Étude de la corrosion du cuivre par microélectrochimie: Comparaison entre microélectrode et microcellule

Ce travail présente la comparaison de mesures électrochimiques réalisées à l'aide d'une microcellule et de microélectrodes conventionnelles. Des mesures de voltamétrie cyclique et d’impédances électrochimiques ont été réalisées sur des électrodes de cuivre pur, électrode classique couplée à des capillaires et microélectrodes, au potentiel de corrosion dans une solution NaCl 0,1 M, La comparaison entre ces deux types de mesure apporte des informations relatives à leurs sensibilités et limitations. En particulier, le domaine des basses fréquences du diagramme d’impédance est sensible à la géométrie de la microcellule ainsi qu'au positionnement relatif des électrodes

Ultrahigh Surface Area Three-Dimensional Porous Graphitic Carbon from Conjugated Polymeric Molecular Framework

Porous graphitic carbon is essential for many applications such as energy storage devices, catalysts, and sorbents. However, current graphitic carbons are limited by low conductivity, low surface area, and ineffective pore structure. Here we report a scalable synthesis of porous graphitic carbons using a conjugated polymeric molecular framework as precursor. The multivalent cross-linker and rigid conjugated framework help to maintain micro- and mesoporous structures, while promoting graphitization during carbonization and chemical activation. The above unique design results in a class of highly graphitic carbons at temperature as low as 800 ??C with record-high surface area (4073 m2 g-1), large pore volume (2.26 cm-3), and hierarchical pore architecture. Such carbons simultaneously exhibit electrical conductivity >3 times more than activated carbons, very high electrochemical activity at high mass loading, and high stability, as demonstrated by supercapacitors and lithium-sulfur batteries with excellent performance. Moreover, the synthesis can be readily tuned to make a broad range of graphitic carbons with desired structures and compositions for many applications.clos

Screening Methodology for the Efficient Pairing of Ionic Liquids and Carbonaceous Electrodes Applied to Electric Energy Storage

A model is presented that correlates the measured electric capacitance with the energy that comprises the desolvation, dissociation and adsorption energy of an ionic liquid into carbonaceous electrode (represented by single-wall carbon nanotubes). An original methodology is presented that allows for the calculation of the adsorption energy of ions in a host system that does not necessarily compensate the total charge of the adsorbed ions, leaving an overall net charge. To obtain overall negative (favorable) energies, adsorption energies need to overcome the energy cost for desolvation of the ion pair and its dissociation into individual ions. Smaller ions, such as BF4 −, generally show larger dissociation energies than anions such as PF6 − or TFSI−. Adsorption energies gradually increase with decreasing pore size of the CNT and show a maximum when the pore size is slightly greater than the dimensions of the adsorbed ion and the attractive van der Waals forces dominate the interaction. At smaller pore diameters, the adsorption energy sharply declines and becomes repulsive as a result of geometry deformations of the ion. Only for those diameters where the adsorption reaches maximum values is the adsorption energy sufficiently negative to balance the positive dissociation and desolvation energies. We present for each ion (and ionic liquid) what the most adequate electrode pore size should be for maximum capacitance

ETUDE ASYMPTOTIQUE DE LA PROPAGATION D'ONDES VISCOPLASTIQUES DANS UN ECHANTILLON DE LONGUEUR FINIE

Le problème étudié est voisin de celui qui est réellement rencontré dans un essai sur barres d'Hopkinson. L'idée directrice est d'évaluer le rôle que peut jouer une méthode asymptotique dans l'obtention d'une approximation systématique des contraintes dans l'échantillon.The problem at hand is close to that of wave propagation in a Hopkinson Pressure Bar test. The goal is to assess the efficiency of an asymptic method to obtain approximate values of stresses in the specimen in a systematic way