8 research outputs found
Elucidation of photocatalysis, photoluminescence and antibacterial studies of ZnO thin films by spin coating method
The ZnO thin films have been prepared by spin coating followed by annealing at different temperatures like 300 °C, 350 °C, 400 °C, 450 °C, 500 °C & 550 °C and ZnO nanoparticles have been used for photocatalytic and antibacterial applications. The morphological investigation and phase analysis of synthesized thin films well characterized by X-ray diffraction (XRD), Field Emission Scanning Electron Microscopy (FESEM), Photoluminescence (PL), Transmission Electron Microscopy (TEM) and Raman studies. The luminescence peaks detected in the noticeable region between 350 nm to 550 nm for all synthesized nanosamples are associated to the existence of defects of oxygen sites. The luminescence emission bands are observed at 487 nm (blue emission), and 530 nm (green emission) at the RT. It is observed that there are no modification positions of PL peaks in all ZnO nanoparticles. In the current attempt, the synthesized ZnO particles have been used photocatalytic and antibacterial applications. The antibacterial activity of characterized samples was regulated using different concentrations of synthesized ZnO particles (100 μg/ml, 200 μg/ml, 300 μg/ml, 400 μg/ml, 500 μg/ml and 600 μg/ml) against gram positive and gram negative bacteria (S. pnemoniae, S. aureus, E. coli and E. hermannii) using agar well diffusion assay. The increase in concentration, decrease in zone of inhibition. The prepared ZnO morphologies showed photocatalytic activity under the sunlight enhancing the degradation rate of Rhodamine-B (RhB), which is one of the common water pollutant released by textile and paper industries
Interferometric measurement of ionization in a grassfire
Grassfire plumes are weakly ionized gas. The ionization in the fire plume is due to thermal and chemi-ionization of incumbent species, which may include graphitic carbon, alkalis and thermally excited radicals, e.g., methyl. The presence of alkalis (e.g., potassium and sodium) in the fires makes thermal ionization a predominant electron producing mechanism in the combustion zone. Alkalis have low dissociation and ionization potentials and therefore require little energy to thermally decompose and give electrons. Assuming a Maxwellian velocity distribution of flame particles and electron-neutral collision frequency much higher than plasma frequency, the propagation of radio waves through a grassfire is predicted to have attenuation and phase shift. Radio wave propagation measurements were performed in a moderate intensity (554 kW m^−1) controlled grassfire at 30- and 151-MHz frequencies on a 44 m path using a radio wave interferometer. The maximum temperature measured in the controlled burn was 1071 K and the observed fire depth was 0.9 m. The radio wave interferometer measured attenuation coefficients of 0.033 and 0.054 dB m^−1 for 30- and 151-MHz, respectively. At collision frequency of 1.0 × 10^11 s^−1, maximum electron density was determined to be 5.061 × 10^15 m^−3