Argon assisted chemical vapor deposition of CrO2_2: an efficient process leading to high quality epitaxial films

A comparative study of the structural, microstructural and magnetic properties of CrO$_2$ thin films grown onto (110) and (100) TiO$_2$ rutile single crystal substrates by chemical vapor deposition (CVD), using CrO$_3$ as chromium precursor and either oxygen or argon as carrier gas is presented. Our results show that growth under argon carrier gas leads to high quality CrO$_2$ epilayers with structural and magnetic properties similar to those obtained using the more standard oxygen carrier gas. Furthermore, we interpret the larger magnetic coercivity observed for the (110) oriented films in terms of their microstructure, in particular of the highest strain and edge roughness of the building structures of the CrO$_2$ epilayers, which are settled by the substrate crystallographic orientation.Comment: 27 pages, 2 tables, 8 figure

A unification in the theory of linearization of second order nonlinear ordinary differential equations

In this letter, we introduce a new generalized linearizing transformation (GLT) for second order nonlinear ordinary differential equations (SNODEs). The well known invertible point (IPT) and non-point transformations (NPT) can be derived as sub-cases of the GLT. A wider class of nonlinear ODEs that cannot be linearized through NPT and IPT can be linearized by this GLT. We also illustrate how to construct GLTs and to identify the form of the linearizable equations and propose a procedure to derive the general solution from this GLT for the SNODEs. We demonstrate the theory with two examples which are of contemporary interest.Comment: 8 page

Evaluation of the potential production of 2nd generation ethanol from waste pruning of the olive grove

Avaliação do potencial de produção de etanol de 2.ª geração a partir dos resíduos das podas do olival

Massive 70 micron quiet clumps I: evidence of embedded low/intermediate-mass star formation activity

Massive clumps, prior to the formation of any visible protostars, are the best candidates to search for the elusive massive starless cores. In this work we investigate the dust and gas properties of massive clumps selected to be 70 micron quiet, therefore good starless candidates. Our sample of 18 clumps has masses 300 < M < 3000 M_sun, radius 0.54 < R < 1.00 pc, surface densities Sigma > 0.05 g cm^-2 and luminosity/mass ratio L/M < 0.3. We show that half of these 70 micron quiet clumps embed faint 24 micron sources. Comparison with GLIMPSE counterparts shows that 5 clumps embed young stars of intermediate stellar mass up to ~5.5 M_sun. We study the clump dynamics with observations of N2H+ (1-0), HNC (1-0) and HCO+ (1-0) made with the IRAM 30m telescope. Seven clumps have blue-shifted spectra compatible with infall signatures, for which we estimate a mass accretion rate 0.04 < M_dot < 2.0 x 10^-3 M_sun yr^-1, comparable with values found in high-mass protostellar regions, and free-fall time of the order of t_ff = 3 x 10^5 yr. The only appreciable difference we find between objects with and without embedded 24 micron sources is that the infall rate appears to increase from 24 micron dark to 24 micron bright objects. We conclude that all 70 micron quiet objects have similar properties on clump scales, independently of the presence of an embedded protostar. Based on our data we speculate that the majority, if not all of these clumps may already embed faint, low-mass protostellar cores. If these clumps are to form massive stars, this must occur after the formation of these lower mass stars.Comment: 44 pages, 11 Figures. Accepted for publication in MNRA

Alkaline pretreatments of agricultural residues for ethanol production

Residues of olive trees pruning need to be removed every year so as not to compromise the health of the fruit (olives). However, at present, despite disposal costs, there is no monetization this waste. Therefore, the use of this waste for the production of cellulosic ethanol could be quite promising. In the present work, the optimization of dilute acid pretreatment conditions of olive tree pruning was studied. A fundamental step in the production of ethanol from lignocellulosic materials is the improvement of the carbohydrates accessibility to enzymatic hydrolysis, which can be performed with physic-chemical pretreatments.Fundação para a Ciência e a Tecnologia (Reference: SFRH/ BD/ 49683/ 2009