Crossover between mean-field and Ising critical behavior in a lattice-gas reaction-diffusion model

Lattice-gas models for CO oxidation can exhibit a discontinuous nonequilibrium transition between reactive and inactive states, which disappears above a critical CO-desorption rate. Using finite-size-scaling analysis, we demonstrate a crossover from Ising to mean-field behavior at the critical point, with increasing surface mobility of adsorbed CO or with decreasing system size. This behavior is elucidated by analogy with that of equilibrium Ising-type systems with long-range interactions.Comment: 6 pages, 3 figure

Rotor Bar Fault Monitoring Method Based on Analysis of Air-Gap Torques of Induction Motors

A robust method to monitor the operating conditions of induction motors is presented. This method utilizes the data analysis of the air-gap torque profile in conjunction with a Bayesian classifier to determine the operating condition of an induction motor as either healthy or faulty. This method is trained offline with datasets generated either from an induction motor modeled by a time-stepping finite-element (TSFE) method or experimental data. This method can effectively monitor the operating conditions of induction motors that are different in frame/class, ratings, or design from the motor used in the training stage. Such differences can include the level of load torque and operating frequency. This is due to a novel air-gap torque normalization method introduced here, which leads to a motor fault classification process independent of these parameters and with no need for prior information about the motor being monitored. The experimental results given in this paper validate the robustness and efficacy of this method. Additionally, this method relies exclusively on data analysis of motor terminal operating voltages and currents, without relying on complex motor modeling or internal performance parameters not readily available

Attractor reconstruction of an impact oscillator for parameter identification

Peer reviewedPreprin

Optimal Controller and Filter Realisations using Finite-precision, Floating- point Arithmetic.

The problem of reducing the fragility of digital controllers and filters implemented using finite-precision, floating-point arithmetic is considered. Floating-point arithmetic parameter uncertainty is multiplicative, unlike parameter uncertainty resulting from fixed-point arithmetic. Based on first- order eigenvalue sensitivity analysis, an upper bound on the eigenvalue perturbations is derived. Consequently, open-loop and closed-loop eigenvalue sensitivity measures are proposed. These measures are dependent upon the filter/ controller realization. Problems of obtaining the optimal realization with respect to both the open-loop and the closed-loop eigenvalue sensitivity measures are posed. The problem for the open-loop case is completely solved. Solutions for the closed-loop case are obtained using non-linear programming. The problems are illustrated with a numerical example

Statistical mechanical models for dissociative adsorption of O2 on metal(100) surfaces with blocking, steering, and funneling

We develop statistical mechanical models amenable to analytic treatment for the dissociative adsorption of O2 at hollow sites on fcc(100) metal surfaces. The models incorporate exclusion of nearest-neighbor pairs of adsorbed O. However, corresponding simple site-blocking models, where adsorption requires a large ensemble of available sites, exhibit an anomalously fast initial decrease in sticking. Thus, in addition to blocking, our models also incorporate more facile adsorption via orientational steering and funneling dynamics (features supported by ab initio Molecular Dynamics studies). Behavior for equilibrated adlayers is distinct from those with finite adspecies mobility. We focus on the low-temperature limited-mobility regime where analysis of the associated master equations readily produces exact results for both short- and long-time behavior. Kinetic Monte Carlo simulation is also utilized to provide a more complete picture of behavior. These models capture both the initial decrease and the saturation of the experimentally observed sticking versus coverage, as well as features of non-equilibrium adlayer ordering as assessed by surface-sensitive diffraction

Dissociative adsorption of O2 on unreconstructed metal (100) surfaces: Pathways, energetics, and sticking kinetics

An accurate description of oxygen dissociation pathways and kinetics for various local adlayer environments is key for an understanding not just of the coverage dependence of oxygen sticking, but also of reactive steady states in oxidation reactions. Density functional theory analysis for M(100) surfaces with M=Pd, Rh, and Ni, where O prefers the fourfold hollow adsorption site, does not support the traditional Brundle-Behm-Barker picture of dissociative adsorption onto second-nearest-neighbor hollow sites with an additional blocking constraint. Rather adsorption via neighboring vicinal bridge sites dominates, although other pathways can be active. The same conclusion also applies for M=Pt and Ir, where oxygen prefers the bridge adsorption site. Statistical mechanical analysis is performed based on kinetic Monte Carlo simulation of a multisite lattice-gas model consistent with our revised picture of adsorption. This analysis determines the coverage and temperature dependence of sticking for a realistic treatment of the oxygen adlayer structure

Symmetry-Breaking and Percolation Transitions in a Surface Reaction Model with Superlattice Ordering

A symmetry-breaking order-disorder transition of the Ising type is found in a nonequilibrium surface reaction model for CO oxidation incorporating superlattice ordering of adsorbed oxygen. We relate this transition to the percolation of superlattice domains of oxygen, and discuss the consequences for chemical diffusion of coadsorbed CO. The latter constitutes a new type of problem involving transport in disordered media