No compelling evidence of distributed production of CO in comet C/1995 O1 (Hale-Bopp) from millimeter interferometric data and a reanalysis of near-IR lines

Based on long-slit infrared spectroscopic observations, it has been suggested that half of the carbon monoxide present in the atmosphere of comet C/1995 O1 (Hale-Bopp) close to perihelion was released by a distributed source in the coma, whose nature (dust or gas) remains unidentified. We re-assess the origin of CO in Hale-Bopp's coma from millimeter interferometric data and a re-analysis of the IR lines. Simultaneous observations of the CO J(1-0) (115 GHz) and J(2-1) (230 GHz) lines were undertaken with the IRAM interferometer in single-dish and interferometric modes. The diversity of angular resolutions (from 1700 to 42000 km diameter at the comet) is suitable to study the radial distribution of CO and detect the extended source observed in the infrared. We used excitation and radiative transfer models to simulate the observations. Various CO density distributions were considered, including 3D time-dependent hydrodynamical simulations which reproduce a CO rotating jet. The CO J(1-0) and J(2-1) observations can be consistently explained by a nuclear production of CO. Composite 50:50 nuclear/extended productions with characteristic scale lengths of CO parent L_p > 1500 km are rejected. Based on similar radiation transfer calculations, we show that the CO v = 1-0 ro-vibrational lines observed in comet Hale-Bopp at heliocentric distances less than 1.5 AU are severely optically thick. The broad extent of the CO brightness distribution in the infrared is mainly due to optical depth effects. Additional factors can be found in the complex structure of the CO coma, and non-ideal slit positioning caused by the anisotropy of dust IR emission. We conclude that both CO millimeter and infrared lines do not provide compelling evidence for a distributed source of CO in Hale-Bopp's atmosphere.Comment: Accepted for publication in Icarus (55 pages, 13 figures

The chemical diversity of comets

A fundamental question in cometary science is whether the different dynamical classes of comets have different chemical compositions, which would reflect different initial conditions. From the ground or Earth orbit, radio and infrared spectroscopic observations of a now significant sample of comets indeed reveal deep differences in the relative abundances of cometary ices. However, no obvious correlation with dynamical classes is found. Further results come, or are expected, from space exploration. Such investigations, by nature limited to a small number of objects, are unfortunately focussed on short-period comets (mainly Jupiter-family). But these in situ studies provide "ground truth" for remote sensing. We discuss the chemical differences in comets from our database of spectroscopic radio observations, which has been recently enriched by several Jupiter-family and Halley-type comets.Comment: In press in Earth, Moon and Planets (proceedings of the workshop "Future Ground-based Solar System Research: Synergies with Space Probes and Space Telescopes", Portoferraio, Isola d'Elba, Livorno (Italy), 8-12 September 2008). 6 pages with 2 figure

Interferometric mapping of the 3.3-mm continuum emission of comet 17P/Holmes after its 2007 outburst

Comet 17P/Holmes underwent a dramatic outburst in October 2007, caused by the sudden fragmentation of its nucleus and the production of a large quantity of grains scattering sunlight. We report on 90 GHz continuum observations carried out with the IRAM Plateau de Bure interferometer on 27.1 and 28.2 October 2007 UT, i.e., 4-5 days after the outburst. These observations probed the thermal radiation of large dust particles, and therefore provide the best constraints on the mass in the ejecta debris. The thermal emission of the debris was modelled and coupled to a time-dependent description of their expansion after the outburst. The analysis was performed in the Fourier plane. Visibilities were computed for the two observing dates and compared to the data to measure their velocity and mass. Optical data and 250-GHz continuum measurements published in the literature were used to further constrain the dust kinematics and size distribution. Two distinct dust components in terms of kinematic properties are identified in the data. The large-velocity component, with typical velocities V0 of 50-100 m/s for 1 mm particles, displays a steep size distribution with a size index estimated to q = -3.7 (\pm0.1), assuming a minimum grain size of 0.1 \mum. It corresponds to the fast expanding shell observed in optical images. The slowly-moving "core" component (V0 = 7-9 m/s) detected near the nucleus has a size index |q| < 3.4 and contains a higher proportion of large particles than the shell. The dust mass in the core is in the range 0.1-1 that of the shell. Using optical constants pertaining to porous grains (50% porosity) made of astronomical silicates mixed with water ice (48% in mass), the total dust mass Mdust injected by the outburst is estimated to 4-14 x 10**11 kg, corresponding to 3-9% the nucleus mass.Comment: 15 pages with 11 figures and 7 tables. Accepted for publication in Astronomy & Astrophysic

Antifreeze in the hot core of Orion - First detection of ethylene glycol in Orion-KL

Comparison of their chemical compositions shows, to first order, a good agreement between the cometary and interstellar abundances. However, a complex O-bearing organic molecule, ethylene glycol (CH$_{2}$OH)$_{2}$, seems to depart from this correlation because it was not easily detected in the interstellar medium although it proved to be rather abundant with respect to other O-bearing species in comet Hale-Bopp. Ethylene glycol thus appears, together with the related molecules glycolaldehyde CH$_{2}$OHCHO and ethanol CH$_{3}$CH$_{2}$OH, as a key species in the comparison of interstellar and cometary ices as well as in any discussion on the formation of cometary matter. We focus here on the analysis of ethylene glycol in the nearest and best studied hot core-like region, Orion-KL. We use ALMA interferometric data because high spatial resolution observations allow us to reduce the line confusion problem with respect to single-dish observations since different molecules are expected to exhibit different spatial distributions. Furthermore, a large spectral bandwidth is needed because many individual transitions are required to securely detect large organic molecules. Confusion and continuum subtraction are major issues and have been handled with care. We have detected the aGg' conformer of ethylene glycol in Orion-KL. The emission is compact and peaks towards the Hot Core close to the main continuum peak, about 2" to the south-west; this distribution is notably different from other O-bearing species. Assuming optically thin lines and local thermodynamic equilibrium, we derive a rotational temperature of 145 K and a column density of 4.6 10$^{15}$ cm$^{-2}$. The limit on the column density of the gGg' conformer is five times lower.Comment: 19 pages, 10 figures, A&A accepte

Interferometric imaging of carbon monoxide in comet C/1995 O1 (Hale-Bopp): evidence for a strong rotating jet

Observations of the CO J(1-0) 115 GHz and J(2-1) 230 GHz lines in comet C/1995 O1 (Hale-Bopp) were performed with the IRAM Plateau de Bure interferometer on 11 March, 1997. The observations were conducted in both single-dish (ON-OFF) and interferometric modes with 0.13 km s-1 spectral resolution. Images of CO emission with 1.7 to 3" angular resolution were obtained. The ON-OFF and interferometric spectra show a velocity shift with sinusoidal time variations related to the Hale-Bopp nucleus rotation of 11.35 h. The peak position of the CO images moves perpendicularly to the spin axis direction in the plane of the sky. This suggests the presence of a CO jet, which is active night and day at about the same extent, and is spiralling with nucleus rotation. The high quality of the data allows us to constrain the characteristics of this CO jet. We have developed a 3-D model to interpret the temporal evolution of CO spectra and maps. The CO coma is represented as the combination of an isotropic distribution and a spiralling gas jet, both of nucleus origin. Spectra and visibilities (the direct output of interferometric data) analysis shows that the CO jet comprises ~40% the total CO production and is located at a latitude ~20 degrees North on the nucleus surface. Our inability to reproduce all observational characteristics shows that the real structure of the CO coma is more complex than assumed, especially in the first thousand kilometres from the nucleus. The presence of another moving CO structure, faint but compact and possibly created by an outburst, is identified.Comment: 20 pages, 26 figures. Accepted for publication in Astronomy & Astrophysic

Ethylene glycol in comet C/1995 O1 (Hale-Bopp)

We report the detection of ethylene glycol (HOCH_2CH_2OH) in comet C/1995 O1 (Hale-Bopp) from the analysis of archival radio spectra. Its production rate is ≈0.25% that of water, making it one of the most abundant organic molecules in cometary ices. This detection strengthens the similarity between interstellar and cometary material

Interferometric imaging of the sulfur-bearing molecules H2S, SO and CS in comet C/1995 O1 (Hale-Bopp)

We present observations of rotational lines of H2S, SO and CS performed in comet C/1995 O1 (Hale-Bopp) in March 1997 with the Plateau de Bure interferometer (IRAM). The observations provide informations on the spatial and velocity distributions of these molecules. They can be used to constrain their photodissociation rate and their origin. We use a radiative transfer code which allows us to compute synthetic line profiles and interferometric maps, to be compared to the observations. Both single-dish spectra and interferometric spectral maps show a day/night asymmetry in the outgassing. From the analysis of the spectral maps, including the astrometry, we show that SO and CS present in addition a jet-like structure that may be the gaseous counterpart of the dust high-latitude jet observed in optical images. A CS rotating jet is also observed. Using the astrometry provided by continuum radio maps obtained in parallel, we conclude that there is no need to invoke of nongravitational forces acting on this comet, and provide an updated orbit. The radial extension of H2S is found to be consistent with direct release from the nucleus. SO displays an extended radial distribution. Assuming that SO2 is the parent of SO, the photodissociation rate of SO is measured to be 1.5 E-4 s-1 at 1 AU from the Sun. This is lower than most laboratory-based estimates and may suggest that SO is not solely produced by SO2 photolysis. From the observations of J(2-1) and J(5-4) CS lines, we deduce a CS photodissociation rate of 1 to 5 E-5 s-1. The photodissociation rate of CS2, the likely parent of CS, cannot be constrained due to insufficient resolution, but our data are consistent with published values. These observations illustrate the cometary science that will be performed with the future ALMA interferometer.Comment: Accepted for publication in Astronomy & Astrophysic

The composition of ices in comet C/1995 O1 (Hale-Bopp) from radio spectroscopy - Further results and upper limits on undetected species

From radio spectroscopic observations of comets, more than 22 molecules, radicals and ions, plus several isotopologues, were detected, the majority of them being recently revealed in comets C/1996 B2 (Hyakutake) and C/1995 O1 (Hale-Bopp). Among them, 6 molecules were detected for the first time (Bockelée-Morvan et al. [CITE]) in the course of a spectral survey conducted at radio wavelengths in comet Hale-Bopp with the CSO, the IRAM 30-m telescope and Plateau de Bure interferometer. In addition, many species were searched for unsuccessfully, some of them with stringent upper limits. We present here a review of these observations and further analysis of their results. This include: (i) confirmed detection of acetaldehyde (CH_3CHO); (ii) limits on small molecules such as ketene (H_2CCO) or methanimine (CH_2NH); (iii) limits on the abundance ratios in homologous series such as HC_5N/HC_3N, ethanol/methanol, acetic acid/formic acid; (iv) searches for precursors of key cometary species such as atomic Na and HNC; (v) constraints on more exotic species ranging from water dimer (H_2O)_2 to glycine; (vi) detection of the H_2^(34)S isotopic species and independent observations of HDO and DCN; (vii) limits on several other deuterated species; (viii) limits on several radicals and ions and a tentative detection of the C_2H radical; (ix) the presence of unidentified lines. Typical abundance upper limits of 2–5 x 10^(-4) relative to water are achieved for many species. Better upper limits are obtained for some linear molecules with high dipole moments. But more complex molecules such as dimethyl ether or glycine are poorly constrained. These results should give important clues to the chemical composition of cometary ices, to the formation mechanisms of cometary material, and to the chemical processes which occur in the inner coma

Submillimetric spectroscopic observations of volatiles in comet C/2004 Q2 (Machholz)

We aim to determine the production rates of several parent and product volatiles and the 12C/13C isotopic carbon ratio in the long-period comet C/2004 Q2 (Machholz), which is likely to originate from the Oort Cloud. The line emission from several molecules in the coma was measured with high signal-to-noise ratio in January 2005 at heliocentric distance of 1.2 AU by means of high-resolution spectroscopic observations using the Submillimeter Telescope (SMT). We have obtained production rates of several volatiles (CH3OH, HCN, H13CN, HNC, H2CO, CO and CS) by comparing the observed and simulated line-integrated intensities. Furthermore, multiline observations of the CH3OH (7-6) series allow us to estimate the rotational temperature using the rotation diagram technique. We find that the CH3OH population distribution of the levels sampled by these lines can be described by a rotational temperature of 40 \pm 3 K. Derived mixing ratios relative to hydrogen cyanide are CO/CH3OH/H2CO/CS/HNC/H13CN/HCN = 30.9/24.6/4.8/0.57/0.031/0.013/1 assuming a pointing offset of 8" due to the uncertain ephemeris at the time of the observations and the telescope pointing error. The measured relative molecular abundances in C/2004 Q2 (Machholz) are between low- to typical values of those obtained in Oort Cloud comets, suggesting that it has visited the inner solar system previously and undergone thermal processing. The HNC/HCN abundance ratio of ~3.1% is comparable to that found in other comets, accounting for the dependence on the heliocentric distance, and could possibly be explained by ion-molecule chemical processes in the low-temperature atmosphere. From a tentative H13CN detection, the measured value of 97 \pm 30 for the H12CN/H13CN isotopologue pair is consistent with a telluric value.Comment: 14 pages with 11 figures, abridged abstrac

A survey of volatile species in Oort cloud comets C/2001 Q4 (NEAT) and C/2002 T7 (LINEAR) at millimeter wavelengths

The line emission in the coma was measured in the comets C/2001 Q4 (NEAT) and C/2002 T7 (LINEAR), that were observed on five consecutive nights, 7-11 May 2004, at heliocentric distances of 1.0 and 0.7 AU, respectively, by means of high-resolution spectroscopy using the 10-m Submillimeter Telescope (SMT). We present a search for six parent- and product-volatile species (HCN, H2CO, CO, CS, CH3OH, and HNC) in both comets. Multiline observations of the CH3OH J = 5-4 series allow us to estimate the rotational temperature using the rotation diagram technique. We derive rotational temperatures of 54(9) K for C/2001 Q4 (NEAT) and 119(34) K for C/2002 T7 (LINEAR) that are roughly consistent with observations of other comets at similar distances from the Sun. The gas production rates of material are computed using a spherically symmetric molecular excitation code that includes collisions between neutrals and electrons. We find an HCN production rate of 2.96(5)e26 molec.s-1 for comet C/2001 Q4 (NEAT), corresponding to a mixing ratio with respect to H2O of 1.12(2)e-3. The mean HCN production rate during the observing period is 4.54(10)e26 molec.s-1 for comet C/2002 T7 (LINEAR), which gives a Q_HCN/Q_H2O mixing ratio of 1.51(3)e-3. With systematically lower mixing ratios in comet C/2001 Q4 (NEAT), production rate ratios of the observed species with respect to H2O lie within the typical ranges of dynamically new comets in both objects. We find a relative low abundance of CO in C/2001 Q4 (NEAT) compared to the observed range in other comets based on millimeter/submillimeter observations, and a significant upper limit on the CO production in C/2002 T7 (LINEAR) is derived. Depletion of CO suggests partial evaporation from the surface layers during previous visits to the outer Solar System and agrees with previous measurements of dynamically new comets.Comment: 20 pages, 18 figures. Minor changes to match the published versio