Assessing the Accuracy of Complex Refractive Index Retrievals from Single Aerosol Particle Cavity Ring-Down Spectroscopy

<p>Cavity ring-down spectroscopy (CRDS) of single, optically manipulated aerosol particles affords quantitative retrieval of refractive indices for particles of fixed or evolving composition with high precision. Here, we quantify the accuracy with which refractive index determinations can be made by CRDS for single particles confined within the core of a Bessel laser beam and how that accuracy is degraded as the particle size is progressively reduced from the coarse mode (>1 μm radius) to the accumulation mode (<500 nm radius) regime. We apply generalized Lorenz–Mie theory to the intra-cavity standing wave to explore the effect of particle absorption on the distribution of extinction cross section determinations resulting from stochastic particle motion in the Bessel beam trap. The analysis provides an assessment of the accuracy with which the real, <i>n</i>, and imaginary, κ, components of the refractive index can be determined for a single aerosol particle.</p> <p>Published with license by American Association for Aerosol Research</p> <p><a href="https://www.tandfonline.com/pb-assets/tandf/Migrated/UAST_VideoAbstract_Transcript.pdf" target="_blank">Read the transcript</a></p> <p><a href="https://vimeo.com/263371383" target="_blank">Watch the video on Vimeo</a></p

Optical extinction efficiency measurements on fine and accumulation mode aerosol using single particle cavity ring-down spectroscopy

We report a new single aerosol particle approach using cavity ringdown spectroscopy to accurately determine optical extinction cross sections at multiple wavelengths.</p

Tuning photochemistry:substituent effects on πσ* state mediated bond fission in thioanisoles

The electronic branching in the thiophenoxyl radicals formed by UV photolysis of thioanisole can be tuned by placing electron withdrawing/donating substituents at the 4-position.</p