Singlet exciton fission in solution.

Singlet exciton fission, the spin-conserving process that produces two triplet excited states from one photoexcited singlet state, is a means to circumvent the Shockley-Queisser limit in single-junction solar cells. Although the process through which singlet fission occurs is not well characterized, some local order is thought to be necessary for intermolecular coupling. Here, we report a triplet yield of 200% and triplet formation rates approaching the diffusion limit in solutions of bis(triisopropylsilylethynyl (TIPS)) pentacene. We observe a transient bound excimer intermediate, formed by the collision of one photoexcited and one ground-state TIPS-pentacene molecule. The intermediate breaks up when the two triplets separate to each TIPS-pentacene molecule. This efficient system is a model for future singlet-fission materials and for disordered device components that produce cascades of excited states from sunlight.B.J.W. was supported by a Herchel Smith Research Fellowship. A.J.M. received funding from a Marie Curie Scholarship. D.B. is a FNRS Research Director. Both A.J.M and D.B. acknowledge support from the European Community’s Initial Training Network SUPERIOR (PITN-GA-2009-238177). Further funding for this project came from the Engineering and Physical Sciences Research Council (EPSRC) and a pump-prime grant from the Winton Programme for the Physics of Sustainability.This is the accepted version of an article originally published in Nature Chemistry 5, 1019–1024 and available online at http://www.nature.com/nchem/journal/v5/n12/full/nchem.1801.html. Nature Publishing Group's conditions for reuse are detailed at http://www.nature.com/authors/policies/license.html

Person-Related Protective and Vulnerability Factors of Psychopathology Symptoms in Non-Clinical Adolescents

Psychopathology in youths is thought to originate from a dynamic interplay of a variety of protective and vulnerability factors. In this study, a large multi-ethnic sample of non-clinical adolescents (N = 376) completed questionnaires for measuring a wide range of person-related protective and vulnerability factors as well as psychopathology symptoms, in order to explore (a) the relations among various protective and vulnerability factors, and (b) the unique contributions of these protective and vulnerability factors to different types of psychological problems. Results indicated that the overlap among protective and vulnerability factors was quite modest. Further, it was found that factors clustered in theoretically meaningful components reflecting protection, vulnerability, and more specific aspects of coping and social support. Finally, data indicated that each type of psychopathology symptoms was associated with a typical set of protective and vulnerability factors. Although these results should be interpreted with caution because of the cross-sectional nature of the study, they may nevertheless guide future research exploring multifactorial models of psychopathology in youths

Crop water stress index is a sensitive water stress indicator in pistachio trees

Regulated deficit irrigation (RDI) strategies, often applied in tree crops, require precise monitoring methods of water stress. Crop water stress index (CWSI), based on canopy temperature measurements, has shown to be a good indicator of water deficits in field crops but has seldom been used in trees. CWSI was measured on a continuous basis in a Central California mature pistachio orchard, under full and deficit irrigation. Two treatments—control, returning the full evapotranspiration (ETc) and RDI—irrigated with 40% ETc during stage 2 of fruit grow (shell hardening). During stage 2, the canopy temperature—measured continuously with infrared thermometers (IRT)—of the RDI treatment was consistently higher than the control during the hours of active transpiration; the difference decreasing after irrigation. The non-water-stressed baseline (NWSB), obtained from clear-sky days canopy–air temperature differential and vapour pressure deficit (VPD) in the control treatment, showed a marked diurnal variation in the intercept, mainly explained by the variation in solar radiation. In contrast, the NWSB slope remained practically constant along the day. Diurnal evolution of calculated CWSI was stable and near zero in the control, but showed a clear rising diurnal trend in the RDI treatment, increasing as water stress increased around midday. The seasonal evolution of the CWSI detected large treatment differences throughout the RDI stress period. While the CWSI in the well-irrigated treatment rarely exceeded 0.2 throughout the season, RDI reached values of 0.8–0.9 near the end of the stress period. The CWSI responded to irrigation events along the whole season, and clearly detected mild water stress, suggesting extreme sensitivity to variations in tree water status. It correlated well with midday leaf water potential (LWP), but was more sensitive than LWP at mild stress levels. We conclude that the CWSI, obtained from continuous nadir-view measurements with IRTs, is a good and very sensitive indicator of water stress in pistachio. We recommend the use of canopy temperature measurements taken from 1200 to 1500 h, together with the following equation for the NWSB: (T c − T a) = −1.33·VPD + 2.44. Measurements of canopy temperature with VPD < 2 kPa are likely to generate significant errors in the CWSI calculation and should be avoided.This work was funded by the California Department of Water Resources, Office of Water Use Efficiency and we thank Peter Brostrom, project manager, for his support and guidance. L. Testi and F. Iniesta were supported by programs AGL2003-01468 and CONSOLIDER-RIDECO C-CSD2006-000672 of the Spanish Ministry of Science and Education.Peer reviewe