PCA of PCA: Principal Component Analysis of Partial Covering Absorption in NGC 1365

We analyse 400 ks of XMM-Newton data on the active galactic nucleus NGC 1365 using principal component analysis (PCA) to identify model independent spectral components. We find two significant components and demonstrate that they are qualitatively different from those found in MCG?6-30-15 using the same method. As the variability in NGC 1365 is known to be due to changes in the parameters of a partial covering neutral absorber, this shows that the same mechanism cannot be the driver of variability in MCG-6-30-15. By examining intervals where the spectrum shows relatively low absorption we separate the effects of intrinsic source variability, including signatures of relativistic reflection, from variations in the intervening absorption. We simulate the principal components produced by different physical variations, and show that PCA provides a clear distinction between absorption and reflection as the drivers of variability in AGN spectra. The simulations are shown to reproduce the PCA spectra of both NGC 1365 and MCG-6-30-15, and further demonstrate that the dominant cause of spectral variability in these two sources requires a qualitatively different mechanism.Comment: 8 pages, 10 figures. Accepted for publication in MNRA

EPR and pulsed ENDOR study of intermediates from reactions of aromatic azides with group 13 metal trichlorides

The reactions of group 13 metal trichlorides with aromatic azides were examined by CW EPR and pulsed ENDOR spectroscopies. Complex EPR spectra were obtained from reactions of aluminium, gallium and indium trichlorides with phenyl azides containing a variety of substituents. Analysis of the spectra showed that 4-methoxy-, 3-methoxy- and 2-methoxyphenyl azides all gave ‘dimer’ radical cations [ArNHC6H4NH2]+• and trimers [ArNHC6H4NHC6H4NH2]+• followed by polymers. 4-Azidobenzonitrile, with its electron-withdrawing substituent, did not react. In general the aromatic azides appeared to react most rapidly with AlCl3 but this reagent tended to generate much polymer. InCl3 was the least reactive group 13 halide. DFT computations of the radical cations provided corroborating evidence and suggested that the unpaired electrons were accommodated in extensive π-delocalised orbitals. A mechanism to account for the reductive conversion of aromatic azides to the corresponding anilines and thence to the dimers and trimers is proposedPublisher PDFPeer reviewe

A Program of Photometric Measurements of Solar Irradiance Fluctuations from Ground-based Observations

Photometric observations of the sun have been carried out at the San Fernando Observatory since early 1985. Since 1986, observations have been obtained at two wavelengths in order to separately measure the contributions of sunspots and bright facular to solar irradiance variations. Researchers believe that the contributions of sunspots can be measured to an accuracy of about plus or minus 30 ppm. The effect of faculae is much less certain, with uncertainties in the range of plus or minus 300 ppm. The larger uncertainty for faculae reflects both the greater difficulty in measuring the facular area, due to their lower contrast compared to sunspots, and the greater uncertainty in their contrast variation with viewing angle on the solar disk. Recent results from two separate photometric telescopes will be compared with bolometric observations from the active cavity radiometer irradiance monitor (ACRIM) that was on board the Solar Max satellite

Experimental investigation of non-uniform heating on flow boiling instabilities in a microchannels based heat sink

Two-phase flow boiling in microchannels is one of the most promising cooling technologies able to cope with high heat fluxes generated by the next generation of central processor units (CPU). If flow boiling is to be used as a thermal management method for high heat flux electronics it is necessary to understand the behaviour of a non-uniform heat distribution, which is typically the case observed in a real operating CPU. The work presented is an experimental study of two-phase boiling in a multi-channel silicon heat sink with non-uniform heating, using water as a cooling liquid. Thin nickel film sensors, integrated on the back side of the heat sinks were used in order to gain insight related to temperature fluctuations caused by two-phase flow instabilities under non-uniform heating. The effect of various hotspot locations on the temperature profile and pressure drop has been investigated, with hotspots located in different positions along the heat sink. It was observed that boiling inside microchannels with non-uniform heating led to high temperature non-uniformity in transverse direction

Disentangling the Complex Broadband X-ray Spectrum of IRAS 13197-1627 with NuSTAR, XMM-Newton and Suzaku

We present results from a coordinated $XMM$-$Newton$+$NuSTAR$ observation of the type 1.8 Seyfert galaxy IRAS 13197-1627. This is a highly complex source, with strong contributions from relativistic reflection from the inner accretion disk, neutral absorption and further reprocessing by more distant material, and ionised absorption from an outflow. We undertake a detailed spectral analysis combining the broadband coverage provided by $XMM$-$Newton$+$NuSTAR$ with a multi-epoch approach incorporating archival observations performed by $XMM$-$Newton$ and $Suzaku$. Our focus is on characterising the reflection from the inner accretion disk, which previous works have suggested may dominate the AGN emission, and constraining the black hole spin. Using lamppost disk reflection models, we find that the results for the inner disk are largely insensitive to assumptions regarding the geometry of the distant reprocessor and the precise form of the illuminating X-ray continuum. However, these results do depend on the treatment of the iron abundance of the distant absorber/reprocessor. The multi-epoch data favour a scenario in which the AGN is chemically homogeneous, and we find that a rapidly rotating black hole is preferred, with $a^* \geq 0.7$, but a slowly-rotating black hole is not strongly excluded. In addition to the results for the inner disk, we also find that both the neutral and ionised absorbers vary from epoch to epoch, implying that both have some degree of inhomogeneity in their structure.Comment: 15 pages, 7 figures, accepted for publication in MNRA

NuSTAR reveals the extreme properties of the super-Eddington accreting supermassive black hole in PG 1247+267

PG1247+267 is one of the most luminous known quasars at z ~ 2 and is a strongly super-Eddington accreting supermassive black hole (SMBH) candidate. We obtained NuSTAR data of this intriguing source in December 2014 with the aim of studying its high-energy emission, leveraging the broad band covered by the new NuSTAR and the archival XMM-Newton data. Several measurements are in agreement with the super-Eddington scenario for PG1247+267: the soft power law (Γ = 2.3 ± 0.1); the weak ionized Fe emission line; and a hint of the presence of outflowing ionized gas surrounding the SMBH. The presence of an extreme reflection component is instead at odds with the high accretion rate proposed for this quasar. This can be explained with three different scenarios; all of them are in good agreement with the existing data, but imply very different conclusions: i) a variable primary power law observed in a low state, superimposed on a reflection component echoing a past, higher flux state; ii) a power law continuum obscured by an ionized, Compton thick, partial covering absorber; and iii) a relativistic disk reflector in a lamp-post geometry, with low coronal height and high BH spin. The first model is able to explain the high reflection component in terms of variability. The second does not require any reflection to reproduce the hard emission, while a rather low high-energy cutoff of ~100 keV is detected for the first time in such a high redshift source. The third model require a face-on geometry, which may affect the SMBH mass and Eddington ratio measurements. Deeper X-ray broad-band data are required in order to distinguish between these possibilities