Spectroscopic analyses of Fe and water in clays: A Martian surface weathering study

Martian surface morphology suggests the presence of liquid H2O on Mars in the past. Reflectance spectra of the Martian surface include features which correspond to the crystal field transitions of iron, as well as features supporting the presence of ice and minerals containing structural OH and surface water. Researchers initiated further spectroscopic studies of surface iron and water and structural OH in clays in order to determine what remotely obtained spectra can indicate about the presence of clays on Mars based on a clearer understanding of the factors influencing the spectral features. Current technology allows researchers to better correlate the low frequency fundamental stretching and bending vibrations of O-H bonds with the diagnostic near infrared overtone and combination bands used in mineral characterization and identification

The Fecal Coliform/Fecal Streptococci Ratio (FC/FS) And Water Quality in the Bluegrass Region of Kentucky

In the mid 70\u27 s, someone noticed that the ratio of two indicator bacteria in fecal wastes - fecal coliforms (FC) and fecal streptococci (FS) - was characteristic of particular animal wastes. In human wastes, the fecal coliform/fecal streptococci ratio (FC/FS ratio) was greater than 4. In domesticated animals, like cattle, the ratio was between 0.1 and 4.0. In wild animals, the ratio was less than 0.1. Since that time, many attempts have been made to use the ratio to determine the source of fecal bacteria in contaminated ground water

Do Cover Crop Residue and No-Till Increase Poultry Litter Runoff?

Manure and litter produced during broiler production are an environmental issue in Kentucky. The most common and practical disposal method is to apply the poultry wastes to pasture and crop land. If the wastes are incorporated by tillage immediately after application to crop land, nitrogen that might otherwise be lost by ammonia volatilization is conserved. However, incorporating wastes is not possible in no-till, which is a best management practice (BMP) used by 51% of Kentucky\u27s farmers to control soil erosion. One question is whether surface application of poultry wastes onto no-till fields could increase fecal bacteria contamination of surrounding waterways if surface runoff occurs

Agricultural Impacts on Fecal Contamination of Shallow Groundwaters in the Bluegrass Region of Kentucky

Any farming practices that degrade water quality contribute to agricultural nonpoint source pollution. This is a problem in Kentucky\u27s Bluegrass region where shallow soils and karst geology permit surface contaminants to reach groundwater quickly. Real and perceived threats to public health may make groundwater protection plans a reality if evidence for non-point source pollution in agricultural areas continues to grow

Effective surface motion on a reactive cylinder of particles that perform intermittent bulk diffusion

In many biological and small scale technological applications particles may transiently bind to a cylindrical surface. In between two binding events the particles diffuse in the bulk, thus producing an effective translation on the cylinder surface. We here derive the effective motion on the surface, allowing for additional diffusion on the cylinder surface itself. We find explicit solutions for the number of adsorbed particles at one given instant, the effective surface displacement, as well as the surface propagator. In particular sub- and superdiffusive regimes are found, as well as an effective stalling of diffusion visible as a plateau in the mean squared displacement. We also investigate the corresponding first passage and first return problems.Comment: 26 pages, 5 figure

Who is in the transition gap? Transition from CAMHS to AMHS in the Republic of Ireland

Objective: The ITRACK study explored the process and predictors of transition between Child and Adolescent Mental Health Services (CAMHS) and Adult Mental Health Services (AMHS) in the Republic of Ireland. Method: Following ethical approval, clinicians in each of Ireland's four Health Service Executive (HSE) areas were contacted, informed about the study and invited to participate. Clinicians identified all cases who had reached the transition boundary (i.e. upper age limit for that CAMHS team ) between January and December 2010. Data were collected on clinical and socio-demographic details and factors that informed the decision to refer or not refer to AMHS and case notes were scrutinised to ascertain the extent of information exchanged between services during transition

Fecal Bacteria in Agricultural Waters of the Bluegrass Region of Kentucky

Agricultural runoff influenced by nonpoint pollution frequently exceeds the USEPA standards for bacterial contamination of primary contact water (200 fecal coliforms/100 mL). Few studies have evaluated the effect of cattle (Bos taurus) grazing on fecal contamination of ground water in the karst topography of central Kentucky. Our objectives were to: (i) observe the extent and pattern of fecal bacteria in agricultural waters from two central Kentucky watersheds; (ii) determine if monthly sampling accurately assessed the extent and variability of fecal contamination; and (iii) assess the fecal coliform/fecal streptococci ratio (FC/FS) as an indicator of fecal bacteria source. Springs, streams, and wells in two agricultural watersheds typical of central Kentucky were monitored for fecal coliform and fecal streptococci from December 1991 to January 1993. Springs and wells exceeded primary contact water standards, between 28 and 74% of the time; streams exceeded water quality standards between 87 and 100% of the time. When fecal bacteria were present, rainfall rapidly moved them from the soil surface into spring and well water. At two springs in Fleming county, only 29% of samples exceeded primary contact standards before cattle were present; 80% exceeded standards after cattle began grazing the surrounding pasture. Monthly sampling adequately reflected the extent of fecal contamination in our study, which had relatively continuous cattle grazing. Although the FC/FS ratio identified domestic animal contamination sources, it did not distinguish between domestic animal and human sources of contamination

How Do Bacteria Move Through Soil?

The contamination of water supplies by fecal bacteria is an important water quality issue in Kentucky. Contamination may come from point sources, such as straight pipes depositing raw sewage into streams, or nonpoint sources, such as manure runoff from cropland. A direct cost of contaminating water supplies is the expense that homesteads or water companies incur to chlorinate, filter, and otherwise treat water to make it potable. Indirect costs are the time lost to illness from drinking inadequately treated water, slower weight gain in livestock drinking contaminated water, and the degradation of aquatic habitats

Particle Size and Temperature Affect Fecal Bacteria Survival in Sediment

When cattle have direct access to streams, fecal bacteria concentrations in stream sediments increase. If these bacteria persist, and if the sediments are resuspended, fecal bacteria may also appear in surrounding water for extended periods. Why do fecal bacteria persist, since dry conditions, high acidity or alkalinity, sunlight, competition from native microbes, and extreme temperatures all diminish their populations in soil? The effects of these environmental factors are much reduced in sediment. Water protects fecal bacteria from desiccation and ultraviolet light. High temperatures can promote their regrowth in wet environments. Fecal bacteria also survive on fine-sized sediments in streams because the sediments have a high surface area. These factors may help explain our observations that streams flowing through pastures typically exceed Kentucky standards for primary contact water (200 fecal coliforms/100 ml) long after cattle depart. The fecal coliform/fecal streptococci ratio (FC/FS), is a tool in water quality assessment that diagnoses the source of fecal contamination, whether from people (FC/FS \u3e 4) or animals (FC/FS \u3c 0.1). The ratio is extremely variable and sensitive to the persistence of the indicator bacteria used in it. For example, we observed in central Kentucky streams that as the temperature increased during spring, the FC/FS ratio also increased. Fecal coliform growth shortly after manure deposition might explain some of the variability we have observed in our water monitoring studies. In this study we tried to account for the seasonal variability of FC/FS ratios in agricultural watersheds, and determine whether sediment particle size and water temperature interacted to influence fecal bacteria persistence and the FC/FS ratio

Effect of Sediment Particle Size and Temperature on Fecal Bacteria Mortality Rates and the Fecal Coliform/Fecal Streptococci Ratio

Extended survival of fecal bacteria in sediment can obscure the source and extent of fecal contamination in agricultural settings. The variability in fecal coliform/fecal streptococci (FC/FS) ratios with time and discrepancies between observable fecal sources and measured FC/FS ratios in shallow surface water from agricultural watersheds may be explained by examining FC and FS mortality rates in response to ambient temperature and sediment particle size. We measured FC and FS mortality rates at three different temperatures and in three feces-amended sediments with different particle size in a laboratory study. In controlled conditions, using physiological saline to reduce cell death by osmotic shock, FC mortality rates exceeded FS mortality rates. These rates declined as sediment particle-size shrank and as temperature decreased. There was no interaction between these two factors in determining fecal bacteria persistence. The apparent half-lives of FCs exceeded those of FS, even though mortality rates were higher, because of FC regrowth shortly after deposition. The FC/FS ratio is influenced by temperature, the presence of sediment, and sediment particle size. In warm conditions, FC regrowth increases FC/FS ratios to levels indicative of human contamination even where none clearly exists. These factors interfere with the interpretation of the FC/FS ratio and contribute to the difficulty of its use in agricultural settings