2,732 research outputs found

    Influence of shear stress applied during flow stoppage and rest period on the mechanical properties of thixotropic suspensions

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    We study the solid mechanical properties of several thixotropic suspensions as a function of the shear stress history applied during their flow stoppage and their aging in their solid state. We show that their elastic modulus and yield stress depend strongly on the shear stress applied during their solid-liquid transition (i.e., during flow stoppage) while applying the same stress only before or only after this transition may induce only second-order effects: there is negligible dependence of the mechanical properties on the preshear history and on the shear stress applied at rest. We also found that the suspensions age with a structuration rate that hardly depends on the stress history. We propose a physical sketch based on the freezing of a microstructure whose anisotropy depends on the stress applied during the liquid-solid transition to explain why the mechanical properties depend strongly on this stress. This sketch points out the role of the internal forces in the colloidal suspensions' behavior. We finally discuss briefly the macroscopic consequences of this phenomenon and show the importance of using a controlled-stress rheometer

    Reverse-selective diffusion in nanocomposite membranes

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    The permeability of certain polymer membranes with impenetrable nanoinclusions increases with the particle volume fraction (Merkel et al., Science, 296, 2002). This intriguing observation contradicts even qualitative expectations based on Maxwell's classical theory of conduction/diffusion in composites with homogeneous phases. This letter presents a simple theoretical interpretation based on classical models of diffusion and polymer physics. An essential feature of the theory is a polymer-segment depletion layer at the inclusion-polymer interface. The accompanying increase in free volume leads to a significant increase in the local penetrant diffusivity, which, in turn, increases the bulk permeability while exhibiting reverse selectivity. This model captures the observed dependence of the bulk permeability on the inclusion size and volume fraction, providing a straightforward connection between membrane microstructure and performance

    Micro-evaporators for kinetic exploration of phase diagrams

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    We use pervaporation-based microfluidic devices to concentrate species in aqueous solutions with spatial and temporal control of the process. Using experiments and modelling, we quantitatively describe the advection-diffusion behavior of the concentration field of various solutions (electrolytes, colloids, etc) and demonstrate the potential of these devices as universal tools for the kinetic exploration of the phases and textures that form upon concentration

    Integration through transients for Brownian particles under steady shear

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    Starting from the microscopic Smoluchowski equation for interacting Brownian particles under stationary shearing, exact expressions for shear-dependent steady-state averages, correlation and structure functions, and susceptibilities are obtained, which take the form of generalized Green-Kubo relations. They require integration of transient dynamics. Equations of motion with memory effects for transient density fluctuation functions are derived from the same microscopic starting point. We argue that the derived formal expressions provide useful starting points for approximations in order to describe the stationary non-equilibrium state of steadily sheared dense colloidal dispersions.Comment: 17 pages, Submitted to J. Phys.: Condens. Matter; revised version with minor correction

    Electric-field-induced displacement of a charged spherical colloid embedded in an elastic Brinkman medium

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    When an electric field is applied to an electrolyte-saturated polymer gel embedded with charged colloidal particles, the force that must be exerted by the hydrogel on each particle reflects a delicate balance of electrical, hydrodynamic and elastic stresses. This paper examines the displacement of a single charged spherical inclusion embedded in an uncharged hydrogel. We present numerically exact solutions of coupled electrokinetic transport and elastic-deformation equations, where the gel is treated as an incompressible, elastic Brinkman medium. This model problem demonstrates how the displacement depends on the particle size and charge, the electrolyte ionic strength, and Young's modulus of the polymer skeleton. The numerics are verified, in part, with an analytical (boundary-layer) theory valid when the Debye length is much smaller than the particle radius. Further, we identify a close connection between the displacement when a colloid is immobilized in a gel and its velocity when dispersed in a Newtonian electrolyte. Finally, we describe an experiment where nanometer-scale displacements might be accurately measured using back-focal-plane interferometry. The purpose of such an experiment is to probe physicochemical and rheological characteristics of hydrogel composites, possibly during gelation

    Universal reduction of pressure between charged surfaces by long-wavelength surface charge modulation

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    We predict theoretically that long-wavelength surface charge modulations universally reduce the pressure between the charged surfaces with counterions compared with the case of uniformly charged surfaces with the same average surface charge density. The physical origin of this effect is the fact that surface charge modulations always lead to enhanced counterion localization near the surfaces, and hence, fewer charges at the midplane. We confirm the last prediction with Monte Carlo simulations.Comment: 8 pages 1 figure, Europhys. Lett., in pres

    Very Low Mass Stars and Brown Dwarfs in Taurus-Auriga

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    We present high resolution optical spectra obtained with the HIRES spectrograph on the Keck I telescope of low mass T Tauri stars and brown dwarfs (LMTTs) in Taurus-Auriga. Of particular interest is the previously classified "continuum T Tauri star" GM Tau, which has a spectral type of M6.5 and a mass just below the stellar/substellar boundary. None of the LMTTs in Taurus are rapidly rotating (vsini < 30 km/s), unlike low mass objects in Orion. Many of the slowly rotating, non-accreting stars and brown dwarfs exhibit prominent H-alpha emission (EWs of 3 - 36 A), indicative of active chromospheres. We demonstrate empirically that the full-width at 10% of the H-alpha emission profile peak is a more practical and possibly more accurate indicator of accretion than either the equivalent width of H-alpha or optical veiling: 10%-widths > 270 km/s are classical T Tauri stars (i.e. accreting), independent of stellar spectral type. Although LMTTs can have accretion rates comparable to that of more typical, higher-mass T Tauri stars (e.g. K7-M0), the average mass accretion rate appears to decrease with decreasing mass. The diminished frequency of accretion disks for LMTTs, in conjunction with their lower, on average, mass accretion rates, implies that they are formed with less massive disks than higher-mass T Tauri stars. The radial velocities, circumstellar properties and known binaries do not support the suggestion that many of the lowest mass members of Taurus have been ejected from higher stellar density regions within the cloud. Instead, LMTTs appear to have formed and are evolving in the same way as higher-mass T Tauri stars, but with smaller disks and shorter disk lifetimes.Comment: 27 pages, plus 8 figures, accepted for publication in Ap

    Simulation of Claylike Colloids

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    We investigate properties of dense suspensions and sediments of small spherical silt particles by means of a combined Molecular Dynamics (MD) and Stochastic Rotation Dynamics (SRD) simulation. We include van der Waals and effective electrostatic interactions between the colloidal particles, as well as Brownian motion and hydrodynamic interactions which are calculated in the SRD-part. We present the simulation technique and first results. We have measured velocity distributions, diffusion coefficients, sedimentation velocity, spatial correlation functions and we have explored the phase diagram depending on the parameters of the potentials and on the volume fraction.Comment: 20 pages, 14 figure
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