Comments on the detection of water and ice clouds on Venus

Problems in detecting ice and water clouds on Venu

L and T Dwarf Models and the L to T Transition

Using a model for refractory clouds, a novel algorithm for handling them, and the latest gas-phase molecular opacities, we have produced a new series of L and T dwarf spectral and atmosphere models as a function of gravity and metallicity, spanning the \teff range from 2200 K to 700 K. The correspondence with observed spectra and infrared colors for early- and mid-L dwarfs and for mid- to late-T dwarfs is good. We find that the width in infrared color-magnitude diagrams of both the T and L dwarf branches is naturally explained by reasonable variations in gravity and, therefore, that gravity is the "second parameter" of the L/T dwarf sequence. We investigate the dependence of theoretical dwarf spectra and color-magnitude diagrams upon various cloud properties, such as particle size and cloud spatial distribution. In the region of the L$\to$T transition, we find that no one cloud-particle-size and gravity combination can be made to fit all the observed data. Furthermore, we note that the new, lower solar oxygen abundances of Allende-Prieto, Lambert, & Asplund (2002) produce better fits to brown dwarf data than do the older values. Finally, we discuss various issues in cloud physics and modeling and speculate on how a better correspondence between theory and observation in the problematic L$\to$T transition region might be achieved.Comment: accepted to the Astrophysical Journal, 21 figures (20 in color); spectral models in electronic form available at http://zenith.as.arizona.edu/~burrow

Spectra and Diagnostics for the Direct Detection of Wide-Separation Extrasolar Giant Planets

We calculate as a function of orbital distance, mass, and age the theoretical spectra and orbit-averaged planet/star flux ratios for representative wide-separation extrasolar giant planets (EGPs) in the optical, near-infrared, and mid-infrared. Stellar irradiation of the planet's atmosphere and the effects of water and ammonia clouds are incorporated and handled in a consistent fashion. We include predictions for 12 specific known EGPs. In the process, we derive physical diagnostics that can inform the direct EGP detection and remote sensing programs now being planned or proposed. Furthermore, we calculate the effects of irradiation on the spectra of a representative companion brown dwarf as a function of orbital distance.Comment: submitted to the Astrophysical Journal, 19 pages, 11 color figure

Phase Functions and Light Curves of Wide Separation Extrasolar Giant Planets

We calculate self-consistent extrasolar giant planet (EGP) phase functions and light curves for orbital distances ranging from 0.2 AU to 15 AU. We explore the dependence on wavelength, cloud condensation, and Keplerian orbital elements. We find that the light curves of EGPs depend strongly on wavelength, the presence of clouds, and cloud particle sizes. Furthermore, the optical and infrared colors of most EGPs are phase-dependent, tending to be reddest at crescent phases in $V-R$ and $R-I$. Assuming circular orbits, we find that at optical wavelengths most EGPs are 3 to 4 times brighter near full phase than near greatest elongation for highly-inclined (i.e., close to edge-on) orbits. Furthermore, we show that the planet/star flux ratios depend strongly on the Keplerian elements of the orbit, particularly inclination and eccentricity. Given a sufficiently eccentric orbit, an EGP's atmosphere may make periodic transitions from cloudy to cloud-free, an effect that may be reflected in the shape and magnitude of the planet's light curve. Such elliptical orbits also introduce an offset between the time of the planet's light curve maximum and the time of full planetary phase, and for some sets of orbital parameters, this light curve maximum can be a steeply increasing function of eccentricity. We investigate the detectability of EGPs by proposed space-based direct-imaging instruments.Comment: submitted to Astrophysical Journa

Terrestrial groundwater and nutrient discharge along the 240-km-long Aquitanian coast

We collected samples from sea water, runnel water, beach pore waters, water from the unconfined surficial aquifer discharging at the beach face, groundwater, and rainwater from the Aquitanian coast in order to determine the flux of dissolved inorganic nitrogen (DIN), phosphorus and silica from terrestrial submarine groundwater discharge (SGD). The flux of fresh groundwater was obtained from a water balance calculation based on precipitation and evapotranspiration and assessment of the coastal watershed from hydrograph separation. Waters with intermediate salinities between sea water and freshwaters are found all along the 240-km-long coast, indicating that SGD is ubiquitous. The estimated fresh water flux is 2.25 m3 d− 1 m− 1 longshore. Terrestrial SGD provides a DIN flux of 9·106 mol each year to the adjacent coastal zone. This flux is about four times lower than the release of DIN due to tidally driven saline SGD. The freshwater DIN flux is low because the upland land use consists almost exclusively of pine forest. Dissolved organic nitrogen represents more than 60% of the total dissolved nitrogen flux. Dissolved iron, phosphorus and silica have much higher concentrations in the anoxic forest aquifer than in the fresh-water end-member of the subterranean estuary sampled in the upper beach aquifer. This suggests that the salinity gradient of the estuary does not correspond to a redox gradient. The redox front between anoxic groundwater and fresh oxic waters occurs below the soil-depleted foredune/yellow dune. Anoxic P- and Si-rich waters seep directly on the beach face only in the north Gironde, where the foredunes are eroded. This study reveals the role of the sandy foredune aquifer in biogeochemical fluxes from SGD, which is to dilute and oxidize waters from the unconfined surficial upland aquifer

Electron mean free path from angle-dependent photoelectron spectroscopy of aerosol particles

We propose angle-resolved photoelectron spectroscopy of aerosol particles as an alternative way to determine the electron mean free path of low energy electrons in solid and liquid materials. The mean free path is obtained from fits of simulated photoemission images to experimental ones over a broad range of different aerosol particle sizes. The principal advantage of the aerosol approach is twofold. Firstly, aerosol photoemission studies can be performed for many different materials, including liquids. Secondly, the size-dependent anisotropy of the photoelectrons can be exploited in addition to size-dependent changes in their kinetic energy. These finite size effects depend in different ways on the mean free path and thus provide more information on the mean free path than corresponding liquid jet, thin film, or bulk data. The present contribution is a proof of principle employing a simple model for the photoemission of electrons and preliminary experimental data for potassium chloride aerosol particles

Albedo and Reflection Spectra of Extrasolar Giant Planets

We generate theoretical albedo and reflection spectra for a full range of extrasolar giant planet (EGP) models, from Jovian to 51-Pegasi class objects. Our albedo modeling utilizes the latest atomic and molecular cross sections, a Mie theory treatment of extinction by condensates, a variety of particle size distributions, and an extension of the Feautrier radiative transfer method which allows for a general treatment of the scattering phase function. We find that due to qualitative similarities in the compositions and spectra of objects within each of five broad effective temperature ranges, it is natural to establish five representative EGP albedo classes: a ``Jovian'' class (T$_{\rm eff} \lesssim 150$ K; Class I) with tropospheric ammonia clouds, a ``water cloud'' class (T$_{\rm eff} \sim 250$ K; Class II) primarily affected by condensed H$_2$O, a ``clear'' class (T$_{\rm eff} \gtrsim 350$ K; Class III) which lacks clouds, and two high-temperature classes: Class IV (900 K $\lesssim$ T$_{\rm{eff}}$ $\lesssim$ 1500 K) for which alkali metal absorption predominates, and Class V (T$_{\rm{eff}}$ $\gtrsim$ 1500 K and/or low surface gravity ($\lesssim$ 10$^3$ cm s$^{-2}$)) for which a high silicate layer shields a significant fraction of the incident radiation from alkali metal and molecular absorption. The resonance lines of sodium and potassium are expected to be salient features in the reflection spectra of Class III, IV, and V objects. We derive Bond albedos and effective temperatures for the full set of known EGPs and explore the possible effects of non-equilibrium condensed products of photolysis above or within principal cloud decks. As in Jupiter, such species can lower the UV/blue albedo substantially, even if present in relatively small mixing ratios.Comment: revised LaTeX manuscript accepted to Ap.J.; also available at http://jupiter.as.arizona.edu/~burrows/paper

Theoretical Spectra and Atmospheres of Extrasolar Giant Planets

We present a comprehensive theory of the spectra and atmospheres of irradiated extrasolar giant planets. We explore the dependences on stellar type, orbital distance, cloud characteristics, planet mass, and surface gravity. Phase-averaged spectra for specific known extrasolar giant planets that span a wide range of the relevant parameters are calculated, plotted, and discussed. The connection between atmospheric composition and emergent spectrum is explored in detail. Furthermore, we calculate the effect of stellar insolation on brown dwarfs. We review a variety of representative observational techniques and programs for their potential for direct detection, in light of our theoretical expectations, and we calculate planet-to-star flux ratios as a function of wavelength. Our results suggest which spectral features are most diagnostic of giant planet atmospheres and reveal the best bands in which to image planets of whatever physical or orbital characteristics.Comment: 47 pages, plus 36 postscript figures; with minor revisions, accepted to the Astrophysical Journal, May 10, 2003 issu

Atomic and Molecular Opacities for Brown Dwarf and Giant Planet Atmospheres

We present a comprehensive description of the theory and practice of opacity calculations from the infrared to the ultraviolet needed to generate models of the atmospheres of brown dwarfs and extrasolar giant planets. Methods for using existing line lists and spectroscopic databases in disparate formats are presented and plots of the resulting absorptive opacities versus wavelength for the most important molecules and atoms at representative temperature/pressure points are provided. Electronic, ro-vibrational, bound-free, bound-bound, free-free, and collision-induced transitions and monochromatic opacities are derived, discussed, and analyzed. The species addressed include the alkali metals, iron, heavy metal oxides, metal hydrides, $H_2$, $H_2O$, $CH_4$, $CO$, $NH_3$, $H_2S$, $PH_3$, and representative grains. [Abridged]Comment: 28 pages of text, plus 22 figures, accepted to the Astrophysical Journal Supplement Series, replaced with more compact emulateapj versio

Greenhouse gas emissions from inland waters: A perspective and research agenda for the tropics and subtropics

peer reviewedStrong consensus indicates that inland waters emit globally significant quantities of greenhouse gases such as carbon dioxide, methane, and nitrous oxide. Tropical inland waters are often considered major contributors to higher greenhouse gas fluxes, yet accurate estimates of aquatic greenhouse gas fluxes are limited for the tropics. We provide a historical perspective on research carried out across low latitudes since the 1980s, synthesize current understanding of the sources and drivers of greenhouse gas emissions, and highlight priority research areas for future tropical inland water greenhouse gas research. We show that much of the focus has been on the humid tropics while the wet-dry, (semi)arid, and mountainous regions remain underrepresented in global datasets. Consistent and reliable greenhouse gas emission estimates will require (1) addressing the observational mismatch with new data from understudied ecoregions, (2) favoring direct and high-resolution carbon dioxide measurements over indirect estimates based on water chemistry parameters, (3) developing approaches that cross boundaries between ecosystem types and scales, and (4) sharing and publishing data more systematically