The Electrochemical Oxidation of Substituted Catechols

The oxidation of substituted catechols was studied by cyclic voltammetry, chronoamperometry, rotating ring‐disk electrode, and coulometry. The results showed that the quinones that were formed from the oxidation of substituted catechols reacted with the basic forms of the starting material to yield the dimeric product. These products were generally unstable and rapidly polymerized or underwent some other irreversible reaction to form an electroinactive product. For 3,4‐dihydroxyacetophenone and propriophenone, the intermediate was stable long enough to be observed in cyclic voltammetry. The rate of the coupling reaction was found to correlate well with the Hammett ρ‐σ parameters and indicated that there was substantial negative charge in the transition state. Finally, an analysis of the coulometric n‐values along with the iat1/2/C values indicated that the initial coupling product was a diphenyl ether. Analysis of the coulometry products showed extensive polymerization

Quantum phase transition in an atomic Bose gas near a Feshbach resonance

We study the quantum phase transition in an atomic Bose gas near a Feshbach resonance in terms of the renormalization group. This quantum phase transition is characterized by an Ising order parameter. We show that in the low temperature regime where the quantum fluctuations dominate the low-energy physics this phase transition is of first order because of the coupling between the Ising order parameter and the Goldstone mode existing in the bosonic superfluid. However, when the thermal fluctuations become important, the phase transition turns into the second order one, which belongs to the three-dimensional Ising universality class. We also calculate the damping rate of the collective mode in the phase with only a molecular Bose-Einstein condensate near the second-order transition line, which can serve as an experimental signature of the second-order transition.Comment: 8 pages, 2 figures, published version in Phys. Rev.

Absorption cross section in warped AdS_3 black hole revisited

We investigate the absorption cross section for minimal-coupled scalars in the warped AdS_3 black hole. According to our calculation, the cross section reduces to the horizon area in the low energy limit as usually expected in contrast to what was previously found. We also calculate the greybody factor and find that the effective temperatures for the two chiral CFT's are consistent with that derived from the quasinormal modes. Observing the conjectured warped AdS/CFT correspondence, we suspect that a specific sector of the CFT operators with the desired conformal dimension could be responsible for the peculiar thermal behaviour of the warped AdS_3 black hole.Comment: 16+1 pages, typos corrected, references and footnotes adde

Low-energy Effective Theory for One-dimensional Lattice Bosons near Integer Filling

A low-energy effective theory for interacting bosons on a one-dimensional lattice at and near integer fillings is proposed. It is found that two sets of bosonic phase fields are necessary in order to explain the complete phase diagram. Using the present effective theory, the nature of the quantum phase transitions among various phases can be identified. Moreover, the general condition for the appearance of the recently proposed Pfaffian-like state can be realized from our effective action.Comment: 6 pages, 2 figures, 1 tabl

Wafer-Level Parylene Packaging With Integrated RF Electronics for Wireless Retinal Prostheses

This paper presents an embedded chip integration technology that incorporates silicon housings and flexible Parylene-based microelectromechanical systems (MEMS) devices. Accelerated-lifetime soak testing is performed in saline at elevated temperatures to study the packaging performance of Parylene C thin films. Experimental results show that the silicon chip under test is well protected by Parylene, and the lifetime of Parylenecoated metal at body temperature (37°C) is more than 60 years, indicating that Parylene C is an excellent structural and packaging material for biomedical applications. To demonstrate the proposed packaging technology, a flexible MEMS radio-frequency (RF) coil has been integrated with an RF identification (RFID) circuit die. The coil has an inductance of 16 μH with two layers of metal completely encapsulated in Parylene C, which is microfabricated using a Parylene–metal–Parylene thin-film technology. The chip is a commercially available read-only RFID chip with a typical operating frequency of 125 kHz. The functionality of the embedded chip has been tested using an RFID reader module in both air and saline, demonstrating successful power and data transmission through the MEMS coil

SU(3) symmetry breaking in decay constants and electromagnetic properties of pseudoscalar heavy mesons

In this paper, the decay constants and mean square radii of pseudoscalar heavy mesons are studied in the SU(3) symmetry breaking. Within the light-front framework, the ratios $f_{D_s}/f_D$ and $f_{B_s}/f_B$ are individually estimated using the hyperfine splittings in the $D_{(s)}^*-D_{(s)}$ and $B_{(s)}^*-B_{(s)}$ states and the light quark masses, $m_{s,q}$ ($q=u,d$), to extract the wave function parameter $\beta$. The values $f_{D_s}/f_D= 1.29\pm0.07$ and $f_{B_s}/f_B= 1.32\pm 0.08$ are obtained, which are not only chiefly determined by the ratio of light quark masses $m_s/m_q$, but also insensitive to the heavy quark masses $m_{c,b}$ and the decay constants $f_{D,B}$. The dependence of $f_{B_c}/f_B$ on $\Delta M_{B_cB^*_c}$ with the varied charm quark masses is also shown. In addition, the mean square radii are estimated as well. The values $\sqrt{} =0.740^{-0.041}_{+0.050}$ and $\sqrt{} =0.711^{-0.049}_{+0.058}$ are obtained, and the sensitivities of $$ on the heavy and light quark masses are similar to those of the decay constants.Comment: 21 pages, 5 figures, 4 tables, some typos are corrected, version to be published in Phys. Rev.

Landau-Zener-Stuckelberg interference in a multi-anticrossing system

We propose a universal analytical method to study the dynamics of a multi-anticrossing system subject to driving by one single large-amplitude triangle pulse, within its time scales smaller than the dephasing time. Our approach can explain the main features of the Landau-Zener-Stuckelberg interference patterns recently observed in a tripartite system [Nature Communications 1:51 (2010)]. In particular, we focus on the effects of the size of anticrossings on interference and compare the calculated interference patterns with numerical simulations. In addition, Fourier transform of the patterns can extract information on the energy level spectrum.Comment: 6 pages, 5 figure

CR3 and Dectin-1 Collaborate in Macrophage Cytokine Response through Association on Lipid Rafts and Activation of Syk-JNK-AP-1 Pathway

Copyright: © 2015 Huang et al. This is an open access article distributed under the terms of the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original author and source are credited Acknowledgments We are grateful to the Second Core Laboratory of Research Core Facility at the National Taiwan University Hospital for confocal microscopy service and providing ultracentrifuge. We thank Dr. William E. Goldman (University of North Carolina, Chapel Hill, NC) for kindly providing WT and ags1-null mutant of H. capsulatum G186A. Funding: This work is supported by research grants 101-2320-B-002-030-MY3 from the Ministry of Science and Technology (http://www.most.gov.tw) and AS-101-TP-B06-3 from Academia Sinica (http://www.sinica.edu.tw) to BAWH. GDB is funded by research grant 102705 from Welcome Trust (http://www.wellcome.ac.uk). The funders had no role in study design, data collection and analysis, decision to publish, or preparation of the manuscript.Peer reviewedPublisher PD

Effective continuous model for surface states and thin films of three dimensional topological insulators

Two-dimensional effective continuous models are derived for the surface states and thin films of the three-dimensional topological insulator (3DTI). Starting from an effective model for 3DTI based on the first principles calculation [Zhang \emph{et al}, Nat. Phys. 5, 438 (2009)], we present solutions for both the surface states in a semi-infinite boundary condition and in the thin film with finite thickness. An effective continuous model was derived for surface states and the thin film 3DTI. The coupling between opposite topological surfaces and structure inversion asymmetry (SIA) give rise to gapped Dirac hyperbolas with Rashba-like splittings in energy spectrum. Besides, the SIA leads to asymmetric distributions of wavefunctions along the film growth direction, making some branches in the energy spectra much harder than others to be probed by light. These features agree well with the recent angle-resolved photoemission spectra of Bi$_{2}$Se $_{3}$ films grown on SiC substrate [Zhang et al, arXiv: 0911.3706]. More importantly, we use the effective model to fit the experimental data and determine the model parameters. The result indicates that the thin film Bi$_{2}$Se$_{3}$ lies in quantum spin Hall region based on the calculation of the Chern number and the $Z_{2}$ invariant. In addition, strong SIA always intends to destroy the quantum spin Hall state.Comment: 12 pages, 7 figures, references are update

Flexural behavior of web elements with openings

INTRODUCTION The purpose of this phase of the research has been to investigate the flexural behavior of C-shaped members with web openings. Three common industry standard C-sections were tested as outlined in the first progress report. The web openings were located at 24 inches on center as illustrated in Fig. 1. Each test specimen was subjected to two point loads until the ultimate flexural strength of the member was obtained. This report summarizes the test procedure and results of the research to date