1,159 research outputs found
Secondary literacy across the curriculum: Challenges and possibilities
This paper discusses the challenges and possibilities attendant upon successfully implementing literacy across the curriculum initiatives – or ‘school language policies’ as they have come to be known - particularly at the secondary or high school level. It provides a theoretical background to these issues, exploring previous academic discussions of school language policies, and highlights key areas of concern as well as opportunity with respect to school implementation of such policies. As such, it provides a necessary conceptual background to the subsequent papers in this special issue, which focus upon the Secondary Schools’ Literacy Initiative (SSLI) – a New Zealand funded programme that aims to establish cross-curricular language and literacy policies in secondary schools
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Important Considerations in Plasmon-Enhanced Electrochemical Conversion at Voltage-Biased Electrodes.
In this perspective we compare plasmon-enhanced electrochemical conversion (PEEC) with photoelectrochemistry (PEC). PEEC is the oxidation or reduction of a reactant at the illuminated surface of a plasmonic metal (or other conductive material) while a potential bias is applied. PEC uses solar light to generate photoexcited electron-hole pairs to drive an electrochemical reaction at a biased or unbiased semiconductor photoelectrode. The mechanism of photoexcitation of charge carriers is different between PEEC and PEC. Here we explore how this difference affects the response of PEEC and PEC systems to changes in light, temperature, and surface morphology of the photoelectrode
Measurement of the complex Faraday angle in thin-film metals and high temperature superconductors
A sensitive polarization modulation technique uses photoelastic modulation
and hetrodyne detection to simultaneously measure the Faraday rotation and
induced ellipticity in light transmitted by semiconducting and metallic
samples. The frequencies measured are in the mid-infrared and correspond to the
spectral lines of a CO2 laser. The measured temperature range is continuous and
extends from 35 to 330K. Measured samples include GaAs and Si substrates, gold
and copper films, and YBCO and BSCCO high temperature superconductors.Comment: 12 pages of text, 6 figures, fixed typos in formulas, added figur
Models for Enhanced Absorption in Inhomogeneous Superconductors
We discuss the low-frequency absorption arising from quenched inhomogeneity
in the superfluid density rho_s of a model superconductor. Such inhomogeneities
may arise in a high-T_c superconductor from a wide variety of sources,
including quenched random disorder and static charge density waves such as
stripes. Using standard classical methods for treating randomly inhomogeneous
media, we show that both mechanisms produce additional absorption at finite
frequencies. For a two-fluid model with weak mean-square fluctuations <(d
rho_s)^2 > in rho_s and a frequency-independent quasiparticle conductivity, the
extra absorption has oscillator strength proportional to the quantity <(d
rho_s)^2>/rho_s, as observed in some experiments. Similar behavior is found in
a two-fluid model with anticorrelated fluctuations in the superfluid and normal
fluid densities. The extra absorption typically occurs as a Lorentzian centered
at zero frequency. We present simple model calculations for this extra
absorption under conditions of both weak and strong fluctuations. The relation
between our results and other model calculations is briefly discussed
The Management of Extrahepatic Portal Vein Aneurysms: Observe or Treat?
A case of a 70 year old man who was found to have an extrahepatic portal vein aneurysm during an evaluation for hematuria is reported. Extrahepatic portal vein aneurysms are rare with only twenty cases reported in the literature. Typically, patients present with hemorrhage requiring surgical exploration or the aneurysm is discovered during evaluation of another abdominal process. Management includes careful follow-up in the asymptomatic patient without underlying liver disease or portal hypertension
A Low Noise Thermometer Readout for Ruthenium Oxide Resistors
The thermometer and thermal control system, for the Absolute Radiometer for
Cosmology, Astrophysics, and Diffuse Emission (ARCADE) experiment, is
described, including the design, testing, and results from the first flight of
ARCADE. The noise is equivalent to about 1 Omega or 0.15 mK in a second for the
RuO_2 resistive thermometers at 2.7 K. The average power dissipation in each
thermometer is 1 nW. The control system can take full advantage of the
thermometers to maintain stable temperatures. Systematic effects are still
under investigation, but the measured precision and accuracy are sufficient to
allow measurement of the cosmic background spectrum.
Journal-ref: Review of Scientific Instruments Vol 73 #10 (Oct 2002)Comment: 5 pages text 7 figure
In Situ ATR-SEIRAS of Carbon Dioxide Reduction at a Plasmonic Silver Cathode.
Illumination of a voltage-biased plasmonic Ag cathode during CO2 reduction results in a suppression of the H2 evolution reaction while enhancing CO2 reduction. This effect has been shown to be photonic rather than thermal, but the exact plasmonic mechanism is unknown. Here, we conduct an in situ ATR-SEIRAS (attenuated total reflectance-surface-enhanced infrared absorption spectroscopy) study of a sputtered thin film Ag cathode on a Ge ATR crystal in CO2-saturated 0.1 M KHCO3 over a range of potentials under both dark and illuminated (365 nm, 125 mW cm-2) conditions to elucidate the nature of this plasmonic enhancement. We find that the onset potential of CO2 reduction to adsorbed CO on the Ag surface is -0.25 VRHE and is identical in the light and the dark. As the production of gaseous CO is detected in the light near this onset potential but is not observed in the dark until -0.5 VRHE, we conclude that the light must be assisting the desorption of CO from the surface. Furthermore, the HCO3- wavenumber and peak area increase immediately upon illumination, precluding a thermal effect. We propose that the enhanced local electric field that results from the localized surface plasmon resonance (LSPR) is strengthening the HCO3- bond, further increasing the local pH. This would account for the decrease in H2 formation and increase the CO2 reduction products in the light
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