Quaternary glacial history of the Mediterranean mountains

Glacial and periglacial landforms are widespread in the mountains of the Mediterranean region. The evidence for glacial and periglacial activity has been studied for over 120 years and it is possible to identify three phases of development in this area of research. First, a pioneer phase characterized by initial descriptive observations of glacial landforms; second, a mapping phase whereby the detailed distribution of glacial landforms and sediments have been depicted on geomorphological maps; and, third, an advanced phase characterized by detailed understanding of the geochronology of glacial sequences using radiometric dating alongside detailed sedimentological and stratigraphical analyses. It is only relatively recently that studies of glaciated mountain terrains in the Mediterranean region have reached an advanced phase and it is now clear from radiometric dating programmes that the Mediterranean mountains have been glaciated during multiple glacial cycles. The most extensive phases of glaciation appear to have occurred during the Middle Pleistocene. This represents a major shift from earlier work whereby many glacial sequences were assumed to have formed during the last cold stage. Glacial and periglacial deposits from multiple Quaternary cold stages constitute a valuable palaeoclimatic record. This is especially so in the Mediterranean mountains, since mountain glaciers in this latitudinal zone would have been particularly sensitive to changes in the global climate system. © 2006 Edward Arnold (Publishers) Ltd

Silica sand resources in the Netherlands

Silica sand, (almost) pure quartz sand, is a valuable and scarce mineral resource within the shallow Dutch subsurface. High-grade deposits are exploited in the southeastemmost part of the country, as raw material for the glass, ceramic, chemical and other process industries. Dutch land-use policy requires that scarce mineral resources (including silica sand) are taken into consideration in spatial planning and when preparing for largescale engineering or construction works. For this purpose, and in order to review the long-term possibilities for home production of silica sand, we determined resource potential nationally. Our approach was (1) to establish the relevant conditions and processes associated with the deposition of the currently exploited sands, (2) identify lithostratigraphic units that are genetically similar or are otherwise known to contain quartz-rich sands, and (3) query the Dutch geological survey's borehole database for potential silica sand occurrences within those units. As we have to rely on non-dedicated data, the latter step was undertaken using a largely qualitative set of lithological search parameters. Finally, a limited number of available chemical analyses was used for preliminary verification purposes. Using this approach, we identified three prospective areas: one in the north of the province of Limburg and east of the province of Noord-Brabant (∼750 km2), one in the central south of Noord-Brabant (∼45 km2), and one in the east of the Gelderland and Overijssel provinces (∼1,200 km2). For each area, first-order characteristics of possible silica sand resources are presented (type of deposit depth, approximate thickness). In the terms of current reporting conventions, we resolved silica sand occurrence to the level of 'reconnaissance mineral resource' or 'exploration result', and our results do not constitute a formal resource declaration. Available chemical data suggest that the resources in the first two areas could be or become economic, although the grades are lower than those of the currently exploited resources. The third area is less promising in that respect, but available data is too limited to reject the area in this stage. Even so, we tentatively conclude that home production of silica sand can probably be maintained after the reserves in Limburg are depleted

Effects of different carrier materials on physicochemical properties of microencapsulated grape skin extract

The goal of this study was to investigate the characteristics of grape skin extract (GSE) spray dried with different carriers: maltodextrin (MD), gum Arabic (GA) and skim milk powder (SMP). The grape skin extract was obtained from winery by-product of red grape variety Prokupac (Vitis vinifera L.). The morphology of the powders, their thermal, chemical and physical properties (water activity, bulk and tapped densities, solubility), as well as release studies in different pH conditions were analyzed. Total anthocyanin content and total phenolic content were determined by spectrophotometric methods. MD and GA-based microparticles were non-porous and spherical, while SMP-based ones were irregularly shaped. The process of spray drying Prokupac GSE using these three carriers produced powders with low water activity (0.24-0.28), good powder characteristics, high yields, and solubility higher than 90%. The obtained dissolution/release profiles indicated prolonged release of anthocyanins and phenolic compounds in different mediums, especially from GSE/GA microparticles. These results have shown that grape skin as the main by-product of wine production could be used as a source of natural colorants and bioactive compounds, and microencapsulation as a promising technique for the protection of these compounds, their stabilization in longer periods and prolonged release

Secoiridoid content of Blackstonia perfoliata in vivo and in vitro

This study reports the analysis of secondary metabolites of gentiopicrin, swertiamarin, and sweroside in shoot and root cultures of yellow wort (Blackstonia perfoliata), which were initiated from seeds, grown on Murashige and Skoog (MS) medium. Shoot cultures of B. perfoliata were inoculated with suspension of Agrobacterium rhizogenes strain A4M70GUS and hairy roots appeared at the infected sites after 3 wk of inoculation. Tips of adventitious roots of B. perfoliata were grown on hormone-free MS medium and three clones of the transformed roots regenerated shoots spontaneously. Gentiopicrin, swertiamarin, and sweroside were detected in both roots and shoots of B. perfoliata in vitro and in vivo, but gentiopicrin was found to be the major compound. The concentration of growth regulator in the medium affected the production of secoiridoids in B. perfoliata in vitro, where the level of gentiopicrin was higher in plants grown in the presence of indole-3-butyric acid, but the presence of 6-benzylaminopurine was inhibitory to secoiridoid production