1,411 research outputs found
Secondary literacy across the curriculum: Challenges and possibilities
This paper discusses the challenges and possibilities attendant upon successfully implementing literacy across the curriculum initiatives – or ‘school language policies’ as they have come to be known - particularly at the secondary or high school level. It provides a theoretical background to these issues, exploring previous academic discussions of school language policies, and highlights key areas of concern as well as opportunity with respect to school implementation of such policies. As such, it provides a necessary conceptual background to the subsequent papers in this special issue, which focus upon the Secondary Schools’ Literacy Initiative (SSLI) – a New Zealand funded programme that aims to establish cross-curricular language and literacy policies in secondary schools
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Important Considerations in Plasmon-Enhanced Electrochemical Conversion at Voltage-Biased Electrodes.
In this perspective we compare plasmon-enhanced electrochemical conversion (PEEC) with photoelectrochemistry (PEC). PEEC is the oxidation or reduction of a reactant at the illuminated surface of a plasmonic metal (or other conductive material) while a potential bias is applied. PEC uses solar light to generate photoexcited electron-hole pairs to drive an electrochemical reaction at a biased or unbiased semiconductor photoelectrode. The mechanism of photoexcitation of charge carriers is different between PEEC and PEC. Here we explore how this difference affects the response of PEEC and PEC systems to changes in light, temperature, and surface morphology of the photoelectrode
Models for Enhanced Absorption in Inhomogeneous Superconductors
We discuss the low-frequency absorption arising from quenched inhomogeneity
in the superfluid density rho_s of a model superconductor. Such inhomogeneities
may arise in a high-T_c superconductor from a wide variety of sources,
including quenched random disorder and static charge density waves such as
stripes. Using standard classical methods for treating randomly inhomogeneous
media, we show that both mechanisms produce additional absorption at finite
frequencies. For a two-fluid model with weak mean-square fluctuations <(d
rho_s)^2 > in rho_s and a frequency-independent quasiparticle conductivity, the
extra absorption has oscillator strength proportional to the quantity <(d
rho_s)^2>/rho_s, as observed in some experiments. Similar behavior is found in
a two-fluid model with anticorrelated fluctuations in the superfluid and normal
fluid densities. The extra absorption typically occurs as a Lorentzian centered
at zero frequency. We present simple model calculations for this extra
absorption under conditions of both weak and strong fluctuations. The relation
between our results and other model calculations is briefly discussed
In Situ ATR-SEIRAS of Carbon Dioxide Reduction at a Plasmonic Silver Cathode.
Illumination of a voltage-biased plasmonic Ag cathode during CO2 reduction results in a suppression of the H2 evolution reaction while enhancing CO2 reduction. This effect has been shown to be photonic rather than thermal, but the exact plasmonic mechanism is unknown. Here, we conduct an in situ ATR-SEIRAS (attenuated total reflectance-surface-enhanced infrared absorption spectroscopy) study of a sputtered thin film Ag cathode on a Ge ATR crystal in CO2-saturated 0.1 M KHCO3 over a range of potentials under both dark and illuminated (365 nm, 125 mW cm-2) conditions to elucidate the nature of this plasmonic enhancement. We find that the onset potential of CO2 reduction to adsorbed CO on the Ag surface is -0.25 VRHE and is identical in the light and the dark. As the production of gaseous CO is detected in the light near this onset potential but is not observed in the dark until -0.5 VRHE, we conclude that the light must be assisting the desorption of CO from the surface. Furthermore, the HCO3- wavenumber and peak area increase immediately upon illumination, precluding a thermal effect. We propose that the enhanced local electric field that results from the localized surface plasmon resonance (LSPR) is strengthening the HCO3- bond, further increasing the local pH. This would account for the decrease in H2 formation and increase the CO2 reduction products in the light
A Low Noise Thermometer Readout for Ruthenium Oxide Resistors
The thermometer and thermal control system, for the Absolute Radiometer for
Cosmology, Astrophysics, and Diffuse Emission (ARCADE) experiment, is
described, including the design, testing, and results from the first flight of
ARCADE. The noise is equivalent to about 1 Omega or 0.15 mK in a second for the
RuO_2 resistive thermometers at 2.7 K. The average power dissipation in each
thermometer is 1 nW. The control system can take full advantage of the
thermometers to maintain stable temperatures. Systematic effects are still
under investigation, but the measured precision and accuracy are sufficient to
allow measurement of the cosmic background spectrum.
Journal-ref: Review of Scientific Instruments Vol 73 #10 (Oct 2002)Comment: 5 pages text 7 figure
Measurement of the complex Faraday angle in thin-film metals and high temperature superconductors
A sensitive polarization modulation technique uses photoelastic modulation
and hetrodyne detection to simultaneously measure the Faraday rotation and
induced ellipticity in light transmitted by semiconducting and metallic
samples. The frequencies measured are in the mid-infrared and correspond to the
spectral lines of a CO2 laser. The measured temperature range is continuous and
extends from 35 to 330K. Measured samples include GaAs and Si substrates, gold
and copper films, and YBCO and BSCCO high temperature superconductors.Comment: 12 pages of text, 6 figures, fixed typos in formulas, added figur
Natural product inhibitors of ocular angiogenesis
Natural products are characterized by high chemical diversity and biochemical specificity; therefore, they are appealing as lead compounds for drug discovery. Given the importance of angiogenesis to many pathologies, numerous natural products have been explored as potential anti-angiogenic drugs. Ocular angiogenesis underlies blinding eye diseases such as retinopathy of prematurity (ROP) in children, proliferative diabetic retinopathy (DR) in adults of working age, and age-related macular degeneration (AMD) in the elderly. Despite the presence of effective therapy in many cases, these diseases are still a significant health burden. Anti-VEGF biologics are the standard of care, but may cause ocular or systemic side effects after intraocular administration and patients may be refractory. Many anti-angiogenic compounds inhibit tumor growth and metastasis alone or in combination therapy, but a more select subset of them has been tested in the context of ocular neovascular diseases. Here, we review the promise of natural products as anti-angiogenic agents, with a specific focus on retinal and choroidal neovascularization. The multifunctional curcumin and the chalcone isoliquiritigenin have demonstrated promising anti-angiogenic effects in mouse models of DR and choroidal neovascularization (CNV) respectively. The homoisoflavanone cremastranone and the flavonoid deguelin have been shown to inhibit ocular neovascularization in more than one disease model. The isoflavone genistein and the flavone apigenin on the other hand are showing potential in the prevention of retinal and choroidal angiogenesis with long-term administration. Many other products with anti-angiogenic potential in vitro such as the lactone withaferin A, the flavonol quercetin, and the stilbenoid combretastatin A4 are awaiting investigation in different ocular disease-relevant animal models. These natural products may serve as lead compounds for the design of more specific, efficacious, and affordable drugs with minimal side effects
Conductivity Due to Classical Phase Fluctuations in a Model For High-T_c Superconductors
We consider the real part of the conductivity, \sigma_1(\omega), arising from
classical phase fluctuations in a model for high-T_c superconductors. We show
that the frequency integral of that conductivity, \int_0^\infty \sigma_1
d\omega, is non-zero below the superconducting transition temperature ,
provided there is some quenched disorder in the system. Furthermore, for a
fixed amount of quenched disorder, this integral at low temperatures is
proportional to the zero-temperature superfluid density, in agreement with
experiment. We calculate \sigma_1(\omega) explicitly for a model of overdamped
phase fluctuations.Comment: 4pages, 2figures, submitted to Phys.Rev.
Facial Cosmetics Have Little Effect on Attractiveness Judgments Compared with Identity
The vast majority of women in modern societies use facial cosmetics, which modify facial cues to attractiveness. However, the size of this increase remains unclear - how much more attractive are individuals after an application of cosmetics? Here, we utilised a 'new statistics' approach, calculating the effect size of cosmetics on attractiveness using a within-subjects design, and compared this with the effect size due to identity - that is, the inherent differences in attractiveness between people. Women were photographed with and without cosmetics, and these images were rated for attractiveness by a second group of participants. The proportion of variance in attractiveness explained by identity was much greater than the variance within models due to cosmetics. This result was unchanged after statistically controlling for the perceived amount of cosmetics that each model used. Although cosmetics increase attractiveness, the effect is small, and the benefits of cosmetics may be inflated in everyday thinking. © 2015, Pion Limited. All rights reserved
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