864 research outputs found
Magnetic excitations in the spin-1/2 triangular-lattice antiferromagnet CsCuBr
We report on high-field electron spin resonance (ESR) studies of magnetic
excitations in the spin-1/2 triangular-lattice antiferromagnet CsCuBr.
Frequency-field diagrams of ESR excitations are measured for different
orientations of magnetic fields up to 25 T. We show that the substantial
zero-field energy gap, K, observed in the low-temperature
excitation spectrum of CsCuBr [Zvyagin , Phys. Rev. Lett. 112,
077206 (2014)], is present well above . Noticeably, the transition into
the long-range magnetically ordered phase does not significantly affect the
size of the gap, suggesting that even below the high-energy spin dynamics
in CsCuBr is determined by short-range-order spin correlations. The
experimental data are compared with results of model spin-wave-theory
calculations for spin-1/2 triangle-lattice antiferromagnet.Comment: 6 pages, 9 figure
Probing the C-H Activation of Linear and Cyclic Ethers at (PNP)Ir
Interaction of the amido/bis(phosphine)-supported (PNP)Ir fragment with a series of linear and cyclic ethers is shown to afford, depending on substrate, products of α,α-dehydrogenation (carbenes), α,β-dehydrogenation (vinyl ethers), or decarbonylation. While carbenes are exclusively obtained from tert-amyl methyl ether, sec-butyl methyl ether (SBME), n-butyl methyl ether (NBME), and tetrahydrofuran (THF), vinyl ethers or their adducts are observed upon reaction with diethyl ether and 1,4-dioxane. Decarbonylation occurs upon interaction of (PNP)Ir with benzyl methyl ether, and a mechanism is proposed for this unusual transformation, which occurs via a series of C−H, C−O, and C−C bond cleavage events. The intermediates characterized for several of these reactions as well as the α,α-dehydrogenation of tert-butyl methyl ether (MTBE) are used to outline a reaction pathway for the generation of PNP-supported iridium(I) carbene complexes, and it is shown that the long-lived, observable intermediates are substrate-dependent and differ for the related cases of MTBE and THF. Taken together, these findings highlight the variety of pathways utilized by the electron-rich, unsaturated (PNP)Ir fragment to stabilize itself by transferring electron density to ethereal substrates through oxidative addition and/or the formation of π-acidic ligands
Mechanical behavior and microstructure evolution of a Ti-15Mo/TiB titanium–matrix composite during hot deformation
A Ti-15Mo/TiB titanium–matrix composite (TMC) was produced by spark plasma sintering at 1400◦C under a load of 40 MPa for 15 min using a Ti-14.25(wt.)%Mo-5(wt.)%TiB2 powder mixture. Microstructure evolution and mechanical behavior of the composite were studied during uniaxial compression at room temperature and in a temperature range of 500–1000◦C
Microstructure evolution of a ti/tib metal-matrix composite during high-temperature deformation
A Ti/TiB metal-matrix composite (MMC) was produced by spark plasma sintering using a Ti-10wt.%TiB2 powder mixture at 850°C under a load of 40 MPa for 15 min. The microstructure evolution and mechanical behavior of the Ti/TiB composite during uniaxial compression at the temperature range 500 - 1050°С was studie
THz-range free-electron laser ESR spectroscopy: techniques and applications in high magnetic fields
The successful use of picosecond-pulse free-electron-laser (FEL) radiation
for the continuous-wave THz-range electron spin resonance (ESR) spectroscopy
has been demonstrated. The combination of two linac-based FELs (covering the
wavelength range of 4 - 250 m) with pulsed magnetic fields up to 70 T
allows for multi-frequency ESR spectroscopy in a frequency range of 1.2 - 75
THz with a spectral resolution better than 1%. The performance of the
spectrometer is illustrated with ESR spectra obtained in the
2,2-diphenyl-1-picrylhydrazyl (DPPH) and the low-dimensional organic material
(CHN)CuCl.Comment: 9 pages, 9 figures. Rev. Sci. Instrum., accepte
Evolution of microstructure and mechanical properties of Tibased metal-matrix composites during high-pressure torsion
The microstructure and microhardness evolution of a Ti/TiB and Ti15(wt.%) Mo/TiB metal-matrix composites (MMC) during high-pressure torsion (HPT) at 400 °C was studie
Effect of plastic deformation on the structure and properties of the Ti/TiB composite produced by spark plasma sintering
A Ti/17 vol % TiB composite material is produced by spark plasma sintering of a mixture of titanium and 10 wt % TiB2 powders at a temperature of 1000°C. Multiaxial isothermal forging is performed at t = 850°C to enhance the mechanical properties of the composit
High-field spectroscopy of singlet-triplet transitions in the spin-dimer systems Sr3Cr2O8 and Ba3Cr2O8
Magnetic excitations in the isostructural spin-dimer systems Sr3Cr2O8 and
Ba3Cr2O8 are probed by means of high-field electron spin resonance at
sub-terahertz frequencies. Three types of magnetic modes were observed. One
mode is gapless and corresponds to transitions within excited states, while two
other sets of modes are gapped and correspond to transitions from the ground to
the first excited states. The selection rules of the gapped modes are analyzed
in terms of a dynamical Dzyaloshinskii-Moriya interaction, suggesting the
presence of phonon-assisted effects in the low-temperature spin dynamics of
Sr3Cr2O8 and Ba3Cr2O8Comment: 6 pages, 4 figures, all comments are welcome and appreciate
Strange Exotic States and Compact Stars
We discuss the possible appearance of strange exotic multi-quark states in
the interior of neutron stars and signals for the existence of strange quark
matter in the core of compact stars. We show how the in-medium properties of
possible pentaquark states are constrained by pulsar mass measurements. The
possibility of generating the observed large pulsar kick velocities by
asymmetric emission of neutrinos from strange quark matter in magnetic fields
is outlined.Comment: 10 pages, invited talk given at the International Conference on
Strangeness in Quark Matter 2006 (SQM2006), UCLA, USA, March 26-31, 2006,
Journal of Physics G in press, refs. adde
Including quaternary ammonium compounds in the composition of silers based on epoxy resins. literature review
The literature review presents the experience of introducing quaternary ammonium compounds into sealers based on epoxy resin - AH-Plus, AH26. Antibacterial effect of endo-sealants modified by the substances most common in dentistry of this class are consideredВ литературном обзоре представлен опыт введения четвертичных аммониевых соединений в состав силеров на основе эпоксидной смолы. Рассмотрен антибактериальный эффект эндогерметиков, модифицированных наиболее распространенными в стоматологии представителями данного класса вещест
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