Investigating the effect of different adhesion materials on electrical resistance using a high pressure torsion rig

This paper presents an assessment of newly-developed conductive adhesion materials (Products A-D) in comparison to standard rail sand used in Britain. The particles were characterised to assess their densities, and size and shape distributions. Bulk behaviour was assessed through three characteristics: angle of repose, bulk shear strength, and particle breakage index. Materials were then assessed using a high pressure torsion approach to measure their effects on adhesion and electrical resistance in dry, wet, and leaf contaminated conditions. It was resolved that all products produced better conductivity than GB rail sand and Product D should be considered for future field testing

Iridium-Catalyzed Silylation

In this chapter, homogeneous iridium-catalyzed silylation reactions are reviewed, focusing primarily on their synthetic utility. Additionally, relevant catalytic cycles are commented, paying especial attention to those that are more representative of each type of process. The chapter is divided into two main types of reactions, namely, hydrosilylation and C–H bond silylation. The former deals with the hydrosilylation of polar unsaturated bonds (ketones and imines) and non-polar unsaturated bonds (alkenes and alkynes). The latter covers the directed and non-directed C–H bond silylation of alkenes, alkynes, arenes, and alkanes – mainly comprising dehydrogenative silylation reactions, which may occur in the presence or absence of a hydrogen acceptor.This work was supported by the “Ramón y Cajal” program (RYC2016-20864) (FSE/Agencia Estatal de Investigación) (M. I.) and the Spanish Ministry of Science, Innovation and Universities (RTI2018-099136-A-I00).Peer reviewe