Exact solution of the Percus-Yevick integral equation for fluid mixtures of hard hyperspheres

Structural and thermodynamic properties of multicomponent hard-sphere fluids at odd dimensions have recently been derived in the framework of the rational function approximation (RFA) [Rohrmann and Santos, Phys. Rev. E \textbf{83}, 011201 (2011)]. It is demonstrated here that the RFA technique yields the exact solution of the Percus-Yevick (PY) closure to the Ornstein-Zernike (OZ) equation for binary mixtures at arbitrary odd dimensions. The proof relies mainly on the Fourier transforms $\hat{c}_{ij}(k)$ of the direct correlation functions defined by the OZ relation. From the analysis of the poles of $\hat{c}_{ij}(k)$ we show that the direct correlation functions evaluated by the RFA method vanish outside the hard core, as required by the PY theory.Comment: 6 page

Equation of state of sticky-hard-sphere fluids in the chemical-potential route

The coupling-parameter method, whereby an extra particle is progressively coupled to the rest of the particles, is applied to the sticky-hard-sphere fluid to obtain its equation of state in the so-called chemical-potential route ($\mu$ route). As a consistency test, the results for one-dimensional sticky particles are shown to be exact. Results corresponding to the three-dimensional case (Baxter's model) are derived within the Percus-Yevick approximation by using different prescriptions for the dependence of the interaction potential of the extra particle on the coupling parameter. The critical point and the coexistence curve of the gas-liquid phase transition are obtained in the $\mu$ route and compared with predictions from other thermodynamics routes and from computer simulations. The results show that the $\mu$ route yields a general better description than the virial, energy, compressibility, and zero-separation routes.Comment: 13 pages, 7 figures; v2: Results from the zero-separation route have been adde

Chemical-potential route for multicomponent fluids

The chemical potentials of multicomponent fluids are derived in terms of the pair correlation functions for arbitrary number of components, interaction potentials, and dimensionality. The formally exact result is particularized to hard-sphere mixtures with zero or positive nonadditivity. As a simple application, the chemical potentials of three-dimensional additive hard-sphere mixtures are derived from the Percus-Yevick theory and the associated equation of state is obtained. This Percus-Yevick chemical-route equation of state is shown to be more accurate than the virial equation of state. An interpolation between the chemical-potential and compressibility routes exhibits a better performance than the well-known Boubl\'ik-Mansoori-Carnahan-Starling-Leland equation of state.Comment: 9 pages, 1 figure; v2: minor change

Hydrogen model atmospheres for white dwarf stars

We present a detailed calculation of model atmospheres for DA white dwarfs. Our atmosphere code solves the atmosphere structure in local thermodynamic equilibrium with a standard partial linearization technique, which takes into account the energy transfer by radiation and convection. This code incorporates recent improved and extended data base of collision induced absorption by molecular hydrogen. We analyse the thermodynamic structure and emergent flux of atmospheres in a range 2500 < Teff < 60000$ K and 6.5 < log g < 9.0. Bolometric correction and colour indices are provided for a subsample of the model grid. Comparison of the colours is made with published observational material and results of other recent model calculations. Motivated by the increasing interest on helium core white dwarfs, we analyse the photometric characteristics of these stars during their cooling, using evolutionary models recently available. Effective temperatures, surface gravities, masses and ages have been determined for some helium core white dwarf candidates, and their possible binary nature is briefly discussed.Comment: 12 pages, 13 figures. Accepted for publication in MNRA

Equation of state for five-dimensional hyperspheres from the chemical-potential route

We use the Percus-Yevick approach in the chemical-potential route to evaluate the equation of state of hard hyperspheres in five dimensions. The evaluation requires the derivation of an analytical expression for the contact value of the pair distribution function between particles of the bulk fluid and a solute particle with arbitrary size. The equation of state is compared with those obtained from the conventional virial and compressibility thermodynamic routes and the associated virial coefficients are computed. The pressure calculated from all routes is exact up to third density order, but it deviates with respect to simulation data as density increases, the compressibility and the chemical-potential routes exhibiting smaller deviations than the virial route. Accurate linear interpolations between the compressibility route and either the chemical-potential route or the virial one are constructed.Comment: 9 pages, 6 figures; v2: Change in one referenc

Evolution and colours of helium-core white dwarf stars: the case of low metallicity progenitors

The present work is designed to explore the evolution of helium-core white dwarf (HeWD) stars for the case of metallicities much lower than the solar one (Z=0.001 and Z=0.0002). Evolution is followed in a self-consistent way with the predictions of detalied and new non-grey atmospheres, time-dependent element diffusion and the history of the white dwarf progenitor. Reliable initial models for low mass HeWDs are obtained by applying mass loss rates to a 1msun stellar model. The loss of angular momentum caused by gravitational wave emission and magnetic stellar wind braking are considered. Model atmospheres, based on a detailed treatment of the microphysics entering the WD atmosphere enable us to provide accurate colours and magnitudes at both early and advanced evolutionary stages. We find that most of our evolutionary sequences experience several episodes of hydrogen thermonuclear flashes. In particular, the lower the metallicity, the larger the minimum stellar mass for the occurrence fo flashes induced by CNO cycle reactions. The existence of a mass-threshold for the occurrence of diffusion-induced CNO flashes leadss to a marked dichotomy in the age of our models. Another finding of this study is that our HeWD models experience unstable hydrogen burning via PP nuclear reactions at late cooling stages as a result of hydrogen chemically diffusing inwards. Such PP flashes take place in models with very low metal content. We also find that models experiencing CNO flashes exhibit a pronouncede turn-off in most of their colours at M_V=16 approximately. Finally, colour-magnitude diagrams for our models are presented and compared with recent observational data of HeWD candidates in the globular clusters NGC 6397 and 47 Tucanae.Comment: 14 pages, 10 figures. Accepted for publication in MNRA

Lyman-alpha wing absorption in cool white dwarf stars

Kowalski & Saumon (2006) identified the missing absorption mechanism in the observed spectra of cool white dwarf stars as the Ly-alpha red wing formed by the collisions between atomic and molecular hydrogen and successfully explained entire spectra of many cool DA-type white dwarfs. Owing to the important astrophysical implications of this issue, we present here an independent assessment of the process. For this purpose, we compute free-free quasi-molecular absorption in Lyman-alpha due to collisions with H and H2 within the one-perturber, quasi-static approximation. Line cross-sections are obtained using theoretical molecular potentials to describe the interaction between the radiating atom and the perturber. The variation of the electric-dipole transition moment with the interparticle distance is also considered. Six and two allowed electric dipole transitions due to H-H and H-H2 collisions, respectively, are taken into account. The new theoretical Lyman-alpha line profiles are then incorporated in our stellar atmosphere program for the computation of synthetic spectra and colours of DA-type white dwarfs. Illustrative model atmospheres and spectral energy distributions are computed, which show that Ly-alpha broadening by atoms and molecules has a significant effect on the white dwarf atmosphere models. The inclusion of this collision-induced opacity significantly reddens spectral energy distributions and affects the broadband colour indices for model atmospheres with Teff<5000 K. These results confirm those previously obtained by Kowalski & Saumon (2006). Our study points out the need for reliable evaluations of H3 potential energy surfaces covering a large region of nuclear configurations, in order to obtain a better description of H-H2 collisions and a more accurate evaluation of their influence on the spectrum of cool white dwarfs.Comment: 11 pages, 12 figures, 1 table, to be published in MNRA

Multicomponent fluids of hard hyperspheres in odd dimensions

Mixtures of hard hyperspheres in odd space dimensionalities are studied with an analytical approximation method. This technique is based on the so-called Rational Function Approximation and provides a procedure for evaluating equations of state, structure factors, radial distribution functions, and direct correlations functions of additive mixtures of hard hyperspheres with any number of components and in arbitrary odd-dimension space. The method gives the exact solution of the Ornstein--Zernike equation coupled with the Percus--Yevick closure, thus extending to arbitrary odd dimension the solution for hard-sphere mixtures [J. L. Lebowitz, Phys.\ Rev.\ \textbf{133}, 895 (1964)]. Explicit evaluations for binary mixtures in five dimensions are performed. The results are compared with computer simulations and a good agreement is found.Comment: 16 pages, 8 figures; v2: slight change of notatio