24,786 research outputs found
No well-defined remnant Fermi surface in Sr2CuO2Cl2
In angle-resolved photoelectron spectra of the antiferromagnetic insulators
Ca2CuO2Cl2 and Sr2CuO2Cl2 a sharp drop of the spectral intensity of the
lowest-lying band is observed along a line in k space equivalent to the Fermi
surface of the optimally doped high-temperature superconductors. This was
interpreted as a signature of the existence of a remnant Fermi surface in the
insulating phase of the high-temperature superconductors. In this paper it is
shown that the drop of the spectral intensity is not related to the spectral
function but is a consequence of the electron-photon matrix elementComment: 4 pages, 3 figure
Three-photon resonant four-photon ionization of H_2 via the C^1 â_u state
Ab initio calculations are presented for the vibrational branching ratios in three-photon resonant four-photon ionization of H_2 via the C^1Î _u state. Energy and internuclear distance dependences of the boundfree electronic transition matrix element are explicitly included to estimate deviations from the Franck-Condon approximation. While our calculated branching ratios confirm certain important trends seen experimentally, some differences remain
Photoionization cross sections of rovibrational levels of the B^1ÎŁ^+_u state of H_2
We report theoretical cross sections for direct photoionization of specific rovibrational levels of the Bâ^1ÎŁ^+_u electronic state of H_2. The calculated cross sections differ considerably from values recently determined by resonant enhanced multiphoton ionization (REMPI) studies. In an attempt to understand the disagreement, we analyze in detail the REMPI dynamics and find that the multiphoton ionization probability is extremely sensitive to the spatial and temporal profiles of the laser pulses. Accurate characterization of laser profiles and their jitter is therefore necessary for a comparison between theory and experiment
Comment on 'Non-equilibrium thermodynamics of light absorption'
A recent paper by Meszéna and Westerhoff (1999 J. Phys. A: Math. Gen. 32 301) has aimed to address what is referred to as a principal question of biological thermodynamics, the possibility of describing photosynthesis in terms of non-equilibrium thermodynamics. The issue is associated with a misrepresentation of the fundamental photophysics involved, and as a result the analysis is invalid
(2+1) resonant enhanced multiphoton ionization of H_2 via the E, F^(1)ÎŁ^+_g state
In this paper, we report the results of ab initio calculations of photoelectron angular distributions and vibrational branching ratios for the (2+1) REMPI of H_2 via the E, F^(1)ÎŁ^+_g state, and compare these with the experimental data of Anderson et al. [Chem. Phys. Lett. 105, 22 (1984)]. These results show that the observed nonâFranckâCondon behavior is predominantly due to the R dependence of the transition matrix elements, and to a lesser degree to the energy dependence. This work presents the first molecular REMPI study employing a correlated wave function to describe the Rydbergâvalence mixing in the resonant intermediate state
Optical properties and electronic structure of ÎČâČâNiAl
The optical constants and their temperature derivatives have been determined for ÎČâČâNiAl from absorption and thermoreflectance measurements in the energy range of 0.2-4.4 eV. The results are interpreted using the self-consistent energy bands of Moruzzi, Williams, and Gelatt. By comparing a calculated joint density of states with Δ2, the imaginary part of the dielectric function, good overall agreement is found between theory and experiment. In contrast to earlier analyses, it is found that the 2.5-eV peak in Δ2 is primarily due to direct interband transitions terminating near the Fermi surface. This new interpretation of the 2.5-eV feature is discussed in relation to previously reported concentration effects and the rigid-band model
An Improved Approximate Consensus Algorithm in the Presence of Mobile Faults
This paper explores the problem of reaching approximate consensus in
synchronous point-to-point networks, where each pair of nodes is able to
communicate with each other directly and reliably. We consider the mobile
Byzantine fault model proposed by Garay '94 -- in the model, an omniscient
adversary can corrupt up to nodes in each round, and at the beginning of
each round, faults may "move" in the system (i.e., different sets of nodes may
become faulty in different rounds). Recent work by Bonomi et al. '16 proposed a
simple iterative approximate consensus algorithm which requires at least
nodes. This paper proposes a novel technique of using "confession" (a mechanism
to allow others to ignore past behavior) and a variant of reliable broadcast to
improve the fault-tolerance level. In particular, we present an approximate
consensus algorithm that requires only nodes, an
improvement over the state-of-the-art algorithms.
Moreover, we also show that the proposed algorithm is optimal within a family
of round-based algorithms
Mid-Infrared Ethane Emission on Neptune and Uranus
We report 8- to 13-micron spectral observations of Neptune and Uranus from
the NASA Infrared Telescope Facility spanning more than a decade. The
spectroscopic data indicate a steady increase in Neptune's mean atmospheric
12-micron ethane emission from 1985 to 2003, followed by a slight decrease in
2004. The simplest explanation for the intensity variation is an increase in
stratospheric effective temperature from 155 +/- 3 K in 1985 to 176 +/- 3 K in
2003 (an average rate of 1.2 K/year), and subsequent decrease to 165 +/- 3 K in
2004. We also detected variation of the overall spectral structure of the
ethane band, specifically an apparent absorption structure in the central
portion of the band; this structure arises from coarse spectral sampling
coupled with a non-uniform response function within the detector elements. We
also report a probable direct detection of ethane emission on Uranus. The
deduced peak mole fraction is approximately an order of magnitude higher than
previous upper limits for Uranus. The model fit suggests an effective
temperature of 114 +/- 3 K for the globally-averaged stratosphere of Uranus,
which is consistent with recent measurements indicative of seasonal variation.Comment: Accepted for publication in ApJ. 16 pages, 10 figures, 2 table
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