64 research outputs found
Thermodynamic analysis of inverted bifurcation
We present a thermodynamic analysis of inverted bifurcation
in binary mixtures heated from below. From this analysis it
follows that an inverted bifurcation is caused by the competition
between a stabilizing effect with a long relaxation time and a
destabilizing effect with a short relaxation time. These
conditions are precisely the same as those that give rise to
overstability. This might explain why overstability and inverted
bifurcation occur in the same systems
Twinning superlattices in indium phosphide nanowires
Here, we show that we control the crystal structure of indium phosphide (InP)
nanowires by impurity dopants. We have found that zinc decreases the activation
barrier for 2D nucleation growth of zinc-blende InP and therefore promotes the
InP nanowires to crystallise in the zinc blende, instead of the commonly found
wurtzite crystal structure. More importantly, we demonstrate that we can, by
controlling the crystal structure, induce twinning superlattices with
long-range order in InP nanowires. We can tune the spacing of the superlattices
by the wire diameter and the zinc concentration and present a model based on
the cross-sectional shape of the zinc-blende InP nanowires to quantitatively
explain the formation of the periodic twinning.Comment: 18 pages, 4 figure
- …