5,457 research outputs found
Identification of a Class of Index Models: A Topological Approach
We establish nonparametric identification in a class of so-called index models by
using a novel approach that relies on general topological results. Our proof strategy requires
substantially weaker conditions on the functions and distributions characterising the model
than those required by existing strategies; in particular, it does not require any large-support
conditions on the regressors of our model. We apply the general identification result to additive
random utility and competing risk model
ALMA CO J=6-5 observations of IRAS16293-2422: Shocks and entrainment
Observations of higher-excited transitions of abundant molecules such as CO
are important for determining where energy in the form of shocks is fed back
into the parental envelope of forming stars. The nearby prototypical and
protobinary low-mass hot core, IRAS16293-2422 (I16293) is ideal for such a
study. The source was targeted with ALMA for science verification purposes in
band 9, which includes CO J=6-5 (E_up/k_B ~ 116 K), at an unprecedented spatial
resolution (~0.2", 25 AU). I16293 itself is composed of two sources, A and B,
with a projected distance of 5". CO J=6-5 emission is detected throughout the
region, particularly in small, arcsecond-sized hotspots, where the outflow
interacts with the envelope. The observations only recover a fraction of the
emission in the line wings when compared to data from single-dish telescopes,
with a higher fraction of emission recovered at higher velocities. The very
high angular resolution of these new data reveal that a bow shock from source A
coincides, in the plane of the sky, with the position of source B. Source B, on
the other hand, does not show current outflow activity. In this region, outflow
entrainment takes place over large spatial scales, >~ 100 AU, and in small
discrete knots. This unique dataset shows that the combination of a
high-temperature tracer (e.g., CO J=6-5) and very high angular resolution
observations is crucial for interpreting the structure of the warm inner
environment of low-mass protostars.Comment: Accepted for publication in A&A Letter
Evidence for a single hydrogen molecule connected by an atomic chain
Stable, single-molecule conducting-bridge configurations are typically
identified from peak structures in a conductance histogram. In previous work on
Pt with H at cryogenic temperatures it has been shown that a peak near 1
identifies a single molecule Pt-H-Pt bridge. The histogram shows
an additional structure with lower conductance that has not been identified.
Here, we show that it is likely due to a hydrogen decorated Pt chain in contact
with the H molecular bridge.Comment: 4 pages, 4 figure
Modelling diverse root density dynamics and deep nitrogen uptake — a simple approach
We present a 2-D model for simulation of root density and plant nitrogen (N) uptake for crops grown in agricultural systems, based on a modification of the root density equation originally proposed by Gerwitz and Page in J Appl Ecol 11:773–781, (1974). A root system form parameter was introduced to describe the distribution of root length vertically and horizontally in the soil profile. The form parameter can vary from 0 where root density is evenly distributed through the soil profile, to 8 where practically all roots are found near the surface. The root model has other components describing root features, such as specific root length and plant N uptake kinetics. The same approach is used to distribute root length horizontally, allowing simulation of root growth and plant N uptake in row crops. The rooting depth penetration rate and depth distribution of root density were found to be the most important parameters controlling crop N uptake from deeper soil layers. The validity of the root distribution model was tested with field data for white cabbage, red beet, and leek. The model was able to simulate very different root distributions, but it was not able to simulate increasing root density with depth as seen in the experimental results for white cabbage. The model was able to simulate N depletion in different soil layers in two field studies. One included vegetable crops with very different rooting depths and the other compared effects of spring wheat and winter wheat. In both experiments variation in spring soil N availability and depth distribution was varied by the use of cover crops. This shows the model sensitivity to the form parameter value and the ability of the model to reproduce N depletion in soil layers. This work shows that the relatively simple root model developed, driven by degree days and simulated crop growth, can be used to simulate crop soil N uptake and depletion appropriately in low N input crop production systems, with a requirement of few measured parameters
Scalable Similarity Search for Molecular Descriptors
Similarity search over chemical compound databases is a fundamental task in
the discovery and design of novel drug-like molecules. Such databases often
encode molecules as non-negative integer vectors, called molecular descriptors,
which represent rich information on various molecular properties. While there
exist efficient indexing structures for searching databases of binary vectors,
solutions for more general integer vectors are in their infancy. In this paper
we present a time- and space- efficient index for the problem that we call the
succinct intervals-splitting tree algorithm for molecular descriptors (SITAd).
Our approach extends efficient methods for binary-vector databases, and uses
ideas from succinct data structures. Our experiments, on a large database of
over 40 million compounds, show SITAd significantly outperforms alternative
approaches in practice.Comment: To be appeared in the Proceedings of SISAP'1
Effect of bonding of a CO molecule on the conductance of atomic metal wires
We have measured the effect of bonding of a CO molecule on the conductance of
Au, Cu, Pt, and Ni atomic contacts at 4.2 K. When CO gas is admitted to the
metal nano contacts, a conductance feature appears in the conductance histogram
near 0.5 of the quantum unit of conductance, for all metals. For Au, the
intensity of this fractional conductance feature can be tuned with the bias
voltage, and it disappears at high bias voltage (above 200 mV). The
bonding of CO to Au appears to be weakest, and associated with monotomic Au
wire formation.Comment: 6 figure
Winter wheat roots grow twice as deep as spring wheat roots, is this important for N uptake and N leaching losses?
Cropping systems comprising winter catch crops followed by spring wheat could reduce N leaching risks compared to traditional winter wheat systems in humid climates. We studied the soil mineral N (Ninorg) and root growth of winter- and spring wheat to 2.5 m depth during three years. Root depth of winter wheat (2.2 m) was twice that of spring wheat, and this was related to much lower amounts of Ninorg in the 1 to 2.5 m layer after winter wheat (81 kg Ninorg ha-1 less). When growing winter catch crops before spring wheat, N content in the 1 to 2.5 m layer after spring wheat was not different from that after winter wheat. The results suggest that by virtue of its deep rooting, winter wheat may not lead to high levels of leaching as it is often assumed in humid climates. Deep soil and root measurements (below 1 m) in this experiment were essential to answer the questions we posed
CTMC calculations of electron capture and ionization in collisions of multiply charged ions with elliptical Rydberg atoms
We have performed classical trajectory Monte Carlo (CTMC) studies of electron
capture and ionization in multiply charged (Q=8) ion-Rydberg atom collisions at
intermediate impact velocities. Impact parallel to the minor and to the major
axis, respectively, of the initial Kepler electron ellipse has been
investigated. The important role of the initial electron momentum distribution
found for singly charged ion impact is strongly disminished for higher
projectile charge, while the initial spatial distribution remains important for
all values of Q studied.Comment: 3 pages, 5 figure
Quantum Interaction : the Construction of Quantum Field defined as a Bilinear Form
We construct the solution of the quantum wave equation
as a bilinear form which can
be expanded over Wick polynomials of the free -field, and where
is defined as the normal ordered product with
respect to the free -field. The constructed solution is correctly defined
as a bilinear form on , where is a
dense linear subspace in the Fock space of the free -field. On
the diagonal Wick symbol of this bilinear form
satisfies the nonlinear classical wave equation.Comment: 32 pages, LaTe
Origins and composition of fine atmospheric carbonaceous aerosol in the Sierra Nevada Mountains, California
In this paper we report chemically resolved measurements
of organic aerosol (OA) and related tracers during the Biosphere Effects on Aerosols and Photochemistry Experiment (BEARPEX) at the Blodgett Forest Research Station, California from 15 August–10 October 2007. OA contributed the majority of the mass to the fine atmospheric particles and was predominately oxygenated (OOA). The highest concentrations of OA were during sporadic wildfire influence when aged plumes were impacting the site. In
situ measurements of particle phase molecular markers were dominated by secondary compounds and along with gas phase compounds could be categorized into six factors or sources: (1) aged biomass burning emissions and oxidized urban emissions, (2) oxidized urban emissions (3) oxidation products of monoterpene emissions, (4) monoterpene emissions, (5) anthropogenic emissions and (6) local
methyl chavicol emissions and oxidation products. There were multiple biogenic components that contributed to OA at this site whose contributions varied diurnally, seasonally and in response to changing meteorological conditions, e.g. temperature and precipitation events. Concentrations of isoprene oxidation products were larger when temperatures were higher during the first half of the campaign (15 August–12 September) due to more substantial emissions of isoprene and enhanced photochemistry. The oxidation of methyl chavicol, an oxygenated terpene emitted by
ponderosa pine trees, contributed similarly to OA throughout the campaign. In contrast, the abundances of monoterpene oxidation products in the particle phase were greater during the cooler conditions in the latter half of the campaign (13 September–10 October), even though emissions of the precursors were lower, although the mechanism is not known. OA was correlated with the anthropogenic tracers 2-propyl nitrate and carbon monoxide (CO), consistent with previous observations, while being comprised of mostly non-fossil carbon (>75%). The correlation between OA and an anthropogenic tracer does not necessarily identify the source of the carbon as being anthropogenic but instead suggests a coupling between the anthropogenic and biogenic components in the air mass that might be related to the source of the oxidant and/or the aerosol sulfate. Observations of organosulfates of isoprene and α-pinene provided evidence for the likely importance of aerosol sulfate in spite of neutralized aerosol although acidic plumes might have played a role upwind of the site. This is in contrast to laboratory studies where strongly acidic seed aerosols were needed in order to form these compounds. These compounds together represented only a minor fraction (<1%) of the total OA mass, which may be the result of the neutralized aerosol at the site or because only a small number of organosulfates were quantified. The low contribution of organosulfates to total OA suggests that other mechanisms, e.g. NO_x enhancement of oxidant levels, are likely responsible for the majority of the anthropogenic enhancement of biogenic secondary organic aerosol observed at this site
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