904 research outputs found
GTI-space : the space of generalized topological indices
A new extension of the generalized topological indices (GTI) approach is carried out torepresent 'simple' and 'composite' topological indices (TIs) in an unified way. Thisapproach defines a GTI-space from which both simple and composite TIs represent particular subspaces. Accordingly, simple TIs such as Wiener, Balaban, Zagreb, Harary and Randićconnectivity indices are expressed by means of the same GTI representation introduced for composite TIs such as hyper-Wiener, molecular topological index (MTI), Gutman index andreverse MTI. Using GTI-space approach we easily identify mathematical relations between some composite and simple indices, such as the relationship between hyper-Wiener and Wiener index and the relation between MTI and first Zagreb index. The relation of the GTI space with the sub-structural cluster expansion of property/activity is also analysed and some routes for the applications of this approach to QSPR/QSAR are also given
The metallic state in disordered quasi-one-dimensional conductors
The unusual metallic state in conjugated polymers and single-walled carbon
nanotubes is studied by dielectric spectroscopy (8--600 GHz). We have found an
intriguing correlation between scattering time and plasma frequency. This
relation excludes percolation models of the metallic state. Instead, the
carrier dynamics can be understood in terms of the low density of delocalized
states around the Fermi level, which arises from the competion between
disorder-induced localization and interchain-interactions-induced
delocalization.Comment: 4 pages including 4 figure
The formation of homogentisate in the biosynthesis of tocopherol and plastoquinone in spinach chloroplasts
Homogentisate is the precursor in the biosynthesis of -tocopherol and plastoquinone-9 in chloroplasts. It is formed of 4-hydroxyphenylpyruvate of the shikimate pathway by the 4-hydroxyphenylpyruvate dioxygenase. In experiments with spinach the dioxygenase was shown to be localized predominatedly in the chloroplasts. Envelope membranes exhibit the highest specific activity, however, because of the high stromal portion of chloroplasts, 60–80% of the total activity is housed in the stroma. The incorporation of 4-hydroxyphenylpyruvate into 2-methyl-6-phytylquinol as the first intermediate in the tocopherol synthesis by the two-step-reaction: 4-Hydroxyphenylpyruvate Homogentisate 2-Methyl-6-phytylquinol was demonstrated by using envelope membranes. Homogentisate originates directly from 4-hydroxyphenylpyruvate of the shikimate pathway. Additionally, a bypass exists in chloroplasts which forms 4-hydroxyphenylpyruvate from tyrosine by an L-amino-acid oxidase of the thylakoids and in peroxisomes by a transaminase reaction. Former results about the dioxygenase in peroxisomes were verified
Meditation-induced bliss viewed as release from conditioned neural (thought) patterns that block reward signals in the brain pleasure center
The nucleus accumbens orchestrates processes related to reward and pleasure,
including the addictive consequences of repeated reward (e.g., drug addiction and
compulsive gambling) and the accompanying feelings of craving and anhedonia.
The neurotransmitters dopamine and endogenous opiates play interactive roles in
these processes. They are released by natural rewards (i.e., food, water, sex, money,
play, etc.) and are released or mimicked by drugs of abuse. Repeated drug use
induces conditioned down-regulation of these neurotransmitters, thus causing
painful suppression of everyday pleasure. As with many spiritual traditions,
Buddhism provides strong advice against the pursuit of worldly pleasures to
attain the ‘‘good life.’’ In contrast, many forms of meditation give rise to an
immense and abiding joy. Most of these practices involve ‘‘stilling the mind,’’
whereby all content-laden thought (e.g., fantasies, daydreams, plans) ceases, and
the mind enters a state of openness, formlessness, clarity, and bliss. This can be
explained by the Buddhist suggestion that almost all of our everyday thoughts are
a form of addiction. It follows that if we turn off this internal ‘‘gossip of ego,’’ we
will find relief from the biochemical dopamine/opiate down-regulation, which is,
perhaps, the perpetual concomitant of our daily rumination
A microscopic model for d-wave charge carrier pairing and non-Fermi-liquid behavior in a purely repulsive 2D electron system
We investigate a microscopic model for strongly correlated electrons with
both on-site and nearest neighbor Coulomb repulsion on a 2D square lattice.
This exhibits a state in which electrons undergo a ``somersault'' in their
internal spin-space (spin-flux) as they traverse a closed loop in external
coordinate space. When this spin-1/2 antiferromagnetic (AFM) insulator is
doped, the ground state is a liquid of charged, bosonic meron-vortices, which
for topological reasons are created in vortex-antivortex pairs. The magnetic
exchange energy of the distorted AFM background leads to a logarithmic
vortex-antivortex attraction which overcomes the direct Coulomb repulsion
between holes localized on the vortex cores. This leads to the appearance of
pre-formed charged pairs. We use the Configuration Interaction (CI) Method to
study the quantum translational and rotational motion of various charged
magnetic solitons and soliton pairs. The CI method systematically describes
fluctuation and quantum tunneling corrections to the Hartree-Fock Approximation
(HFA). We find that the lowest energy charged meron-antimeron pairs exhibit
d-wave rotational symmetry, consistent with the symmetry of the cuprate
superconducting order parameter. For a single hole in the 2D AFM plane, we find
a precursor to spin-charge separation in which a conventional charged
spin-polaron dissociates into a singly charged meron-antimeron pair. This model
provides a unified microscopic basis for (i) non-Fermi-liquid transport
properties, (ii) d-wave preformed charged carrier pairs, (iii) mid-infrared
optical absorption, (iv) destruction of AFM long range order with doping and
other magnetic properties, and (v) certain aspects of angled resolved
photo-emission spectroscopy (ARPES).Comment: 14 pages, 17 figure
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