82 research outputs found
Electrical Resistivity of Lanthanum, Praseodymium, Neodymium, and Samarium
The electrical resistivities of polycrystalline samples of La, Pr, Nd, and Sm are reported in the temperature range 1.3 to 300 deg K. La exhibits a superconducting transition at 5.8 deg K. The curve for Pr has slope changes at 61 and 95 deg K. The Nd curve shows small jumps at 5 and 20 deg K. Sm shows slope changes at 14 and 106 deg K. (auth
Forced Solid-State Interactions for the Selective âTurn-Onâ Fluorescence Sensing of Aluminum Ions in Water Using a Sensory Polymer Substrate
Selective and sensitive solid sensory substrates for detecting Al(III) in pure
water are reported. The material is a flexible polymer film that can be handled and exhibits gel
behavior and membrane performance. The film features a chemically anchored salicylaldehyde
benzoylhydrazone derivative as an aluminum ion fluorescence sensor. A novel procedure for
measuring Al(III) at the ppb level using a single solution drop in 20 min was developed. In this
procedure, a drop was allowed to enter the hydrophilic material for 15 min before a 5 min
drying period. The process forced the Al(III) to interact with the sensory motifs within the
membrane before measuring the fluorescence of the system. The limit of detection of Al(III)
was 22 ppm. Furthermore, a water-soluble sensory polymer containing the same sensory
motifs was developed with a limit of detection of Al(III) of 1.5 ppb, which was significantly
lower than the Environmental Protection Agency recommendations for drinking water.Spanish Ministerio de EconomiÌa
y Competitividad-Feder
(MAT2011-22544) and by the ConsejeriÌa
de EducacioÌn - Junta
de Castilla y LeoÌn (BU232U13)
Trade-Off between Toxicity and Signal Detection Orchestrated by Frequency- and Density-Dependent Genes
Behaviors in insects are partly highly efficient Bayesian processes that fulfill exploratory tasks ending with the colonization of new ecological niches. The foraging (for) gene in Drosophila encodes a cGMP-dependent protein kinase (PKG). It has been extensively described as a frequency-dependent gene and its transcripts are differentially expressed between individuals, reflecting the population density context. Some for transcripts, when expressed in a population at high density for many generations, concomitantly trigger strong dispersive behavior associated with foraging activity. Moreover, genotype-by-environment interaction (GEI) analysis has highlighted a dormant role of for in energetic metabolism in a food deprivation context. In our current report, we show that alleles of for encoding different cGMP-dependent kinase isoforms influence the oxidation of aldehyde groups of aromatic molecules emitted by plants via Aldh-III and a phosphorylatable adaptor. The enhanced efficiency of oxidation of aldehyde odorants into carboxyl groups by the action of for lessens their action and toxicity, which should facilitate exploration and guidance in a complex odor environment. Our present data provide evidence that optimal foraging performance requires the fast metabolism of volatile compounds emitted by plants to avoid neurosensory saturation and that the frequency-dependent genes that trigger dispersion influence these processes
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Argonne National Laboratory Reports
Report issued by the Argonne National Laboratory discussing single-phase water loop systems. As stated in the introduction, "the principal objective of this study was to determine the reliability of the calculations based upon numerical solutions of finite-difference energy and flow equations" (p. 9). This report includes tables, illustrations, and photographs
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