62 research outputs found
Hydrodynamic approach to coherent nuclear spin transport
We develop a linear response formalism for nuclear spin diffusion in a
dipolar coupled solid. The theory applies to the high-temperature,
long-wavelength regime studied in the recent experiments of Boutis et al.
[Phys. Rev. Lett. 92, 137201 (2004)], which provided direct measurement of
interspin energy diffusion in such a system. A systematic expansion of Kubo's
formula in the flip-flop term of the Hamiltonian is used to calculate the
diffusion coefficients. We show that this approach is equivalent to the method
of Lowe and Gade [Phys. Rev. 156, 817 (1967)] and Kaplan [Phys. Rev. B 2, 4578
(1970)], but has several calculational and conceptual advantages. Although the
lowest orders in this expansion agree with the experimental results for
magnetization diffusion, this is not the case for energy diffusion. Possible
reasons for this disparity are suggested.Comment: 7 pages, REVTeX4; Published Versio
Nuclear magnetic resonance probes for the Kondo scenario for the 0.7 feature in semiconductor quantum point contact devices
We propose a probe based on nuclear relaxation and Knight shift measurements
for the Kondo scenario for the "0.7 feature" in semiconductor quantum point
contact (QPC) devices. We show that the presence of a bound electron in the QPC
would lead to a much higher rate of nuclear relaxation compared to nuclear
relaxation through exchange of spin with conduction electrons. Furthermore, we
show that the temperature dependence of this nuclear relaxation is very
non-monotonic as opposed to the linear-T relaxation from coupling with
conduction electrons. We present a qualitative analysis for the additional
relaxation due to nuclear spin diffusion (NSD) and study the extent to which
NSD affects the range of validity of our method. The conclusion is that nuclear
relaxation, in combination with Knight shift measurements, can be used to
verify whether the 0.7 feature is indeed due to the presence of a bound
electron in the QPC.Comment: Published version. Appears in a Special Section on the 0.7 Feature
and Interactions in One-Dimensional Systems. 16 page
Dynamic nuclear polarization and spin-diffusion in non-conducting solids
There has been much renewed interest in dynamic nuclear polarization (DNP),
particularly in the context of solid state biomolecular NMR and more recently
dissolution DNP techniques for liquids. This paper reviews the role of spin
diffusion in polarizing nuclear spins and discusses the role of the spin
diffusion barrier, before going on to discuss some recent results.Comment: submitted to Applied Magnetic Resonance. The article should appear in
a special issue that is being published in connection with the DNP Symposium
help in Nottingham in August 200
Light-induced nuclear quadrupolar relaxation in semiconductors
Light excitation of a semiconductor, known to dynamically-polarize the
nuclear spins by hyperfine contact interaction with the photoelectrons, also
generates an intrinsic nuclear depolarization mechanism. This novel relaxation
process arises from the modulation of the nuclear quadrupolar Hamiltonian by
photoelectron trapping and recombination at nearby localized states. For nuclei
near shallow donors, the usual diffusion radius is replaced by a smaller,
quadrupolar, radius. If the light excitation conditions correspond to partial
donor occupation by photoelectrons, the nuclear magnetization and the nuclear
field can be decreased by more than one order of magnitude
High-sensitivity diamond magnetometer with nanoscale resolution
We present a novel approach to the detection of weak magnetic fields that
takes advantage of recently developed techniques for the coherent control of
solid-state electron spin quantum bits. Specifically, we investigate a magnetic
sensor based on Nitrogen-Vacancy centers in room-temperature diamond. We
discuss two important applications of this technique: a nanoscale magnetometer
that could potentially detect precession of single nuclear spins and an optical
magnetic field imager combining spatial resolution ranging from micrometers to
millimeters with a sensitivity approaching few femtotesla/Hz.Comment: 29 pages, 4 figure
Oscillations and waves in solar spicules
Since their discovery, spicules have attracted increased attention as energy/mass bridges between the dense and dynamic photosphere and the tenuous hot solar corona. Mechanical energy of photospheric random and coherent motions can be guided by magnetic field lines, spanning from the interior to the upper parts of the solar atmosphere, in the form of waves and oscillations. Since spicules are one of the most pronounced features of the chromosphere, the energy transport they participate in can be traced by the observations of their oscillatory motions. Oscillations in spicules have been observed for a long time. However the recent high-resolutions and high-cadence space and ground based facilities with superb spatial, temporal and spectral capacities brought new aspects in the research of spicule dynamics. Here we review the progress made in imaging and spectroscopic observations of waves and oscillations in spicules. The observations are accompanied by a discussion on theoretical modelling and interpretations of these oscillations. Finally, we embark on the recent developments made on the presence and role of Alfven and kink waves in spicules. We also address the extensive debate made on the Alfven versus kink waves in the context of the explanation of the observed transverse oscillations of spicule axes
Statistical Theory of Spin Relaxation and Diffusion in Solids
A comprehensive theoretical description is given for the spin relaxation and
diffusion in solids. The formulation is made in a general
statistical-mechanical way. The method of the nonequilibrium statistical
operator (NSO) developed by D. N. Zubarev is employed to analyze a relaxation
dynamics of a spin subsystem. Perturbation of this subsystem in solids may
produce a nonequilibrium state which is then relaxed to an equilibrium state
due to the interaction between the particles or with a thermal bath (lattice).
The generalized kinetic equations were derived previously for a system weakly
coupled to a thermal bath to elucidate the nature of transport and relaxation
processes. In this paper, these results are used to describe the relaxation and
diffusion of nuclear spins in solids. The aim is to formulate a successive and
coherent microscopic description of the nuclear magnetic relaxation and
diffusion in solids. The nuclear spin-lattice relaxation is considered and the
Gorter relation is derived. As an example, a theory of spin diffusion of the
nuclear magnetic moment in dilute alloys (like Cu-Mn) is developed. It is shown
that due to the dipolar interaction between host nuclear spins and impurity
spins, a nonuniform distribution in the host nuclear spin system will occur and
consequently the macroscopic relaxation time will be strongly determined by the
spin diffusion. The explicit expressions for the relaxation time in certain
physically relevant cases are given.Comment: 41 pages, 119 Refs. Corrected typos, added reference
The human DNA glycosylases NEIL1 and NEIL3 excise psoralen-induced DNA-DNA cross-links in a four-stranded DNA structure
Interstrand cross-links (ICLs) are highly cytotoxic DNA lesions that block DNA replication and transcription by preventing strand separation. Previously, we demonstrated that the bacterial and
human DNA glycosylases Nei and NEIL1 excise unhooked psoralen-derived ICLs in three-stranded DNA via hydrolysis of the glycosidic bond between the crosslinked base and deoxyribose sugar. Furthermore, NEIL3 from Xenopus laevis has been shown to cleave psoralen- and abasic site-induced ICLs in Xenopus
egg extracts. Here we report that human NEIL3 cleaves psoralen-induced DNA-DNA cross-links in three-stranded and four-stranded DNA substrates to generate unhooked DNA fragments containing
either an abasic site or a psoralen-thymine monoadduct. Furthermore, while Nei and NEIL1 also cleave a psoralen-induced four-stranded DNA substrate to generate two unhooked DNA duplexes with a nick, NEIL3 targets both DNA strands in the ICL without generating single-strand breaks. The DNA substrate specificities of these Nei-like enzymes imply the occurrence of long uninterrupted three- and four-stranded crosslinked DNA-DNA structures that may originate in vivo from DNA replication fork
bypass of an ICL. In conclusion, the Nei-like DNA glycosylases unhook psoralen-derived ICLs in various DNA structures via a genuine repair mechanism in which complex DNA lesions can be removed without generation of highly toxic double-strand breaks
Mesoporous Silica Nanoparticles Loaded with Surfactant: Low Temperature Magic Angle Spinning 13C and 29Si NMR Enhanced by Dynamic Nuclear Polarization
We show that dynamic nuclear polarization (DNP) can be used to enhance NMR signals of13C and 29Si nuclei located in mesoporous organic/inorganic hybrid materials, at several hundreds of nanometers from stable radicals (TOTAPOL) trapped in the surrounding frozen disordered water. The approach is demonstrated using mesoporous silica nanoparticles (MSN), functionalized with 3-(N-phenylureido)propyl (PUP) groups, filled with the surfactant cetyltrimethylammonium bromide (CTAB). The DNP-enhanced proton magnetization is transported into the mesopores via 1H–1H spin diffusion and transferred to rare spins by cross-polarization, yielding signal enhancements εon/off of around 8. When the CTAB molecules are extracted, so that the radicals can enter the mesopores, the enhancements increase to εon/off ≈ 30 for both nuclei. A quantitative analysis of the signal enhancements in MSN with and without surfactant is based on a one-dimensional proton spin diffusion model. The effect of solvent deuteration is also investigated
Adapting agriculture to climate change: a synopsis of Coordinated National Crop Wild Relative Seed Collecting Programs across five continents.
Na publicação: Marcelo B. Medeiros
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