involving carbonyl-bridge breaking, rotation about the Fe–Fe bond, and bridge reformation is shown to account qualitatively for changes in the carbonyl region of the 13C n.m.r spectrum of the complex [(cp)(OC)[graphic omitted]e(cp){P(OEt)3}] and quantitatively for [(cp)(OC)[graphic omitted]e(CO)(cp)](cp =η-cyclopentadienyl).The activation energy for this process, 49.0 ± 4 kJ mol^–1(11.7 ± 1 kcal mol^–1), is close to that reported for cis–trans-isomerization of the cp groups, in accord with this mechanism. Variable-temperature 13C n.m.r. spectra of the complexes [(cp)(OC)[graphic omitted]u(CO)(cp)] and [(cp)(OC)[graphic omitted]i(cp)] are also reported

Noncontact temperature pattern measuring device

Laser pyrometer techniques are utilized to accurately image a true temperature distribution on a given target without touching the target and without knowing the localized emissivity of the target. The pyrometer utilizes a very high definition laser beam and photodetector, both having a very narrow focus. The pyrometer is mounted in a mechanism designed to permit the pyrometer to be aimed and focused at precise localized points on the target surface. The pyrometer is swept over the surface area to be imaged, temperature measurements being taken at each point of focus