Electrochemical Investigation of Phenethylammonium Bismuth Iodide as Anode in Aqueous Zn2+ Electrolytes

Despite the high potential impact of aqueous battery systems, fundamental characteristics such as cost, safety, and stability make them less feasible for large-scale energy storage systems. One of the main barriers encountered in the commercialization of aqueous batteries is the development of large-scale electrodes with high reversibility, high rate capability, and extended cycle stability at low operational and maintenance costs. To overcome some of these issues, the current research work is focused on a new class of material based on phenethylammonium bismuth iodide on fluorine doped SnO2-precoated glass substrate via aerosol-assisted chemical vapor deposition, a technology that is industrially competitive. The anode materials were electrochemically investigated in Zn2+ aqueous electrolytes as a proof of concept, which presented a specific capacity of 220 mAh g−1 at 0.4 A g−1 with excellent stability after 50 scans and capacity retention of almost 100%

Electrochemical Properties of APCVD alpha-Fe2O3 Nanoparticles at 300 degrees C

The growth of hematite (FeIII oxide) by atmospheric pressure chemical vapor deposition was possible at 300 oC by controlling the nitrogen flow rate through the iron precursor bubbler. An increase of crystallinity along with the presence of compact interconnected nanoparticles was observed upon increasing the nitrogen flow rate. The amount of incorporated charge was the highest for the 0.6 L min−1 coating presenting reversibility after a period of 1400 s as obtained from chronoamperometry measurements. Additionally, the charge transfer of lithium‐ions across the FeIII oxide / electrolyte interface was easier enhancing its performance presenting capacitance retention of 94 % after 500 scans. The importance of nitrogen flow rate towards the deposition of an anode with good stability and effective electrochemical behavior is highlighted

Hydrothermal Growth of MnO2 at 95 oC as an Anode Material

The hydrothermal growth of manganese dioxide was carried out on indium tin dioxide coated glass substrates using potassium permanganate at 95 oC for 24 h and adjusting the pH solution to 3 and 4 through nitric acid. The best capacitive response was observed from the hexagonal ε-manganese dioxide at pH 4 having a specific charge of 129 ± 1 A g-1 and specific discharge capacity of 943 mAh g-1 with capacitance retention of 98 % after 500 scans at 4 A g-1 presenting high rate performance and good stability. The importance of achieving crystalline electrodes with high specific surface area towards the improvement of their capacitive performance for power devices is highlighted

V2O5 as magnesium cathode material with extended cyclic stability

In this work, the electrochemical performance of aerosol-assisted chemical vapour deposited vanadium pentoxide cathodes at 600 °C, is presented. The as-grown oxides indicate specific discharge capacity of 300 mA h g-1 with capacity retention of 92 % after 10000 scans, coulombic efficiency of 100 %, noble structural stability and high reversibility. The present study shows the possibility to grow large-area magnesium cathode material with extended cycle stability via utilization of an aqueous electrolyte under a corrosive environment. This enhanced performance may be a combination of electrode morphology and adherence, when compared to previous work employing electrode growth temperature at 500 °C

Towards High Performance Chemical Vapour Deposition V2O5 Cathodes for Batteries Employing Aqueous Media

The need for clean and efficient energy storage has become the center of attention due to the eminent global energy crisis and growing ecological concerns. A key component in this effort is the ultra-high performance battery, which will play a major role in the energy industry. To meet the demands in portable electronic devices, electric vehicles, and large-scale energy storage systems, it is necessary to prepare advanced batteries with high safety, fast charge ratios, and discharge capabilities at a low cost. Cathode materials play a significant role in determining the performance of batteries. Among the possible electrode materials is vanadium pentoxide, which will be discussed in this review, due to its low cost and high theoretical capacity. Additionally, aqueous electrolytes, which are environmentally safe, provide an alternative approach compared to organic media for safe, cost-effective, and scalable energy storage. In this review, we will reveal the industrial potential of competitive methods to grow cathodes with excellent stability and enhanced electrochemical performance in aqueous media and lay the foundation for the large-scale production of electrode materials

Aerosol-assisted chemical vapor deposition of V2O5 cathodes with high rate capabilities for magnesium-ion batteries

The growth of orthorhombic vanadium pentoxide nanostructures was accomplished using an aerosol-assisted chemical vapor deposition process. These materials showed excellent electrochemical performance for magnesium-ion storage in an aqueous electrolyte; showing specific discharge capacities of up to 427 mAh g−1 with a capacity retention of 82% after 2000 scans under a high specific current of 5.9 A g−1. The high rate capability suggested good structural stability and high reversibility. We believe the development of low-cost and large-area coating methods, such as the technique used herein, will be essential for the upscalable fabrication of next-generation rechargeable battery technologies

One pot direct hydrothermal growth of photoactive TiO2 films on glass

We demonstrate that titanium (IV) oxide films may be deposited on Corning glass by a simple, one-pot, low temperature (95 ◦C) hydrothermal growth technique and that providing the correct conditions are employed, the films produced show clear photoactivity under UV illumination as evidenced by changes in water contact angle and the progressive photo-oxidation of stearic acid. It is further demonstrated that the growth, structure and photoactivity of the films depends critically upon the H2O concentration employed during growth. For H2O concentrations below 0.1 M, little or no growth was observed, while above 0.3 M, precipitation or even gelation rapidly occurred. Only at H2O concentrations of 0.1M and 0.2Mwas appreciable film growth observed, while photoactive titaniawas formed only via growth using a water concentration of 0.1M, the films grown using the higher concentration of water (0.2M) being essentially photo-inactive. The method developed is discussed in terms of the possible chemical steps involved and is proposed as a low-cost alternative to higher temperature, less environmentally friendly approaches to TiO2 film production