Observations of Extrasolar Planets During the non-Cryogenic Spitzer Space Telescope Mission

Precision infrared photometry from Spitzer has enabled the first direct studies of light from extrasolar planets, via observations at secondary eclipse in transiting systems. Current Spitzer results include the first longitudinal temperature map of an extrasolar planet, and the first spectra of their atmospheres. Spitzer has also measured a temperature and precise radius for the first transiting Neptune-sized exoplanet, and is beginning to make precise transit timing measurements to infer the existence of unseen low mass planets. The lack of stellar limb darkening in the infrared facilitates precise radius and transit timing measurements of transiting planets. Warm Spitzer will be capable of a precise radius measurement for Earth-sized planets transiting nearby M-dwarfs, thereby constraining their bulk composition. It will continue to measure thermal emission at secondary eclipse for transiting hot Jupiters, and be able to distinguish between planets having broad band emission versus absorption spectra. It will also be able to measure the orbital phase variation of thermal emission for close-in planets, even non-transiting planets, and these measurements will be of special interest for planets in eccentric orbits. Warm Spitzer will be a significant complement to Kepler, particularly as regards transit timing in the Kepler field. In addition to studying close-in planets, Warm Spitzer will have significant application in sensitive imaging searches for young planets at relatively large angular separations from their parent stars.Comment: 12 pages, 7 figures, to appear in "Science Opportunities for the Warm Spitzer Mission

Synthesis, Structure, and Properties of Compounds in the NaHSO_4−CsHSO_4 System. 1. Crystal Structures of Cs_2Na(HSO_4)_3 and CsNa_2(HSO_4_)3

Exploratory synthesis in the NaHSO₄-CsHSO₄ system, aimed at discovering novel proton conducting solids, resulted in the new compounds CsNa₂(HSO₄)₃ and Cs₂Na(HSO₄)₃. Single-crystal X-ray diffraction (performed at room temperature) revealed CsNa₂(HSO₄)₃ to crystallize in the cubic space group P2₁3 with lattice parameters a=10.568(2)Å and Z=4, whereas CS2Na(HSO₄)₃, studied by both single-crystal neutron and X-ray methods, crystallizes in the hexagonal space group P6₃/m. The latter compound has lattice parameters a=8.5712(17) and c=9.980(2)Å, and Z=2. The unit cell volumes are 1180.4(4) and 634.9(2)ų, respectively, giving calculated densities of 2.645 and 3.304 mg m⁻³. Refinement using all observed reflections yielded a weighted residual, R-w(F²), of 0.0515 based on F² X-ray values for CsNa₂(HSO₄)₃. For Cs₂Na(HSO₄)₃ the analogous X-ray and neutron values were 0.0483 and 0.1715, respectively. Both structures contain a single, crystallographically distinct, asymmetric hydrogen bond (as confirmed by NMR investigations) and unique, three-membered (HSO₄)₃ rings. The geometric match between the NaO₆ octahedra and the rings suggests the sodium polyhedra may serve to template the (HSO₄)₃ unit. In CsNa₂(HSO₄)₃ the rings form a distorted cubic close-packed array. The Cs atoms are located within the "octahedral" sites of this array, and the Na atoms, within the "tetrahedral" sites. The rings in CS₂Na(HSO₄)₃ are linked together by NaO6 octahedra to form infinite Na(HSO₄)₃ chains that extend along 001. The hexagonal compound exhibits disorder about the sulfate tetrahedron that suggests a P6₃/m → P6 phase transition may occur upon cooling

BMP action in skeletogenesis involves attenuation of retinoid signaling

The bone morphogenetic protein (BMP) and growth and differentiation factor (GDF) signaling pathways have well-established and essential roles within the developing skeleton in coordinating the formation of cartilaginous anlagen. However, the identification of bona fide targets that underlie the action of these signaling molecules in chondrogenesis has remained elusive. We have identified the gene for the retinoic acid (RA) synthesis enzyme Aldh1a2 as a principal target of BMP signaling; prochondrogenic BMPs or GDFs lead to attenuation of Aldh1a2 expression and, consequently, to reduced activation of the retinoid signaling pathway. Consistent with this, antagonism of retinoid signaling phenocopies BMP4 action, whereas RA inhibits the chondrogenic stimulatory activity of BMP4. BMP4 also down-regulates Aldh1a2 expression in organ culture and, consistent with this, Aldh1a2 is actively excluded from the developing cartilage anlagens. Collectively, these findings provide novel insights into BMP action and demonstrate that BMP signaling governs the fate of prechondrogenic mesenchyme, at least in part, through regulation of retinoid signaling

The first legal mortgagor: a consumer without adequate protection?

This article contends that the UK government’s attempt to create a well-functioning consumer credit market will be undermined if it fails to reform the private law framework relating to the first legal mortgage. Such agreements are governed by two distinct regulatory regimes that are founded upon very different conceptions of the mortgagor. The first, the regulation of financial services overseen by the Financial Conduct Authority, derives from public law and is founded upon a conception of the mortgagor as “consumer”. The other is land law, private law regulation implemented by the judiciary and underpinned by a conception of the mortgagor as “landowner”. Evidence suggests that the operation of these two regimes prevents mortgagors from receiving fair and consistent treatment. The current reform of financial services regulation therefore will change only one part of this governance regime and will leave mortgagors heavily reliant upon a regulator that still has to prove itself. What this article argues is that reform of the rules of private law must also be undertaken with the aim of initiating a paradigm shift in the conception of the mortgagor from “landowner” to “consumer”. Cultural shifts of this kind take time but the hope is that this conceptual transformation will occur in time to deter the predicted rise in mortgage possessions

Exoplanet phase curves: observations and theory

Phase curves are the best technique to probe the three dimensional structure of exoplanets' atmospheres. In this chapter we first review current exoplanets phase curve observations and the particular challenges they face. We then describe the different physical mechanisms shaping the atmospheric phase curves of highly irradiated tidally locked exoplanets. Finally, we discuss the potential for future missions to further advance our understanding of these new worlds.Comment: Fig.5 has been updated. Table 1 and corresponding figures have been updated with new values for WASP-103b and WASP-18b. Contains a table sumarizing phase curve observation

Detection of a Westward Hotspot Offset in the Atmosphere of a Hot Gas Giant CoRoT-2b

Short-period planets exhibit day-night temperature contrasts of hundreds to thousands of degrees K. They also exhibit eastward hotspot offsets whereby the hottest region on the planet is east of the substellar point; this has been widely interpreted as advection of heat due to eastward winds. We present thermal phase observations of the hot Jupiter CoRoT-2b obtained with the IRAC instrument on the Spitzer Space Telescope. These measurements show the most robust detection to date of a westward hotspot offset of 23 $\pm$ 4 degrees, in contrast with the nine other planets with equivalent measurements. The peculiar infrared flux map of CoRoT-2b may result from westward winds due to non-synchronous rotation magnetic effects, or partial cloud coverage, that obscures the emergent flux from the planet's eastern hemisphere. Non-synchronous rotation and magnetic effects may also explain the planet's anomalously large radius. On the other hand, partial cloud coverage could explain the featureless dayside emission spectrum of the planet. If CoRoT-2b is not tidally locked, then it means that our understanding of star-planet tidal interaction is incomplete. If the westward offset is due to magnetic effects, our result represents an opportunity to study an exoplanet's magnetic field. If it has Eastern clouds, then it means that our understanding of large-scale circulation on tidally locked planets is incomplete.Comment: 30 pages, 4 figures, 15 supplementary figure

Fungal Planet description sheets: 1436–1477

Novel species of fungi described in this study include those from various countries as follows: Argentina, Colletotrichum araujiae on leaves, stems and fruits of Araujia hortorum. Australia, Agaricus pateritonsus on soil, Curvularia fraserae on dying leaf of Bothriochloa insculpta, Curvularia millisiae from yellowing leaf tips of Cyperus aromaticus, Marasmius brunneolorobustus on well-rotted wood, Nigrospora cooperae from necrotic leaf of Heteropogon contortus, Penicillium tealii from the body of a dead spider, Pseudocercospora robertsiorum from leaf spots of Senna tora, Talaromyces atkinsoniae from gills of Marasmius crinis-equi and Zasmidium pearceae from leaf spots of Smilax glyciphylla. Brazil, Preussia bezerrensis from air. Chile, Paraconiothyrium kelleni from the rhizosphere of Fragaria chiloensis subsp. chiloensis f. chiloensis. Finland, Inocybe udicola on soil in mixed forest with Betula pendula, Populus tremula, Picea abies and Alnus incana. France, Myrmecridium normannianum on dead culm of unidentified Poaceae. Germany, Vexillomyces fraxinicola from symptomless stem wood of Fraxinus excelsior. India, Diaporthe limoniae on infected fruit of Limonia acidissima, Didymella naikii on leaves of Cajanus cajan, and Fulvifomes mangroviensis on basal trunk of Aegiceras corniculatum. Indonesia, Penicillium ezekielii from Zea mays kernels. Namibia, Neocamarosporium calicoremae and Neocladosporium calicoremae on stems of Calicorema capitata, and Pleiochaeta adenolobi on symptomatic leaves of Adenolobus pechuelii. Netherlands, Chalara pteridii on stems of Pteridium aquilinum, Neomackenziella juncicola (incl. Neomackenziella gen. nov.) and Sporidesmiella junci from dead culms of Juncus effusus. Pakistan, Inocybe longistipitata on soil in a Quercus forest. Poland, Phytophthora viadrina from rhizosphere soil of Quercus robur, and Septoria krystynae on leaf spots of Viscum album. Portugal (Azores), Acrogenospora stellata on dead wood or bark. South Africa, Phyllactinia greyiae on leaves of Greyia sutherlandii and Punctelia anae on bark of Vachellia karroo. Spain, Anteaglonium lusitanicum on decaying wood of Prunus lusitanica subsp. lusitanica, Hawksworthiomyces riparius from fluvial sediments, Lophiostoma carabassense endophytic in roots of Limbarda crithmoides, and Tuber mohedanoi from calcareus soils. Spain (Canary Islands), Mycena laurisilvae on stumps and woody debris. Sweden, Elaphomyces geminus from soil under Quercus robur. Thailand, Lactifluus chiangraiensis on soil under Pinus merkusii, Lactifluus nakhonphanomensis and Xerocomus sisongkhramensis on soil under Dipterocarpus trees. Ukraine, Valsonectria robiniae on dead twigs of Robinia hispida. USA, Spiralomyces americanus (incl. Spiralomyces gen. nov.) from office air. Morphological and culture characteristics are supported by DNA barcodes

Antibacterial Activity of Phenolic Compounds Against the Phytopathogen Xylella fastidiosa

Xylella fastidiosa is a pathogenic bacterium that causes diseases in many crop species, which leads to considerable economic loss. Phenolic compounds (a group of secondary metabolites) are widely distributed in plants and have shown to possess antimicrobial properties. The anti-Xylella activity of 12 phenolic compounds, representing phenolic acid, coumarin, stilbene and flavonoid, was evaluated using an in vitro agar dilution assay. Overall, these phenolic compounds were effective in inhibiting X. fastidiosa growth, as indicated by low minimum inhibitory concentrations (MICs). In addition, phenolic compounds with different structural features exhibited different anti-Xylella capacities. Particularly, catechol, caffeic acid and resveratrol showed strong anti-Xylella activities. Differential response to phenolic compounds was observed among X. fastidiosa strains isolated from grape and almond. Elucidation of secondary metabolite-based host resistance to X. fastidiosa will have broad implication in combating X. fastidiosa-caused plant diseases. It will facilitate future production of plants with improved disease resistance properties through genetic engineering or traditional breeding approaches and will significantly improve crop yield