A semiquantitative approach to the impurity-band-related transport properties of GaMnAs nanolayers

We investigate the spin-polarized transport of GaMnAs nanolayers in which a ferromagnetic order exists below a certain transition temperature. Our calculation for the self-averaged resistivity takes into account the existence of an impurity band determining the extended ("metallic" transport) or localized (hopping by thermal excitation) nature of the states at and near the Fermi level. Magnetic order and resistivity are inter-related due to the influence of the spin polarization of the impurity band and the effect of the Zeeman splitting on the mobility edge. We obtain, for a given range of Mn concentration and carrier density, a "metallic" behavior in which the transport by extended carriers dominates at low temperature, and is dominated by the thermally excited localized carriers near and above the transition temperature. This gives rise to a conspicuous hump of the resistivity which has been experimentally observed and brings light onto the relationship between transport and magnetic properties of this material

Modelling the behaviour of steel fibre reinforced concrete using a discrete strong discontinuity approach

The use of Fibre Reinforced Concrete (FRC) is gradually wide-spreading due to the significant advantages relatively to Normal Concrete (NC). In the case of steel fibres, the quasi-brittle behaviour of plain concrete structures can be modified into an enhanced ductile behaviour as a direct result of this addition. Since the mechanical properties of both FRC and NC can be significantly different, this work aims at developing a finite element formulation to specifically address the simulation of the behaviour of FRC members up to failure. For this purpose, the Conforming Generalised Strong Discontinuity Approach (CGSDA) is adopted with steel fibres explicitly introduced in the finite element mesh. The resulting formulation has the following main characteristics: i) variational consistency; ii) fibre elements automatically considered regardless of the presence of cracks; and iii) no additional degrees of freedom are required. The proposed formulation is validated using experimental results from tests conducted with different dosages of steel fibres.FCOMP-01-0124-FEDER-020275, FCT PTDC/ECM/119214/2010, FCT SFRH/BD/85922/2012, ARC DE150101703

Avaliação do sistema radicular de Lima Ácida Tahiti em dois sistemas de manejo.

Para que as plantas cítricas tenham longevidade é necessário que o sistema radicular possa se desenvolver sem limitações. Rezende et al. (2002) registram o desenvolvimento prejudicado do sistema radicular de citros nos solos coesos dos Tabuleiros Costeiros, com as plantas geralmente exibindo sistema radicular superficial e enovelamento da raiz principal. A utilização de práticas de manejo de solo como, uso de coberturas vegetais e subsolagem, melhoram a morfologia da planta, uma melhor distribuição do sistema radicular permite explorar maior volume de solo para absorção de nutrientes e principalmente de água em profundidade. A produção citrícola nos Tabuleiros Costeiros, onde predominam Latossolos Amarelos e Argissolos Amarelos, caracterizados como profundos, ácidos e com presença de horizontes coesos (Jacomine et al., 1977), é realizada praticamente sem uso de irrigação, pois a região dispõe de uma distribuição de chuvas regular durante 9 a 10 meses/ano (CNPMF, 1993). Práticas culturais, como a utilização de leguminosas nas entrelinhas e herbicidas nas linhas, em áreas subsoladas a 0,50 m de profundidade, que foram capazes de aumentar o volume do sistema radicular dos citros neste ecossistema entre 68 e 148% e a produção de frutos entre 28 e 40%, respectivamente (Carvalho et al.,1999). O objetivo deste trabalho foi avaliar o sistema radicular da Lima Ácida Tahiti, verificando a capacidade das raízes de explorar o solo, comparando dois sistemas de cultivo.pdf 220

Aplicação fracionada de nitrogênio no algodoeiro irrigado.

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Structures and Vibrational Spectra of CH,OCH,CH,OH : The

Ab initio calculations at the MP2/6-31G* and MP2/6-31G*//6-31G* levels have been carried out for the monomer of 2-methoxyethanol (CH,OCH,CH,OH). The MP2/6-31G* results indicate that the two more stable conformers (tGg’ and gGg‘) display intramolecular hydrogen bonds directed from the hydroxy H atom to one of the lone pairs of the ether 0 atom, and that the tGg’ conformer is 6.3 kJ mol-’ more stable than the gGg’ conformer. As the MP2/6-31G* and MP2/6-3lG*//6-31G* calculations do not yield results differing by more than a few tenths of a kJ mol-‘, it is concluded that the structure-sensitive and the dynamic correlation corrections are far from being additive. While the optimization of geometry for the correlated wavefunction generally leads to increase of bond lengths and reduction of bond angles, on the whole the geometrical parameters undergo similar changes in different conformers. Ab initio harmonic 6-31G* derived force fields were used to perform normal mode analyses for the more stable conformers. The calculated v(CH) frequencies are found to correlate linearly with some of the ab initio calculated CH bond lengths. An interpretation of the FTIR and Raman spectra for the liquid phase consonant with the structural and vibrational ab initio results is presented. Two spectral features observed both in Raman and in FTIR spectra and associated with v(0H) in monomeric species are ascribed to conformers, in accord with the theoretical and experimental results. On the whole, both the structural and the vibrational results presented point to a distinction between the hydrogen-bonded G-type conformers (tGg’ and gGg‘) and the higher energy T-type conformers (tTg and tTt)