561 research outputs found
Raman excitation spectroscopy of carbon nanotubes: effects of pressure medium and pressure
Raman excitation and emission spectra for the radial breathing mode (RBM) are
reported, together with a preliminary analysis. From the position of the peaks
on the two-dimensional plot of excitation resonance energy against Raman shift,
the chiral indices (m, n) for each peak are identified. Peaks shift from their
positions in air when different pressure media are added - water, hexane,
sulphuric acid - and when the nanotubes are unbundled in water with surfactant
and sonication. The shift is about 2 - 3 cm-1 in RBM frequency, but
unexpectedly large in resonance energy, being spread over up to 100meV for a
given peak. This contrasts with the effect of pressure. The shift of the peaks
of semiconducting nanotubes in water under pressure is orthogonal to the shift
from air to water. This permits the separation of the effects of the pressure
medium and the pressure, and will enable the true pressure coefficients of the
RBM and the other Raman peaks for each (m, n) to be established unambiguously.Comment: 6 pages, 3 Figures, Proceedings of EHPRG 2011 (Paris
Pressure coefficients of Raman modes of carbon nanotubes resolved by chirality: Environmental effect on graphene sheet
Studies of the mechanical properties of single-walled carbon nanotubes are
hindered by the availability only of ensembles of tubes with a range of
diameters. Tunable Raman excitation spectroscopy picks out identifiable tubes.
Under high pressure, the radial breathing mode shows a strong environmental
effect shown here to be largely independent of the nature of the environment .
For the G-mode, the pressure coefficient varies with diameter consistent with
the thick-wall tube model. However, results show an unexpectedly strong
environmental effect on the pressure coefficients. Reappraisal of data for
graphene and graphite gives the G-mode Grueuneisen parameter gamma = 1.34 and
the shear deformation parameter beta = 1.34.Comment: Submitted to Physical Review
Nonlinear Optics and Quantum Entanglement of Ultra-Slow Single Photons
Two light pulses propagating with ultra-slow group velocities in a coherently
prepared atomic gas exhibit dissipation-free nonlinear coupling of an
unprecedented strength. This enables a single-photon pulse to coherently
control or manipulate the quantum state of the other. Processes of this kind
result in generation of entangled states of radiation field and open up new
prospectives for quantum information processing
The Communities First (ComFi) study: protocol for a prospective controlled quasi-experimental study to evaluate the impact of area-wide regeneration on mental health and social cohesion in deprived communities
published_or_final_versio
The removal of thermally aged films of triacylglycerides by surfactant solutions
Thermal ageing of triacylglycerides (TAG) at high temperatures produces films which resist removal using aqueous surfactant solutions. We used a mass loss method to investigate the removal of thermally aged TAG films from hard surfaces using aqueous solutions of surfactants of different charge types. It was found that cationic surfactants are most effective at high pH, whereas anionics are most effective at low pH and a non-ionic surfactant is most effective at intermediate pH. We showed that the TAG film removal process occurs in several stages. In the first ‘‘lag phase’’ no TAG removal occurs; the surfactant first partitions into the thermally aged film. In the second stage, the TAG film containing surfactant was removed by solubilisation into micelles in the aqueous solution. The effects of pH and surfactant charge on the TAG removal process correlate with the effects of these variables on the extent of surfactant partitioning to the TAG film and on the maximum extent of TAG solubilisation within the micelles. Additionally, we showed how the TAG removal is enhanced by the addition of amphiphilic additives such as alcohols which act as co-surfactants. The study demonstrates that aqueous surfactant solutions provide a viable and more benign alternative to current methods for the removal of thermally aged TAG films
Enhancement of Magneto-Optic Effects via Large Atomic Coherence
We utilize the generation of large atomic coherence to enhance the resonant
nonlinear magneto-optic effect by several orders of magnitude, thereby
eliminating power broadening and improving the fundamental signal-to-noise
ratio. A proof-of-principle experiment is carried out in a dense vapor of Rb
atoms. Detailed numerical calculations are in good agreement with the
experimental results. Applications such as optical magnetometry or the search
for violations of parity and time reversal symmetry are feasible
Magnetic Field and Pressure Phase Diagrams of Uranium Heavy-Fermion Compound UZn
We have performed magnetization measurements at high magnetic fields of up to
53 T on single crystals of a uranium heavy-fermion compound UZn
grown by the Bridgman method. In the antiferromagnetic state below the N\'{e}el
temperature = 9.7 K, a metamagnetic transition is found at
32 T for the field along the [110] direction (-axis). The
magnetic phase diagram for the field along the [110] direction is
given. The magnetization curve shows a nonlinear increase at 35
T in the paramagnetic state above up to a characteristic
temperature where the magnetic susceptibility or
electrical resistivity shows a maximum value. This metamagnetic behavior of the
magnetization at is discussed in comparison with the metamagnetic
magnetism of the heavy-fermion superconductors UPt, URuSi, and
UPdAl. We have also carried out high-pressure resistivity measurement
on UZn using a diamond anvil cell up to 8.7 GPa. Noble gas argon was
used as a pressure-transmitting medium to ensure a good hydrostatic
environment. The N\'{e}el temperature is almost
pressure-independent up to 4.7 GPa and starts to increase in the
higher-pressure region. The pressure dependences of the coefficient of the
term in the electrical resistivity , the antiferromagnetic gap
, and the characteristic temperature are
discussed. It is found that the effect of pressure on the electronic states in
UZn is weak compared with those in the other heavy fermion
compounds
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