Factors Influencing the Mode I Interlaminar Fracture Toughness of a Rubber Toughened Thermoplastic Matrix Composite

The use of a rubber modified thermoplastic resin has been investigated as a method to improve the Mode I interlaminar fracture toughness of a unidirectional con tinuous carbon fiber composite Test results show that the improvement in the fracture toughness is less than expected due to rubber particle agglomeration, solvent and molding induced crystallization of the matrix and poor fiber/matrix adhesion The plastic zone in composites utilizing tough matrices can extend well beyond a single interfibrillar spacing However, the development of the plastic zone is limited due to the failure of the fiber/ matrix interface. In order to fully evaluate the potential of tough composites using toughened matrices, any improvement made in the matrix toughness must be coupled with improvements in the fiber/matrix adhesion.Peer Reviewedhttp://deepblue.lib.umich.edu/bitstream/2027.42/68684/2/10.1177_089270578900200101.pd

Chemical aging of m-xylene secondary organic aerosol: laboratory chamber study

Secondary organic aerosol (SOA) can reside in the atmosphere for a week or more. While its initial formation from the gas-phase oxidation of volatile organic compounds tends to take place in the first few hours after emission, SOA can continue to evolve chemically over its atmospheric lifetime. Simulating this chemical aging over an extended time in the laboratory has proven to be challenging. We present here a procedure for studying SOA aging in laboratory chambers that is applied to achieve 36 h of oxidation. The formation and evolution of SOA from the photooxidation of m-xylene under low-NO_x conditions and in the presence of either neutral or acidic seed particles is studied. In SOA aging, increasing molecular functionalization leads to less volatile products and an increase in SOA mass, whereas gas- or particle-phase fragmentation chemistry results in more volatile products and a loss of SOA. The challenge is to discern from measured chamber variables the extent to which these processes are important for a given SOA system. In the experiments conducted, m-xylene SOA mass, calculated under the assumption of size-invariant particle composition, increased over the initial 12–13 h of photooxidation and decreased beyond that time, suggesting the existence of fragmentation chemistry. The oxidation of the SOA, as manifested in the O:C elemental ratio and fraction of organic ion detected at m/z 44 measured by the Aerodyne aerosol mass spectrometer, increased continuously starting after 5 h of irradiation until the 36 h termination. This behavior is consistent with an initial period in which, as the mass of SOA increases, products of higher volatility partition to the aerosol phase, followed by an aging period in which gas- and particle-phase reaction products become increasingly more oxidized. When irradiation is stopped 12.4 h into one experiment, and OH generation ceases, minimal loss of SOA is observed, indicating that the loss of SOA is either light- or OH-induced. Chemical ionization mass spectrometry measurements of low-volatility m-xylene oxidation products exhibit behavior indicative of continuous photooxidation chemistry. A condensed chemical mechanism of m-xylene oxidation under low-NO_x conditions is capable of reproducing the general behavior of gas-phase evolution observed here. Moreover, order of magnitude analysis of the mechanism suggests that gas-phase OH reaction of low volatility SOA precursors is the dominant pathway of aging in the m-xylene system although OH reaction with particle surfaces cannot be ruled out. Finally, the effect of size-dependent particle composition and size-dependent particle wall loss rates on different particle wall loss correction methods is discussed

Ultrafast spectroscopy of propagating coherent acoustic phonons in GaN/InGaN heterostructures

We show that large amplitude, coherent acoustic phonon wavepackets can be generated and detected in In$_x$Ga$_{1-x}$N/GaN epilayers and heterostructures in femtosecond pump-probe differential reflectivity experiments. The amplitude of the coherent phonon increases with increasing Indium fraction $x$ and unlike other coherent phonon oscillations, both \textit{amplitude} and \textit{period} are strong functions of the laser probe energy. The amplitude of the oscillation is substantially and almost instantaneously reduced when the wavepacket reaches a GaN-sapphire interface below the surface indicating that the phonon wavepackets are useful for imaging below the surface. A theoretical model is proposed which fits the experiments well and helps to deduce the strength of the phonon wavepackets. Our model shows that localized coherent phonon wavepackets are generated by the femtosecond pump laser in the epilayer near the surface. The wavepackets then propagate through a GaN layer changing the local index of refraction, primarily through the Franz-Keldysh effect, and as a result, modulate the reflectivity of the probe beam. Our model correctly predicts the experimental dependence on probe-wavelength as well as epilayer thickness.Comment: 11 pages, 14 figure

Density fluctuations in κ\kappa-deformed inflationary universe

We study the spectrum of metric fluctuation in $\kappa$-deformed inflationary universe. We write the theory of scalar metric fluctuations in the $\kappa-$deformed Robertson-Walker space, which is represented as a non-local theory in the conventional Robertson-Walker space. One important consequence of the deformation is that the mode generation time is naturally determined by the structure of the $\kappa-$deformation. We expand the non-local action in $H^2/\kappa^2$, with $H$ being the Hubble parameter and $\kappa$ the deformation parameter, and then compute the power spectra of scalar metric fluctuations both for the cases of exponential and power law inflations up to the first order in $H^2/\kappa^2$. We show that the power spectra of the metric fluctuation have non-trivial corrections on the time dependence and on the momentum dependence compared to the commutative space results. Especially for the power law inflation case, the power spectrum for UV modes is weakly blue shifted early in the inflation and its strength decreases in time. The power spectrum of far-IR modes has cutoff proportional to $k^3$ which may explain the low CMB quadrupole moment.Comment: final revision; 19 pages, 3 figures; to appear in Phys. Rev.

Transformation of stimulus correlations by the retina

Redundancies and correlations in the responses of sensory neurons seem to waste neural resources but can carry cues about structured stimuli and may help the brain to correct for response errors. To assess how the retina negotiates this tradeoff, we measured simultaneous responses from populations of ganglion cells presented with natural and artificial stimuli that varied greatly in correlation structure. We found that pairwise correlations in the retinal output remained similar across stimuli with widely different spatio-temporal correlations including white noise and natural movies. Meanwhile, purely spatial correlations tended to increase correlations in the retinal response. Responding to more correlated stimuli, ganglion cells had faster temporal kernels and tended to have stronger surrounds. These properties of individual cells, along with gain changes that opposed changes in effective contrast at the ganglion cell input, largely explained the similarity of pairwise correlations across stimuli where receptive field measurements were possible.Comment: author list corrected in metadat

Multiwavelength Mass Comparisons of the z~0.3 CNOC Cluster Sample

Results are presented from a detailed analysis of optical and X-ray observations of moderate-redshift galaxy clusters from the Canadian Network for Observational Cosmology (CNOC) subsample of the EMSS. The combination of extensive optical and deep X-ray observations of these clusters make them ideal candidates for multiwavelength mass comparison studies. X-ray surface brightness profiles of 14 clusters with 0.17<z<0.55 are constructed from Chandra observations and fit to single and double beta-models. Spatially resolved temperature analysis is performed, indicating that five of the clusters in this sample exhibit temperature gradients within their inner 60-200 kpc. Integrated spectra extracted within R_2500 provide temperature, abundance, and luminosity information. Under assumptions of hydrostatic equilibrium and spherical symmetry, we derive gas and total masses within R_2500 and R_200. We find an average gas mass fraction within R_200 of 0.136 +/- 0.004, resulting in Omega_m=0.28 +/- 0.01 (formal error). We also derive dynamical masses for these clusters to R_200. We find no systematic bias between X-ray and dynamical methods across the sample, with an average M(dyn)/M(X-ray) = 0.97 +/- 0.05. We also compare X-ray masses to weak lensing mass estimates of a subset of our sample, resulting in a weighted average of M(lens)/M(X-ray) of 0.99 +/- 0.07. We investigate X-ray scaling relationships and find powerlaw slopes which are slightly steeper than the predictions of self-similar models, with an E(z)^(-1) Lx-Tx slope of 2.4 +/- 0.2 and an E(z) M_2500-Tx slope of 1.7 +/- 0.1. Relationships between red-sequence optical richness (B_gc,red) and global cluster X-ray properties (Tx, Lx and M_2500) are also examined and fitted.Comment: Astrophysical Journal, 48 pages, 11 figures, LaTeX. Added correction to surface brightness normalization of MS1512.4+3647, corrections to sample gas mass fractions and calculated value of Omega_m. Figure resolution has been reduced to comply with astro-ph upload requirement