853 research outputs found

    Magnetic excitations in the spin-1/2 triangular-lattice antiferromagnet Cs2_2CuBr4_4

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    We report on high-field electron spin resonance (ESR) studies of magnetic excitations in the spin-1/2 triangular-lattice antiferromagnet Cs2_2CuBr4_4. Frequency-field diagrams of ESR excitations are measured for different orientations of magnetic fields up to 25 T. We show that the substantial zero-field energy gap, Δ9.5\Delta\approx9.5 K, observed in the low-temperature excitation spectrum of Cs2_2CuBr4_4 [Zvyagin et al.et~al., Phys. Rev. Lett. 112, 077206 (2014)], is present well above TNT_N. Noticeably, the transition into the long-range magnetically ordered phase does not significantly affect the size of the gap, suggesting that even below TNT_N the high-energy spin dynamics in Cs2_2CuBr4_4 is determined by short-range-order spin correlations. The experimental data are compared with results of model spin-wave-theory calculations for spin-1/2 triangle-lattice antiferromagnet.Comment: 6 pages, 9 figure

    Probing the C-H Activation of Linear and Cyclic Ethers at (PNP)Ir

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    Interaction of the amido/bis(phosphine)-supported (PNP)Ir fragment with a series of linear and cyclic ethers is shown to afford, depending on substrate, products of α,α-dehydrogenation (carbenes), α,β-dehydrogenation (vinyl ethers), or decarbonylation. While carbenes are exclusively obtained from tert-amyl methyl ether, sec-butyl methyl ether (SBME), n-butyl methyl ether (NBME), and tetrahydrofuran (THF), vinyl ethers or their adducts are observed upon reaction with diethyl ether and 1,4-dioxane. Decarbonylation occurs upon interaction of (PNP)Ir with benzyl methyl ether, and a mechanism is proposed for this unusual transformation, which occurs via a series of C−H, C−O, and C−C bond cleavage events. The intermediates characterized for several of these reactions as well as the α,α-dehydrogenation of tert-butyl methyl ether (MTBE) are used to outline a reaction pathway for the generation of PNP-supported iridium(I) carbene complexes, and it is shown that the long-lived, observable intermediates are substrate-dependent and differ for the related cases of MTBE and THF. Taken together, these findings highlight the variety of pathways utilized by the electron-rich, unsaturated (PNP)Ir fragment to stabilize itself by transferring electron density to ethereal substrates through oxidative addition and/or the formation of π-acidic ligands

    Mechanical behavior and microstructure evolution of a Ti-15Mo/TiB titanium–matrix composite during hot deformation

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    A Ti-15Mo/TiB titanium–matrix composite (TMC) was produced by spark plasma sintering at 1400◦C under a load of 40 MPa for 15 min using a Ti-14.25(wt.)%Mo-5(wt.)%TiB2 powder mixture. Microstructure evolution and mechanical behavior of the composite were studied during uniaxial compression at room temperature and in a temperature range of 500–1000◦C

    Microstructure evolution of a ti/tib metal-matrix composite during high-temperature deformation

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    A Ti/TiB metal-matrix composite (MMC) was produced by spark plasma sintering using a Ti-10wt.%TiB2 powder mixture at 850°C under a load of 40 MPa for 15 min. The microstructure evolution and mechanical behavior of the Ti/TiB composite during uniaxial compression at the temperature range 500 - 1050°С was studie

    THz-range free-electron laser ESR spectroscopy: techniques and applications in high magnetic fields

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    The successful use of picosecond-pulse free-electron-laser (FEL) radiation for the continuous-wave THz-range electron spin resonance (ESR) spectroscopy has been demonstrated. The combination of two linac-based FELs (covering the wavelength range of 4 - 250 μ\mum) with pulsed magnetic fields up to 70 T allows for multi-frequency ESR spectroscopy in a frequency range of 1.2 - 75 THz with a spectral resolution better than 1%. The performance of the spectrometer is illustrated with ESR spectra obtained in the 2,2-diphenyl-1-picrylhydrazyl (DPPH) and the low-dimensional organic material (C6_6H9_9N2_2)CuCl3_3.Comment: 9 pages, 9 figures. Rev. Sci. Instrum., accepte

    Evolution of microstructure and mechanical properties of Tibased metal-matrix composites during high-pressure torsion

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    The microstructure and microhardness evolution of a Ti/TiB and Ti15(wt.%) Mo/TiB metal-matrix composites (MMC) during high-pressure torsion (HPT) at 400 °C was studie

    Effect of plastic deformation on the structure and properties of the Ti/TiB composite produced by spark plasma sintering

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    A Ti/17 vol % TiB composite material is produced by spark plasma sintering of a mixture of titanium and 10 wt % TiB2 powders at a temperature of 1000°C. Multiaxial isothermal forging is performed at t = 850°C to enhance the mechanical properties of the composit

    High-field spectroscopy of singlet-triplet transitions in the spin-dimer systems Sr3Cr2O8 and Ba3Cr2O8

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    Magnetic excitations in the isostructural spin-dimer systems Sr3Cr2O8 and Ba3Cr2O8 are probed by means of high-field electron spin resonance at sub-terahertz frequencies. Three types of magnetic modes were observed. One mode is gapless and corresponds to transitions within excited states, while two other sets of modes are gapped and correspond to transitions from the ground to the first excited states. The selection rules of the gapped modes are analyzed in terms of a dynamical Dzyaloshinskii-Moriya interaction, suggesting the presence of phonon-assisted effects in the low-temperature spin dynamics of Sr3Cr2O8 and Ba3Cr2O8Comment: 6 pages, 4 figures, all comments are welcome and appreciate

    Strange Exotic States and Compact Stars

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    We discuss the possible appearance of strange exotic multi-quark states in the interior of neutron stars and signals for the existence of strange quark matter in the core of compact stars. We show how the in-medium properties of possible pentaquark states are constrained by pulsar mass measurements. The possibility of generating the observed large pulsar kick velocities by asymmetric emission of neutrinos from strange quark matter in magnetic fields is outlined.Comment: 10 pages, invited talk given at the International Conference on Strangeness in Quark Matter 2006 (SQM2006), UCLA, USA, March 26-31, 2006, Journal of Physics G in press, refs. adde

    Comparative analysis of the organization of medical care in the terrorist attack on Dubrovka and Beslan

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    The article discusses the features of medical care in emergency situations. The most important aspects of first aid are investigated. The author analyzes statistical data from previous years and considers the most important points for reducing losses and complications among the child population. A comparative description of erroneous actions in organizing assistance in a terrorist attack in a theater center during the musical “Nord-Ost” on Dubrovka and Beslan is carried out.В статье описаны особенности оказания медицинской помощи в чрезвычайных ситуациях. Исследуются наиболее важные аспекты первой помощи. Авторами анализируются статистические данные прошлых лет и обсуждаются наиболее значимые моменты с целью понижения потерь и осложнений среди населения. Проведена сравнительная характеристика ошибочных действий при организации помощи при теракте в театральном центре во время мюзикла “Норд-Ост” на Дубровке и в Беслане
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