23 research outputs found
A Derivation of Three-Dimensional Inertial Transformations
The derivation of the transformations between inertial frames made by
Mansouri and Sexl is generalised to three dimensions for an arbitrary direction
of the velocity. Assuming lenght contraction and time dilation to have their
relativistic values, a set of transformations kinematically equivalent to
special relativity is obtained. The ``clock hypothesis'' allows the derivation
to be extended to accelerated systems. A theory of inertial transformations
maintaining an absolute simultaneity is shown to be the only one logically
consistent with accelerated movements. Algebraic properties of these
transformations are discussed. Keywords: special relativity, synchronization,
one-way velocity of light, ether, clock hypothesis.Comment: 16 pages (A5), Latex, one figure, to be published in Found. Phys.
Lett. (1997
Molar conductance of aqueous solutions of sodium, potassium, and nickel trifluoromethanesulfomate at 25°C
The electrical conductivities of aqueous solutions of NaCF3SO3, KCF3SO3, and Ni(CF3SO3)2 have been measured at 25°C in the concentration range 1 to 25×10-3 mol-dm-3. The data approach the Onsager limiting law at low concentrations, leading to a limiting molar ion conductivity for the CF3SO-3 ion of 44.5±0.2 S-cm2-mol-1, based on standard values for the cations. Using a simple size parameter for unsymmetrical polyatomic ions, based on the ion geometry, it is shown that the well known empirical relation between the molar conductivities of symmetrical ions and their radii can be extended to include certain polyatomic anions including CF3SO-3. The results suggest that the CF3SO-3-ion is either a weak structure breaker in aqueous solution or neutral in this respect
