Reverse osmosis membrane composition, structure and performance modification by bisulphite, iron(III), bromide and chlorite exposure

Reverse osmosis (RO) membrane exposure to bisulphite, chlorite, bromide and iron(III) was assessed in terms of membrane composition, structure and performance. Membrane composition was determined by Rutherford backscattering spectrometry (RBS) and membrane performance was assessed by water and chloride permeation, using a modified version of the solution-diffusion model. Iron(III) dosage in presence of bisulphite led to an autooxidation of the latter, probably generating free radicals which damaged the membrane. It comprised a significant raise in chloride passage (chloride permeation coefficient increased 5.3–5.1 fold compared to the virgin membrane under the conditions studied) rapidly. No major differences in terms of water permeability and membrane composition were observed. Nevertheless, an increase in the size of the network pores, and a raise in the fraction of aggregate pores of the polyamide (PA) layer were identified, but no amide bond cleavage was observed. These structural changes were therefore, in accordance with the transport properties observed.Peer ReviewedPostprint (author's final draft

Multicriteria evaluation of novel technologies for organic micropollutants removal in advanced water reclamation schemes for indirect potable reuse

Postprint (author's final draft

Determination of dimethyl selenide and dimethyl sulphide compounds causing off-flavours in bottled mineral waters

Sales of bottled drinking water have shown a large growth during the last two decades due to the general belief that this kind of water is healthier, its flavour is better and its consumption risk is lower than that of tap water. Due to the previous points, consumers are more demanding with bottled mineral water, especially when dealing with its organoleptic properties, like taste and odour. This work studies the compounds that can generate obnoxious smells, and that consumers have described like swampy, rotten eggs, sulphurous, cooked vegetable or cabbage. Closed loop stripping analysis (CLSA) has been used as a pre-concentration method for the analysis of off-flavour compounds in water followed by identification and quantification by means of GC-MS. Several bottled water with the aforementioned smells showed the presence of volatile dimethyl selenides and dimethyl sulphides, whose concentrations ranged, respectively, from 4 to 20 ng/L and from 1 to 63 ng/L. The low odour threshold concentrations (OTCs) of both organic selenide and sulphide derivatives prove that several objectionable odours in bottled waters arise from them. Microbial loads inherent to water sources, along with some critical conditions in water processing, could contribute to the formation of these compounds. There are few studies about volatile organic compounds in bottled drinking water and, at the best of our knowledge, this is the first study reporting the presence of dimethyl selenides and dimethyl sulphides causing odour problems in bottled watersPostprint (published version

Characterization of natural Yemeni zeolites as powder sorbents for ammonium valorization from domestic waste water streams using high rate activated sludge processes

BACKGROUND In this study three natural Yemeni zeolites (NZ1, NZ2 and NZ3) having major minerals such as clinoptilolite and mordenite, were evaluated as low cost sorbents for the removal and recovery of ammonium ions. RESULTS The zeolite samples, with pHPZC =¿9.1¿±¿0.2, 7.9¿±¿0.2 and 7.4¿±¿0.2 for NZ1, NZ2 and NZ3, respectively, showed high ammonium sorption capacities. At pH¿8, for treated waste waters: (i) with low NH4+ levels (from 25 to 100 mgNH4/L); and (ii) for concentrated NH4+ side streams generated from the anaerobic digestion of sewage sludge (from 400 up to 1500¿mg L-1), maximum loading capacities of 27 to 51 mgNH4 g-1 were measured for the studied zeolites. Measured sorption isotherms, in the concentration range 0.05 to 5¿g L-1, were well described by the Langmuir isotherm. The ammonium sorption kinetics was controlled by particle diffusion and was well described by both the homogeneous diffusion (HPDM) and shell progressive (SPM) models. CONCLUSION Comparison of the equilibrium data with results for natural and synthetic zeolites demonstrate the higher performance of the studied zeolites providing low residual ammonium values <1 mgNH4 g-1 and <10 mgNH4 g-1 when treating both diluted and concentrated-NH4+ streams, respectively.Preprin

Trace ions rejection tunning in NF by selecting solution composition: Ion permeances estimation

Nanofiltration (NF) is suggested to selectively remove ionic species in aqueous process streams taking benefit of both membrane and aqueous solution composition. The importance of predicting and optimizing selective ion rejections by NF not only of major compounds (e.g. NaCl, Na2SO4, MgCl2, MgSO4) but also of minor ones such as ammonium (NH4+), nitrate (NO3-), bromide (Br-), iodide (I-) typically present in natural and industrial process streams is crucial. The current work explores ion rejection patterns and membrane ion permeances using the phenomenological Solution-Electro-Diffusion-Film (SEDF) model. It makes possible rapid calculations that account for the effects of spontaneously arising electric fields on rejections. Experimental ion rejection data of several inorganic ions species at various transmembrane pressures and at fixed cross-flow velocity have been obtained with NF270 membrane. A number of trace ions (Na+, K+, Cl-, Ca2+, Mg2+, SO42-, NO3-, NH4+, Br-and I-) have been used in combination with various dominant salts (NaCl, MgCl2, MgSO4) as model feed solutions. Results showed that dominant salts were moderately (NaCl) and highly (MgCl2, MgSO4) rejected when some ions are divalent, while trace ions exhibited quite variable rejection, including negative ones mainly at low transmembrane volume flows. The electric field of membrane potential can accelerate or retard the ion flows to the permeate, so negative or unexpectedly high rejections could be observed. Ions transport was shown to be affected by the membrane chemistry (e.g. acid-base properties of the un-crosslinked carboxylic and amine groups) and the dielectric exclusion phenomena. From the modelling procedure, ionic membrane permeances were determined for various multi-ion systems studied. Results showed that nature of dominant salt composition can be used to control the rejection of minor components.Peer ReviewedPostprint (author's final draft

Las mediciones de la calidad del aprendizaje matemático en México: ¿qué nos devela la prueba PISA 2003 y cómo podemos responder?

Este ensayo aporta elementos para delinear una agenda que efectivamente responda a la realidad que develan las mediciones de la calidad de la educación básica en el caso de las matemáticas en México. El ensayo se centra en la prueba PISA 2003, instrumentada por la OCDE. Está dividido en dos partes: la primera está dedicada a especificar los retos educativos en matemáticas que develó la prueba PISA 2003 en el caso mexicano; la segunda está dedicada a enmarcar los retos conceptuales implícitos en el desarrollo de intervenciones educativas eficaces en contextos institucionales en los que adquieren gran importancia los resultados de pruebas estandarizadas como la de PISA 2003. Se distingue entre dos racionalidades básicas implícitas en los programas de mejoramiento de la enseñanza matemática: la descendente y la ascendente. Se explica por qué la racionalidad ascendente puede ser más pertinente para el caso mexicano

Selectrodialysis and bipolar membrane electrodialysis combination for industrial process brines treatment: Monovalent-divalent ions separation and acid and base production

Chemical industries generate large amounts of wastewater rich in different chemical constituents. Amongst these, salts at high concentrations are of major concern, making necessary the treatment of saline effluents before discharge. Because most of these rejected streams comprise a combination of more than one salt at high concentration, it is reasonable to try to separate and revalorize them to promote circular economy at industry site level. For this reason, ion-exchange membranes based technologies were integrated in this study: selectrodialysis (SED) and electrodialysis with bipolar membranes (EDBM). Different process brines composed by Na2SO4 and NaCl at different concentrations were treated first by SED to separate each salt, and then by EDBM to produce base (NaOH) and acids (HCl and H2SO4) from each salt. The optimum of both electrolyte nature and concentration of the SED stack streams was evaluated. Results indicated that it was possible to separate Cl- and SO42- depending on the anionic membrane, initial electrolytes and concentrations of each stream. Pure NaOH and a mixture of HCl and H2SO4 with different purities could be obtained. Energy consumption evolutions were plotted and an optimal zone work was found where the consumption values were acceptable.Peer ReviewedPostprint (author's final draft

Rosbi y las matemáticas

Este escrito está basado en la entrevista que se realizó a una estudiante de primero de secundaria (13 años) de una escuela pública urbana mexicana. En la entrevista, la alumna describe la transformación que experimentó como estudiante en la clase de matemáticas a lo largo de su primer año de educación secundaria. Esta transformación implicó, además de un cambio de actitud hacia las matemáticas, un mejoramiento importante en su manera de participar en clase y en su aprovechamiento. En el escrito se explica de qué modo la experiencia de esta alumna puede orientar a los maestros de matemáticas que realizan su labor en América Latina en sus esfuerzos para ayudar a que mejoren sus estudiantes rezagados

Investigar las fracciones: experiencias inspiradas en la metodología de los experimentos de diseño

Se discuten las aportaciones a la didáctica de las fracciones de cuatro investigaciones que el autor y sus colegas han realizado, retomando algunos aspectos de la metodología de los experimentos de diseño. Estas aportaciones conciernen a la puntualización de los objetivos de aprendizaje de las fracciones, la identificación de puntos de partida para la enseñanza y el desarrollo de propuestas alternativas para apoyar el aprendizaje de este concepto