Excitation and Relaxation of Nonthermal Electron Energy Distributions in Metals with Application to Gold

A semiempirical theory for the excitation and subsequent relaxation of nonthermal electrons is described. The theory, which is applicable to ultrafast-laser excited metals, is based on the Boltzmann transport equation for the carrier distribution function $f(\epsilon,t)$ and includes electron-phonon, electron-electron, and electron-photon scattering integrals in forms that explicitly depend on the electronic density of states. Electron-phonon coupling is treated by extending the theory of Allen [Phys. Rev. Lett. 59, 1460 (1987)] to include highly-excited nonthermal electron distributions, and is used to determine the energy transfer rate between a nonthermal electron subsystem and a thermal phonon subsystem. Electron-electron scattering is treated with a simple energy-conserving electron-electron scattering integral. The electron-photon integral assumes photon absorption is phonon assisted. We apply the theory to analyze prior ultrafast thermionic emission, two-color photoemission, and electronic inelastic light (Raman) scattering experiments on Au. These analyses show that getting the details of $f(\epsilon,t)$ is necessary for proper interpretation of each experiment. Together, the photoemission and Raman-scattering analyses indicate an electron excited 1 eV above the Fermi level has an electron-electron scattering time in the range of 25 to 55 fs.Comment: 26 pages, 5 figures; 1 page Supplemental Materia

A spatially and temporally localized sub-laser-cycle electron source

We present an experimental and numerical study of electron emission from a sharp tungsten tip triggered by sub-8 femtosecond low power laser pulses. This process is non-linear in the laser electric field, and the non-linearity can be tuned via the DC voltage applied to the tip. Numerical simulations of this system show that electron emission takes place within less than one optical period of the exciting laser pulse, so that an 8 fsec 800 nm laser pulse is capable of producing a single electron pulse of less than 1 fsec duration. Furthermore, we find that the carrier-envelope phase dependence of the emission process is smaller than 0.1% for an 8 fsec pulse but is steeply increasing with decreasing laser pulse duration.Comment: 4 pages, 5 figure

Sports review: A content analysis of the International Review for the Sociology of Sport, the Journal of Sport and Social Issues and the Sociology of Sport Journal across 25 years

The International Review for the Sociology of Sport, the Journal of Sport and Social Issues and Sociology of Sport Journal have individually and collectively been subject to a systematic content analysis. By focusing on substantive research papers published in these three journals over a 25-year time period it is possible to identify the topics that have featured within the sociology of sport. The purpose of the study was to identify the dominant themes, sports, countries, methodological frameworks and theoretical perspectives that have appeared in the research papers published in these three journals. Using the terms, identified by the author(s), that appear in the paper’s title, abstract and/or listed as a key word, subject term or geographical term, a baseline is established to reflect on the development of the sub-discipline as represented by the content of these three journals. It is suggested that the findings illustrate what many of the more experienced practitioners in the field may have felt subjectively. On the basis of this systematic, empirical study it is now possible to identify those areas have received extensive coverage and those which are under-researched within the sociology of sport. The findings are used to inform a discussion of the role of academic journals and the recent contributions made by Michael Silk, David Andrews, Michael Atkinson and Dominic Malcolm on the past, present and future of the ‘sociology of sport’

Femtosecond Thermionic Emission in the Space-Charge Limited Regime

We study femtosecond-laser-pulse-induced electron emission from W(100), Al(110), and Ag(lll) in the sub-damage regime (1–44 mJ/cm2 fluence) by simultaneously measuring the incident-light reflectivity, total electron yield, and electron-energy distribution curves of the emitted electrons. The total-yield results are compared with a space-charge-limited extension of the Richardson-Dushman equation for short-time-scale thermionic emission and with particle-in-a-cell computer simulations of femtosecond-pulsed-induced thermionic emission. Quantitative agreement between the experimental results and two calculated temperature-dependent yields is obtained and shows that the yield varies linearly with temperature beginning at a threshold electron temperature of ~0.25 eV The particle-in-a-cell simulations also reproduce the experimental electron-energy distribution curves. Taken together, the experimental results, the theoretical calculations, and the results of the simulations indicate that thermionic emission from nonequilibrium electron heating provides the dominant source of the emitted electrons. Furthermore, the results demonstrate that a quantitative theory of space-charge-limited femtosecond-pulse-induced electron emission is possible

Surface Core Level Shifts of Clean and Oxygen Covered Ru(0001)

We have performed high resolution XPS experiments of the Ru(0001) surface, both clean and covered with well-defined amounts of oxygen up to 1 ML coverage. For the clean surface we detected two distinct components in the Ru 3d_{5/2} core level spectra, for which a definite assignment was made using the high resolution Angle-Scan Photoelectron Diffraction approach. For the p(2x2), p(2x1), (2x2)-3O and (1x1)-O oxygen structures we found Ru 3d_{5/2} core level peaks which are shifted up to 1 eV to higher binding energies. Very good agreement with density functional theory calculations of these Surface Core Level Shifts (SCLS) is reported. The overriding parameter for the resulting Ru SCLSs turns out to be the number of directly coordinated O atoms. Since the calculations permit the separation of initial and final state effects, our results give valuable information for the understanding of bonding and screening at the surface, otherwise not accessible in the measurement of the core level energies alone.Comment: 16 pages including 10 figures. Submitted to Phys. Rev. B. Related publications can be found at http://www.fhi-berlin.mpg.de/th/paper.htm

Electron-lattice kinetics of metals heated by ultrashort laser pulses

We propose a kinetic model of transient nonequilibrium phenomena in metals exposed to ultrashort laser pulses when heated electrons affect the lattice through direct electron-phonon interaction. This model describes the destruction of a metal under intense laser pumping. We derive the system of equations for the metal, which consists of hot electrons and a cold lattice. Hot electrons are described with the help of the Boltzmann equation and equation of thermoconductivity. We use the equations of motion for lattice displacements with the electron force included. The lattice deformation is estimated immediately after the laser pulse up to the time of electron temperature relaxation. An estimate shows that the ablation regime can be achieved.Comment: 7 pages; Revtex. to appear in JETP 88, #1 (1999