145 research outputs found
Nonlinear optical properties of nanomotors for optoelectronic applications
Date du colloque : 10/2008</p
Some selected and functionalised organometallic molecules for NLO applications
Organometallics nano complexes are important targets for the construction of advanced materials, the investigation of electron-transfer processes and of novel devices for non-linear optical (NLO) applications. In this work the diagnostic and characterisation of novel molecular organics nano complexes thin films functionalized for NLO applications will be discussed. On other hand a rich study of the formation of surface-relief gratings (SRGs), using a picosecond pulsed laser at 532 nm, resulted in instantaneous inscription will be presented
Average distance in growing trees
Two kinds of evolving trees are considered here: the exponential trees, where
subsequent nodes are linked to old nodes without any preference, and the
Barab\'asi--Albert scale-free networks, where the probability of linking to a
node is proportional to the number of its pre-existing links. In both cases,
new nodes are linked to nodes. Average node-node distance is
calculated numerically in evolving trees as dependent on the number of nodes
. The results for not less than a thousand are averaged over a thousand
of growing trees. The results on the mean node-node distance for large
can be approximated by for the exponential trees, and
for the scale-free trees, where the are constant. We
derive also iterative equations for and its dispersion for the exponential
trees. The simulation and the analytical approach give the same results.Comment: 6 pages, 3 figures, Int. J. Mod. Phys. C14 (2003) - in prin
Third harmonic generation via dendrimers of four generations
We report on third harmonic generation of E-O active dendrimers dispersed in polycarbonate matrix. Four kinds of polyester type dendrimers G0, G1, G2 and G3 containing azobenzene in the core used as third order nonlinear optical active chromophores were prepared as guest-host type system based on polycarbonate matrix spin-coated on a glass substrate. Third harmonic generation was measured while exciting the samples with fundamental wavelength 1.064 ¿m. Non-linear third-order susceptibility ¿(3) for different generations of dendrimers was evaluated
Enhancement of bulk second-harmonic generation from silicon nitride films by material composition
We present a comprehensive tensorial characterization of second-harmonic
generation from silicon nitride films with varying composition. The samples
were fabricated using plasma-enhanced chemical vapor deposition, and the
material composition was varied by the reactive gas mixture in the process. We
found a six-fold enhancement between the lowest and highest second-order
susceptibility, with the highest value of approximately 5 pm/V from the most
silicon-rich sample. Moreover, the optical losses were found to be sufficiently
small (below 6 dB/cm) for applications. The tensorial results show that all
samples retain in-plane isotropy independent of silicon content, highlighting
the controllability of the fabrication process.Comment: 4 pages, 3 figures, 2 tables; Re-submitted to Optics Letter
Study of surface relief gratings on azo organometallic films in picosecond regime
Materials for optical data storage and optical information processing must exhibit good holographic properties. Many materials for these applications have been already proposed. Here we describe a grating inscription process characterized by short inscription time and long-time stability. A series of ruthenium-acetylide organometallic complexes containing an azobenzene fragment were synthesized. Photo-induced gratings were produced by short pulse (16 ps, 532 nm) laser irradiation. The surface relief gratings formed at the same time were observed by atomic force microscope. In this work, we highlight the short inscription times brought into play as well as the good temporal stability of these gratings stored at room temperature. We study the influence of the polarization states and the light intensity of writing beams on the dynamics of the surface relief gratings formation and we compare these results with those of a known representative of azobenzene derivative (Disperse Red 1). Lastly, we show that it is possible to write two-dimensional surface relief gratings
Ferroelectric AgNa(NO2)2 crystals as novel highly efficient nonlinear optical material: Phase matched second harmonic generation driven by a spontaneous and electric field induced polarizations
Paper reports the second harmonic generation(SHG) in ferroelectric AgNa ( NO 2 ) 2 crystals being driven by the spontaneous and electric field induced polarizations. Obtained results are interpreted within the phenomenological theory which considers the free energy describing the interaction between the spontaneous or electric field induced polarizations and spatially inhomogeneous electric polarizations resulted from propagating optical waves. Relatively high magnitudes of the effective second order nonlinear optical (NLO) susceptibilities in these crystals are combined with several phase matching geometries which allows to consider them as high-performance materials for potential NLO applications, such as parametric generation and amplification, frequency doubling, or other applications that require high-efficient frequency conversion. In addition, an anomalously large response of NLO susceptibilities with respect to an applied electric field has been found in the vicinity of the Curie point. This may also have a number of applications, especially in those devices where an efficient tunable control of SHG intensity is demanded
Nonlinear optical properties of thiazolidinone derivatives
Thiazolidinone derivatives were synthesized and their physicochemical properties are determined by absorption, H NMR spectroscopies. The third order nonlinear optical properties of thiazolidinone containing compounds were investigated in solutions using degenerate four wave mixing (DFWM) method at 532 nm
Third order NLO properties of TTF-based self assembled molecular corners and polygons (poster presentation)
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