4,974 research outputs found

    A single-board preprocessor and pulse generator

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    The Aeronomy Lab. of NOAA has designed and built a single board, programmable radar controller for use with VHF ST (stratosphere troposphere) radars. The controller consists of a coherent integrator preprocessor and a radar pulse generator, both of which are described, as well as interfaces to an antenna beam switch and a receiver bandwidth switch. The controller occupies a single slot in a Data General Nova of Eclipse computer. The integrator and pulse generator take advantage of high density, dual port FIFO chips such as the 512 x 9 Mostek MK 4501. These FIFOs have separate input and output ports and independent read and write cycles with cycle times of less than 200 ns, making them very fast and easy to interface. A simple block diagram of the coherent integrator is shown. The integrator is designed to handle inputs from one receiver (2 channels) with 1 sec sample spacing. The pulse generator is based on controllers designed by R. F. Woodman for the Arecibo and SOUSY radars us a recirculating memory scheme

    Haze in the Klang Valley of Malaysia

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    Continuous measurements of dry aerosol light scattering (Bsp) were made at two sites in the Klang Valley of Malaysia between December 1998 and December 2000. In addition 24-h PM2.5 samples were collected on a one-day-in-six cycle and the chemical composition of the aerosol was determined. Periods of excessive haze were defined as 24-h average Bsp values greater than 150 Mm-1 and these occurred on a number of occasions, between May and September 1999, during May 2000, and between July and September 2000. The evidence for smoke being a significant contributor to aerosol during periods of excessive haze is discussed and includes features of the aerosol chemistry, the diurnal cycle of Bsp, and the coincidence of forest fires on Sumatra during the southwest (SW) monsoon period, as well as transport modelling for one week of the southwest Monsoon of 2000. The study highlights that whilst transboundary smoke is a major contributor to poor visibility in the Klang Valley, smoke from fires on Peninsular Malaysia is also a contributor, and at all times, the domestic source of secondary particle production is present

    A Consistent Reduced Network for HCN Chemistry in Early Earth and Titan Atmospheres: Quantum Calculations of Reaction Rate Coefficients

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    HCN is a key ingredient for synthesizing biomolecules such as nucleobases and amino acids. We calculate 42 reaction rate coefficients directly involved with or in competition with the production of HCN in the early Earth or Titan atmospheres. These reactions are driven by methane and nitrogen radicals produced via UV photodissociation or lightning. For every reaction in this network, we calculate rate coefficients at 298 K using canonical variational transition state theory (CVT) paired with computational quantum chemistry simulations at the BHandHLYP/augcc-pVDZ level of theory. We also calculate the temperature dependence of the rate coefficients for the reactions that have barriers from 50 to 400 K. We present 15 new reaction rate coefficients with no previously known value; 93% of our calculated coefficients are within an order of magnitude of the nearest experimental or recommended values. Above 320 K, the rate coefficient for the new reaction H2CN -> HCN + H dominates. Contrary to experiments, we find the HCN reaction pathway, N + CH3 -> HCN + H2, to be inefficient and suggest that the experimental rate coefficient actually corresponds to an indirect pathway, through the H2CN intermediate. We present CVT using energies computed with density functional theory as a feasible and accurate method for calculating a large network of rate coefficients of small-molecule reactions.Comment: 34 pages, 8 figures, 14 tables, accepted for publication in J Phys Chem
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