27,905 research outputs found

    Cosmological Constraints with Clustering-Based Redshifts

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    We demonstrate that observations lacking reliable redshift information, such as photometric and radio continuum surveys, can produce robust measurements of cosmological parameters when empowered by clustering-based redshift estimation. This method infers the redshift distribution based on the spatial clustering of sources, using cross-correlation with a reference dataset with known redshifts. Applying this method to the existing SDSS photometric galaxies, and projecting to future radio continuum surveys, we show that sources can be efficiently divided into several redshift bins, increasing their ability to constrain cosmological parameters. We forecast constraints on the dark-energy equation-of-state and on local non-gaussianity parameters. We explore several pertinent issues, including the tradeoff between including more sources versus minimizing the overlap between bins, the shot-noise limitations on binning, and the predicted performance of the method at high redshifts. Remarkably, we find that, once this technique is implemented, constraints on dynamical dark energy from the SDSS imaging catalog can be competitive with, or better than, those from the spectroscopic BOSS survey and even future planned experiments. Further, constraints on primordial non-Gaussianity from future large-sky radio-continuum surveys can outperform those from the Planck CMB experiment, and rival those from future spectroscopic galaxy surveys. The application of this method thus holds tremendous promise for cosmology.Comment: 7 pages, 3 figures, 2 tables; to be submitted to MNRA

    Insight into Solvent Coordination of an Iron Porphyrin Hydroxylamine Complex from Spectroscopy and DFT Calculations

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    The reduction of Fe(OEP)(NO) in the presence of substituted phenols leads to a three‐electron reduction to form Fe(OEP)(NH2OH), which has been characterized by visible spectroscopy and electron stoichiometry. In this work, we have further characterized this species using infrared and 1H NMR spectroscopy, along with DFT calculations. The infrared bands in the 3400–3600 cm–1 region, due to hydroxylamine, were significantly downshifted to the 2500–2700 cm–1 region when 4‐[D1]chlorophenol replaced the normal abundance acid. Using 1H NMR spectroscopy, the hydroxylamine and the meso‐protons were identified. From DFT calculations, the 1H NMR spectra were most consistent with a six‐coordinate complex, Fe(OEP)(NH2OH)(THF)

    A first-principles investigation on the effects of magnetism on the Bain transformation of α\alpha-phase FeNi systems

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    The effects of magnetism on the Bain transformation of α\alpha-phase FeNi systems are investigated by using the full potential linearized augmented plane wave (FLAPW) method based on the generalized gradient approximation (GGA). We found that Ni impurity in bcc Fe increases the lattice constant in ferromagnetic (FM) states, but not in the nonmagnetic (NM) states. The shear modulus GG and Young's modulus EE of bcc Fe are also increased by raising the concentration of nickel. All the compositions considered show high shear anisotropy and the ratio of the bulk to shear modulus is greater than 1.75 implying ductility. The mean sound velocities in the [100][100] directions are greater than in the [110][110] directions. The Bain transformation, which is a component of martensitic transformation, has also been studied to reveal that Nix_{x}Fe1x_{1-x} alloys are elastically unstable in the NM states, but not so in the FM states. The electronic structures explain these results in terms of the density of states at the Fermi level. It is evident that magnetism cannot be neglected when dealing with the Bain transformation in iron and its alloys.Comment: Accepted for publications in J. Appl. Phys. (2012

    On entropy, specific heat, susceptibility and Rushbrooke inequality in percolation

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    We investigate percolation, a probabilistic model for continuous phase transition (CPT), on square and weighted planar stochastic lattices. In its thermal counterpart, entropy is minimally low where order parameter (OP) is maximally high and vice versa. Besides, specific heat, OP and susceptibility exhibit power-law when approaching the critical point and the corresponding critical exponents α,β,γ\alpha, \beta, \gamma respectably obey the Rushbrooke inequality (RI) α+2β+γ2\alpha+2\beta+\gamma\geq 2. Their analogues in percolation, however, remain elusive. We define entropy, specific heat and redefine susceptibility for percolation and show that they behave exactly in the same way as their thermal counterpart. We also show that RI holds for both the lattices albeit they belong to different universality classes.Comment: 5 pages, 3 captioned figures, to appear as a Rapid Communication in Physical Review E, 201

    Thin shell wormhole due to dyadosphere of a charged black hole

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    To explain Gamma Ray Bursts, Ruffini argued that the event horizon of a charged black hole is surrounded by a special region called, the Dyadosphere where electric field exceeds the critical value for e+e^+ ee^- pair production. In the present work, we construct a thin shell wormhole by performing a thought surgery between two dadospheres. Several physical properties of this thin shell wormhole have been analyzed.Comment: 10 pages, 2 figures. Accepted in Mod.Phys.Lett.

    Social Network Capital and Academic Careers

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    Social Network Capital and Academic Careers: The Case of a College of Agriculture ABSTRACT The relationship between economic performance and various forms of capital anchors a significant portion of mainstream economic theory and applied economics. Human, physical and financial capital represent important factors in the production of goods and services. The label “capital” implies characteristics such as investment, accumulation, maintenance, depreciation, and transfer. Recently, social capital or social network capital (SNC) has received increased scholarly attention in the literature of sociology, business, and economics. Limited analysis, however, has been directed at the role of SNC in the academy. We hypothesize that academic success at the professorial level is determined by the stock of human (HC) and SNC and the value flows emerging from these stocks. We view SNC as a complement to HC, increasing the productivity of HC while holding all other factors constant. An analysis of SNC’s importance to academic career success should interest the academy as well as other large organizations (i.e. research laboratories, government agencies) with similar structures and incentive systems.Social capital, academic networks, human capital, Institutional and Behavioral Economics, Labor and Human Capital, Teaching/Communication/Extension/Profession,

    The Role of Economic Factors, Including the Level of Tuition, in Individual University Participation Decisions in Canada

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    The study uses individual data from the Canadian Labour Force Survey to consider economic factors in university participation decisions by persons aged 17-24 from 1976 to 2003. The level of real tuition is one economic factor that may affect the university participation decision. There is also regional variation in the opportunity cost of university attendance; in the reduction in the probability of unemployment after obtaining a university degree; and in the proportion of university budgets used for financial support of students. In addition, there is some national variation by gender and over time in the return to a university education. This study finds that higher tuition levels in the 1990s did reduce the probability of university participation by persons aged 17,18 or 19 relative to a province-specific trend increase in university participation. Before drawing a policy conclusion from this result, it would be necessary to consider what the trend terms represent in the university participation decision.tuition fees; enrollment

    Redox and Spectroscopic Properties of Iron Porphyrin Nitroxyl in the Presence of Weak Acids

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    The spectroelectrochemistry and voltammetry of Fe(OEP) (NO) in the presence of substituted phenols was studied. Cyclic voltammetry showed that two closely spaced waves were observed for the reduction of Fe(OEP) (NO) in the presence of substituted phenols. The first wave was a single electron reduction under voltammetric conditions. The second wave was kinetically controlled, multielectron process. Visible spectroelectrochemistry of Fe(OEP) (NO) in the presence of substituted phenols showed that three species were present during the electrolysis. Additional spectroscopic studies indicated that the two reduction species were Fe(OEP) (HNO) and Fe(OEP)(H2NOH). The Fe(OEP) (HNO) species, which can be generated chemically, was stable over a period of hours. Additional acid did not lead to further protonation. Proton NMR spectroscopy confirmed the Fe(OEP) (HNO) species could be deprotonated under basic conditions. The third species, Fe(OEP)(H2NOH), was generated by the further reduction of the chemically generated Fe(OEP) (HNO) complex. Both the Fe(OEP) (HNO) and Fe(OEP)(H2NOH) complexes could be slowly oxidized back to Fe(OEP) (NO). At millimolar concentrations of Fe(OEP) (HNO), there was no evidence for the disproportionation of Fe(OEP) (HNO) to Fe(OEP) (NO) and H2 in the presence of substituted phenols. Nor was there evidence for the generation of N2O. The FTIR spectroelectrochemistry showed changes in the infrared spectra in the presence of substituted phenols, but no isotopic sensitive bands were observed for the reduced species between 1450 and 1200 cm–1. This may be because the νNO band shifted into a region (1500–1450 cm–1) where it would be difficult to observe
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