Direct observation of substitutional Ga after ion implantation in Ge by means of extended x-ray absorption fine structure

We present an experimental lattice location study of Ga atoms in Ge after ion implantation at elevated temperature (250°C). Using extended x-rayabsorption fine structure (EXAFS) experiments and a dedicated sample preparation method, we have studied the lattice location of Ga atoms in Ge with a concentration ranging from 0.5 at. % down to 0.005 at. %. At Ga concentrations ≤0.05 at.%, all Ga dopants are substitutional directly after ion implantation, without the need for post-implantation thermal annealing. At higher Ga concentrations, a reduction in the EXAFS amplitude is observed, indicating that a fraction of the Ga atoms is located in a defective environment. The local strain induced by the Ga atoms in the Ge matrix is independent of the Ga concentration and extends only to the first nearest neighbor Ge shell, where a 1% contraction in bond length has been measured, in agreement with density functional theory calculations.We acknowledge the support from the Research Foundation Flanders, the epi-team from imec, the KU Leuven GOA 09/06 project, the IUAP program P6/42 and the Australian Research Council. S.C. acknowledges support from OCAS NV by an OCAS-endowed chair at Ghent University

Knee valgus in self-initiated vertical jump landings: developmental and gender comparisons

The study examined gender and developmental differences in knee valgus angle and external knee valgus moment at the time of maximal vertical ground reaction force (MGRFz) in self-initiated vertical jump (VJ) landings. Fifty-six subjects grouped by age (pre-pubescent (8-11 yrs); post-pubescent (19-29 yrs)) and gender jumped for a ball set at 50% of their maximum VJ height then landed on two feet with only their dominant foot on the force plate. Statistical analyses of motion analysis (3-D) and GRF data showed that children had greater valgus angles (p = .003) and moments (p = .026) at MGRFz compared to adults. Females had greater (p = .016) valgus moments than males, but similar valgus angles at MGRFz. It will be important to ensure that as both boys and girls progress through puberty they develop an ability to offset high valgus moments and land with good lower extremity alignment

Knee valgus in self-initiated vertical jump landings: developmental and gender comparisons

The study examined gender and developmental differences in knee valgus angle and external knee valgus moment at the time of maximal vertical ground reaction force (MGRFz) in self-initiated vertical jump (VJ) landings. Fifty-six subjects grouped by age (pre-pubescent (8-11 yrs); post-pubescent (19-29 yrs)) and gender jumped for a ball set at 50% of their maximum VJ height then landed on two feet with only their dominant foot on the force plate. Statistical analyses of motion analysis (3-D) and GRF data showed that children had greater valgus angles (p = .003) and moments (p = .026) at MGRFz compared to adults. Females had greater (p = .016) valgus moments than males, but similar valgus angles at MGRFz. It will be important to ensure that as both boys and girls progress through puberty they develop an ability to offset high valgus moments and land with good lower extremity alignment

Loading rate in self-initiated vertical jump landings: developmental and gender comparisons

The study compared gender and developmental differences in vertical loading rate upon a two-footed landing from a self-initiated VJ. Fifty-seven subjects grouped by age (pre-pubescent (8-11 yrs); post-pubescent (19-29 yrs)) and gender consented to participate. Subjects jumped for a ball set at 50% of their maximum VJ height, and landed on two feet, facing forward, with only their dominant foot on the force plate. Motion analysis (3-D) and ground reaction force (GRF) data were collected. Statistical analyses indicated significant developmental differences in vertical loading rate normalized to kinetic energy, but no gender differences. Children may have higher loading rates because they lack the experience, strength, and associated neuromuscular patterns that prepare them to modulate force as adults do

KNEE VALGUS IN SELF-INITIATED VERTICAL JUMP LANDINGS: DEVELOPMENTAL AND GENDER COMPARISIONS

The study examined gender and developmental differences in knee valgus angle and external knee valgus moment at the time of maximal vertical ground reaction force (MGRFz) in self-initiated vertical jump (VJ) landings. Fifty-six subjects grouped by age (pre-pubescent (8-11 yrs); post-pubescent (19-29 yrs)) and gender jumped for a ball set at 50% of their maximum VJ height then landed on two feet with only their dominant foot on the force plate. Statistical analyses of motion analysis (3-D) and GRF data showed that children had greater valgus angles (p = .003) and moments (p = .026) at MGRFz compared to adults. Females had greater (p = .016) valgus moments than males, but similar valgus angles at MGRFz. It will be important to ensure that as both boys and girls progress through puberty they develop an ability to offset high valgus moments and land with good lower extremity alignment

LOADING RATE IN SELF-INITIATED VERTICAL JUMP LANDINGS: DEVELOPMENTAL AND GENDER COMPARISONS

The study compared gender and developmental differences in vertical loading rate upon a two-footed landing from a self-initiated VJ. Fifty-seven subjects grouped by age (pre-pubescent (8-11 yrs); post-pubescent (19-29 yrs)) and gender consented to participate. Subjects jumped for a ball set at 50% of their maximum VJ height, and landed on two feet, facing forward, with only their dominant foot on the force plate. Motion analysis (3-D) and ground reaction force (GRF) data were collected. Statistical analyses indicated significant developmental differences in vertical loading rate normalized to kinetic energy, but no gender differences. Children may have higher loading rates because they lack the experience, strength, and associated neuromuscular patterns that prepare them to modulate force as adults do

Enhancing Employees’ Duty Orientation and Moral Potency: Dual Mechanisms Linking Ethical Psychological Climate to Ethically‐Focused Proactive Behaviors

Based on social cognitive theory (SCT), we develop and test a model that links ethical psychological climate to ethically‐focused proactive behavior (i.e., ethical voice and ethical taking charge) via two distinct mechanisms (i.e., duty orientation and moral potency). Results from multi‐wave field studies conducted in the United States, Turkey, France, Vietnam, and India demonstrate that an ethical psychological climate indirectly influences employees’ ethical voice and ethical taking charge behaviors through the dual mechanisms of duty orientation and moral potency. Additionally, we find that individuals’ moral attentiveness strengthened these mediating processes. Together, these findings suggest that ethical psychological climate is an important antecedent of ethically‐focused proactive behavior by stimulating individuals’ sense of duty and enhancing their moral potency, particularly when employees are already highly attuned to moral issues

Electrical and structural properties of In-implanted Si1−xGex alloys

We report on the effects of dopant concentration and substrate stoichiometry on the electrical and structural properties of In-implanted Si1−xGex alloys. Correlating the fraction of electrically active In atoms from Hall Effect measurements with the In atomic environment determined by X-ray absorption spectroscopy, we observed the transition from electrically active, substitutional In at low In concentration to electrically inactive metallic In at high In concentration. The In solid-solubility limit has been quantified and was dependent on the Si1−xGex alloy stoichiometry; the solid-solubility limit increased as the Ge fraction increased. This result was consistent with density functional theory calculations of two In atoms in a Si1−xGex supercell that demonstrated that In–In pairing was energetically favorable for x ≲ 0.7 and energetically unfavorable for x ≳ 0.7. Transmission electron microscopy imaging further complemented the results described earlier with the In concentration and Si1−xGex alloy stoichiometry dependencies readily visible. We have demonstrated that low resistivity values can be achieved with In implantation in Si1−xGex alloys, and this combination of dopant and substrate represents an effective doping protocol

Observation of reduced thermal conductivity in a metal-organic framework due to the presence of adsorbates

Whether the presence of adsorbates increases or decreases thermal conductivity in metal-organic frameworks (MOFs) has been an open question. Here we report observations of thermal transport in the metal-organic framework HKUST-1 in the presence of various liquid adsorbates: water, methanol, and ethanol. Experimental thermoreflectance measurements were performed on single crystals and thin films, and theoretical predictions were made using molecular dynamics simulations. We find that the thermal conductivity of HKUST-1 decreases by 40 – 80% depending on the adsorbate, a result that cannot be explained by effective medium approximations. Our findings demonstrate that adsorbates introduce additional phonon scattering in HKUST-1, which particularly shortens the lifetimes of low-frequency phonon modes. As a result, the system thermal conductivity is lowered to a greater extent than the increase expected by the creation of additional heat transfer channels. Finally, we show that thermal diffusivity is even more greatly reduced than thermal conductivity by adsorption