Electrodeposition of copper from mixed sulphate–chloride acidic electrolytes at rotating disc electrode

The effect of chloride ion on the deposition of copper from low metal concentrations in aqueous, acid sulphate solutions was investigated. The electrolytes contained 0·05 mol dm?3 CuSO4 and 0·5 mol dm?3 Na2SO4 at pH 2 and 296 K. The chloride ion concentration was varied in a wide range from 0·03 to 2·0 mol dm?3. Linear sweep voltammetry was carried out under well defined flow conditions at a smooth platinum rotating disc electrode. The progressive transition from a single, two-electron reaction for the reduction of Cu(II)?Cu(0) to two, single-electron reactions for the reduction sequence: Cu(II)?Cu(I)?Cu(0) was clearly evident as the chloride ion concentration increased. The charge transfer and mass transport characteristics of these reactions were evaluated. The formal potential for the Cu II) reduction to Cu(I), the shift in the potential region for complete mass transport controlled reduction of Cu(I) to Cu(0) and the potential for hydrogen evolution at the deposited copper were also studied. A semi-logarithmic relationship between exchange current density and half-wave potential for Cu(II)?Cu(I) with chloride ion was achieved when the Cl?/Cu(II) ratio in the electrolytes exceeded 2, due to the presence of the Cu(I) dichlorocuprous anion, CuCl2?

Deep-inelastic Electron-Photon Scattering at High Q^2 : Neutral and Charged Current Reactions

We present the results of a calculation of deep inelastic electron-photon scattering at a linear collider for very high virtuality of the intermediate gauge boson up to NLO in perturbative QCD. The real photon is produced unpolarized via the Compton back scattering of laser light of the incoming beam. For $Q^2$ values close to the masses squared of the Z and W gauge bosons, the deep inelastic electron-photon scattering process receives important contributions not only from virtual photon exchange but also from the exchange of a Z-boson and a W-boson. We find that the total cross section for center of mass energies above $500 \rm{GeV}$ is at least of ${\cal O}(pb)$ and has an important charged current contribution.Comment: Talk given at the International Conference on the Structure and Interactions of the Photon, PHOTON 99, Freiburg im Breisgau, Germany, May 23-27, 1999. To be published in the Proceedings. 6 pages, 6 postscript figures. The complete paper, including figures, is also available via anonymous ftp at ftp://ttpux2.physik.uni-karlsruhe.de/ttp99/ttp99-30/ or via www at http://www-ttp.physik.uni-karlsruhe.de/Preprints

The infrared environments of masers associated with star formation

The near infrared (1-2um) and the thermal infrared (3-25um) trace many of the environments in which masers are thought to reside, including shocks, outflows, accretion disks, and the dense medium near protostars. After a number of recent surveys it has been found that there is a higher detection rate of mid-IR emission towards masers than cm radio continuum emission from UC HII regions, and that the mid-IR emission is actually more closely cospatial to the maser locations. A high percentage of water and methanol masers that are not coincident with the UC HII regions in massive star forming regions are likely to be tracing outflows and extremely young high mass stars before the onset of the UC HII region phase. After a decade of groundwork supporting the hypothesis that linarly distributed class II methanol masers may generally trace accretion disks around young massive stars, compelling evidence is mounting that these masers may generally be associated with outflows instead. Substantiation of this claim comes from recent outflow surveys and high angular resolution mid-IR imaging of the maser environments.Comment: 8 pages, 2 figures, to appear in the proceedings of IAUS 242 "Astrophysical Masers and Their Environments", eds. J. Chapman & W. Baan. A version with higher resolution is available at http://www.ctio.noao.edu/~debuize

Oxidation of the borohydride Ion at silver nanoparticles on a glassy carbon electrode (GCE) using pulsed potential techniques

Direct oxidation borohydride fuel cells are very attractive energy conversion devices. Silver has been reported as one of the few materials which can catalyze an 8-electron oxidation. Potential step amperometric pulse techniques to synthesize nanostructured silver material on flat glassy carbon electrodes is reported and significant differences with bulk silver deposit have been observed. The oxidation of borohydride ion on the silver particles occurs at -0.025 V vs. SCE and the potential decreases towards negative values at longer cycle times. The oxidation current also decreases with the number of cycles, suggesting that the silver active sites become partially blocked by oxidation products of borohydride. The electroactive area per unit electrode area of silver was relatively low for particles deposited using potential step amperometric techniques on glassy carbon (0.002 cm2 per cm-2) compared with the area found at a polycrystalline silver electrode (0.103 cm2 per cm-2

Embedded Stellar Populations towards Young Massive Star Formation Regions I. G305.2+0.2

We present deep, wide-field J, H and Ks images taken with IRIS2 on the Anglo Australian Telescope, towards the massive star formation region G305.2+0.2. Combined with 3.6, 4.5, 5.8 and 8.0 micron data from the GLIMPSE survey on the Spitzer Space Telescope, we investigate the properties of the embedded stellar populations. After removing contamination from foreground stars we separate the sources based on their IR colour. Strong extended emission in the GLIMPSE images hampers investigation of the most embedded sources towards the known sites of massive star formation. However, we find a sizeable population of IR excess sources in the surrounding region free from these completeness effects. Investigation reveals the recent star formation activity in the region is more widespread than previously known. Stellar density plots show the embedded cluster in the region, G305.24+0.204, is offset from the dust emission. We discuss the effect of this cluster on the surrounding area and argue it may have played a role in triggering sites of star formation within the region. Finally, we investigate the distribution of IR excess sources towards the cluster, in particular their apparent lack towards the centre compared with its immediate environs.Comment: 16 pages, 16 figures (significantly size reduced), 2 tables, accepted MNRA

Radio Observations of New Galactic Bulge Planetary Nebulae

We observed 64 newly identified galactic bulge planetary nebulae in the radio continuum at 3 and 6 cm with the Australia Telescope Compact Array. We present their radio images, positions, flux densities, and angular sizes. The survey appears to have detected a larger ratio of more extended planetary nebulae with low surface brightness than in previous surveys. We calculated their distances according to Van de Steene & Zijlstra (1995). We find that most of the new sample is located on the near side around the galactic center and closer in than the previously known bulge PNe. Based on H-alpha images and spectroscopic data, we calculated the total H-alpha flux. We compare this flux value with the radio flux density and derive the extinction. We confirm that the distribution of the extinction values around the galactic center rises toward the center, as expected.Comment: accepted for publication in A&

MRK 1216 & NGC 1277 - An orbit-based dynamical analysis of compact, high velocity dispersion galaxies

We present a dynamical analysis to infer the structural parameters and properties of the two nearby, compact, high velocity dispersion galaxies MRK1216 & NGC1277. Combining deep HST imaging, wide-field IFU stellar kinematics, and complementary long-slit spectroscopic data out to 3 R_e, we construct orbit-based models to constrain their black hole masses, dark matter content and stellar mass-to-light ratios. We obtain a black hole mass of log(Mbh/Msun) = 10.1(+0.1/-0.2) for NGC1277 and an upper limit of log(Mbh/Msun) = 10.0 for MRK1216, within 99.7 per cent confidence. The stellar mass-to-light ratios span a range of Upsilon_V = 6.5(+1.5/-1.5) in NGC1277 and Upsilon_H = 1.8(+0.5/-0.8) in MRK1216 and are in good agreement with SSP models of a single power-law Salpeter IMF. Even though our models do not place strong constraints on the dark halo parameters, they suggest that dark matter is a necessary ingredient in MRK1216, with a dark matter contribution of 22(+30/-20) per cent to the total mass budget within 1 R_e. NGC1277, on the other hand, can be reproduced without the need for a dark halo, and a maximal dark matter fraction of 13 per cent within the same radial extent. In addition, we investigate the orbital structures of both galaxies, which are rotationally supported and consistent with photometric multi-S\'ersic decompositions, indicating that these compact objects do not host classical, non-rotating bulges formed during recent (z <= 2) dissipative events or through violent relaxation. Finally, both MRK 1216 and NGC 1277 are anisotropic, with a global anisotropy parameter delta of 0.33 and 0.58, respectively. While MRK 1216 follows the trend of fast-rotating, oblate galaxies with a flattened velocity dispersion tensor in the meridional plane of the order of beta_z = delta, NGC 1277 is highly tangentially anisotropic and seems to belong kinematically to a distinct class of objects.Comment: 27 pages, 15 figures and 4 tables. Accepted for publication in MNRA

A Farm-Level Evaluation of Conditions Under Which Farmers Will Supply Biomass Feedstocks for Energy Production

This study evaluated the risk management potential of including biomass crops as a diversification strategy for a grain farm in northwest Tennessee. Results indicate that adding biomass crops to the farm enterprise mix could improve mean net revenues and reduced net revenue variability.Resource /Energy Economics and Policy,

The 3D printing of a polymeric electrochemical cell body and its characterisation

An undivided flow cell was designed and constructed using additive manufacturing technology and its mass transport characteristics were evaluated using the reduction of ferricyanide, hexacyanoferrate (III) ions at a nickel surface. The dimensionless mass transfer correlation Sh = aRebScdLee was obtained using the convective-diffusion limiting current observed in linear sweep voltammetry; this correlation compared closely with that reported in the literature from traditionally machined plane parallel rectangular flow channel reactors. The ability of 3D printer technology, aided by computational graphics, to rapidly and conveniently design, manufacture and re-design the geometrical characteristics of the flow cell ishighlighted