Static and dynamic failure load of fiber-reinforced composite and particulate filler composite cantilever resin-bonded fixed dental prostheses

Purpose: The aim of this study was to evaluate in vitro the influence of fiber reinforcement and luting cement on the static failure load (SFL) and dynamic failure load (DFL) of simulated two-unit cantilever resin-bonded fixed dental prostheses (RBFDPs). Materials and Methods: Forty-six particulate filler composite (PFC) beams and 76 fiber-reinforced composite (FRC) beams were prefabricated and subsequently luted (RelyX ARC or Panavia F2.0) onto flat ground bovine enamel. The SFL of the different specimen types was determined with a peel test and the DEL was determined with a rotating cantilever beam fatigue testing device. Results: The PFC specimens showed a significantly lower SFL than the FRC specimens. The luting cement showed a significant effect on the SFL of the PFC specimens, but not with FRC. The DEL of PFC specimens was significantly lower than for FRC specimens. The luting cement showed a significant effect on the DFL of the PFC specimens, but not so with FRC. With both the SFL and the DEL tests all PFC beams fractured, leaving the bonded part on the tooth surface, but FRC beams partially debonded from the tooth surface, leaving fibers connected to the enamel surface to a varying extent. Coincidentally, the uncured fibers turned out to be prone to aging, an effect which has been investigated. Conclusion: Within the limitations of this study, it can be concluded that PFC without fiber reinforcement is not suitable for the fabrication of two-unit cantilever RBFDPs, despite the significant effect of the luting cement, but FRC is suitable

Three-dimensional finite element analysis of anterior two-unit cantilever resin-bonded fixed dental prostheses

The aim of this study was to evaluate the influence of different framework materials on biomechanical behaviour of anterior two-unit cantilever resin-bonded fixed dental prostheses (RBFDPs). A three-dimensional finite element model of a two-unit cantilever RBFDP replacing amaxillary lateral incisorwas created. Five frameworkmaterialswere evaluated: direct fibre-reinforced composite (FRC-Z250), indirect fibre-reinforced composite (FRC-ES), gold alloy (M), glass ceramic (GC), and zirconia (ZI). Finite element analysis was performed and stress distribution was evaluated. A similar stress pattern, with stress concentrations in the connector area, was observed in RBFDPs for all materials.Maximal principal stress showed a decreasing order: ZI >M>GC> FRC-ES > FRCZ250. The maximum displacement of RBFDPs was higher for FRC-Z250 and FRC-ES than for M, GC, and ZI. FE analysis depicted differences in location of the maximum stress at the luting cement interface between materials. For FRC-Z250 and FRC-ES, the maximum stress was located in the upper part of the proximal area of the retainer, whereas, for M, GC, and ZI, the maximum stress was located at the cervical outline of the retainer. The present study revealed differences in biomechanical behaviour between all RBFDPs.The general observation was that a RBFDP made of FRC provided a more favourable stress distribution

Effect of hydrothermal aging on the microhardness of high- and low-viscosity conventional and additively manufactured polymers.

STATEMENT OF PROBLEM Studies on the microhardness of novel additively manufactured polymers compared with well-established low- and high-viscosity composite resins with regard to chemical composition are lacking. PURPOSE The purpose of this in vitro study was to evaluate the effect of hydrothermal aging on the microhardness of various conventional and additively manufactured polymers. MATERIAL AND METHODS Cylindrically shaped specimens (N=240, n=10 per group) (Ø10×2 mm) were either additively manufactured (6 groups) or conventionally (6 groups) manufactured by using 3D (Optiprint Temp [OP; Dentona]; C&B MFH [ND; NextDent]; Saremco print CROWNTEC [SA; Saremco Dental AG]; Temp Print [TP; GC]; 3DELTA ETEMP [DM; Deltamed]; MED690 [ST; Stratasys, Ltd]) or conventional low (Gradia Direct [GR; GC]; Clearfil Majesty [CM; Kuraray Noritake]; Tetric EvoCeram [TE; Ivoclar Vivadent AG]) and high (Gradia Direct Flo [GR-F; GC]; Clearfil Majesty Flow [CM-F; Kuraray Noritake]; Tetric EvoFlow [TE-F; Ivoclar Vivadent AG]) viscous materials. All specimens were randomly allotted to 2 different aging methods (no-aging [dry] or aging by thermocycling [TC], ×6000, 5 °C-55 °C) and Vickers hardness (VH) tested (ZHV30; Zwick). Three indentations were made on each specimen (0.98-N load, duration 15 seconds). The calculated average microhardness value of each specimen was statistically analyzed by using 2-way ANOVA and Tukey post hoc tests (α=.05). Two-parameter Weibull distribution was calculated to predict the reliability of material type and aging method on VH. RESULTS The mean ±standard deviation VH ranged between 17 ±0.5 VHN and 68 ±0.5 VHN in the following ascending order: group STa.05). The mean ±standard deviation of HV for aged (37 ±1 VHN) and nonaged (35 ±1 VHN) specimens were statistically similar (P>.05). The Weibull distribution values presented the highest shape for the aged group SA (37.81). CONCLUSIONS The choice of the material had a significant effect and resulted in lower hardness for the 3-dimensionally printed materials than for the conventional composite resins. Under fatigue conditions, the choice of the material showed no significant difference when the Vickers microhardness was evaluated

Synthesis, spectroscopy and photophysical properties of ruthenium triazole complexes and their application as dye-molecules in regenerative solar cells

The complexes [Ru(dcb)2(L)] (L = 3-(2-phenol)-5-(pyridin-2-yl)-1,2,4-triazole (2-ppt), 3-(4-phenol)-5-(pyridin-2-yl)-1,2,4-triazole (4-ppt), 3,5-bis(pyrazin-2-yl)-1,2,4-triazole (bpzt), 3-(2-phenol)-5-(pyrazin-2-yl)-1,2,4-triazole (2-ppzt) and dcb = 4,4’-(CO2H)2-2,2’-bipyridine) have been synthesized, spectroscopically characterized and anchored to nanocrystalline TiO2 electrodes for the conversion of light into electricity in regenerative solar cells. The different efficiencies observed have been rationalized on the basis of an analytical expression relating the incident photon-to-current-conversion efficiency (IPCE) to the kinetic parameters of the relevant electron transfer processes involved in the solar cell

Enhanced Osteogenic and Vasculogenic Differentiation Potential of Human Adipose Stem Cells on Biphasic Calcium Phosphate Scaffolds in Fibrin Gels

For bone tissue engineering synthetic biphasic calcium phosphate (BCP) with a hydroxyapatite/ -tricalcium phosphate (HA/ -TCP) ratio of 60/40 (BCP60/40) is successfully clinically applied, but the high percentage of HA may hamper efficient scaffold remodelling. Whether BCP with a lower HA/ -TCP ratio (BCP20/80) is more desirable is still unclear. Vascular development is needed before osteogenesis can occur. We aimed to test the osteogenic and/or vasculogenic differentiation potential as well as degradation of composites consisting of human adipose stem cells (ASCs) seeded on BCP60/40 or BCP20/80 incorporated in fibrin gels that trigger neovascularization for bone regeneration. ASC attachment to BCP60/40 and BCP20/80 within 30 min was similar (>93%). After 11 days of culture BCP20/80-based composites showed increased alkaline phosphatase activity and DMP1 gene expression, but not RUNX2 and osteonectin expression, compared to BCP60/40-based composites. BCP20/80-based composites also showed enhanced expression of the vasculogenic markers CD31 and VEGF189, but not VEGF165 and endothelin-1. Collagen-1 and collagen-3 expression was similar in both composites. Fibrin degradation was increased in BCP20/80-based composites at day 7. In conclusion, BCP20/80-based composites showed enhanced osteogenic and vasculogenic differentiation potential compared to BCP60/40-based composites in vitro, suggesting that BCP20/80-based composites might be more promising for in vivo bone augmentation than BCP60/40-based composites

Fatigue resistance of composite resins and glass-ceramics on dentin and enamel

Statement of problem: Composite resins and glass-ceramics are both used to restore worn teeth. Which restoration material is more durable is unclear. Purpose: The purpose of this in vitro study was to evaluate the load to failure of thin composite resins and glass-ceramic restorations on enamel and dentin under increasing repetitive loads. Material and methods: Glass-ceramic blocks (IPS e.max CAD; Ivoclar Vivadent AG) were shaped into cylinders (Ø4.0×1.0 mm), crystallized, and adhesively luted to bovine dentin and enamel substrates that were embedded in polymethyl methacrylate (n=20). Identical direct composite resin restorations (Clearfil AP-X; Kuraray Noritake Dental Inc) were made and directly applied on the same substrates (n=20). All specimens were tested in a pneumatic device with a stainless steel ball that provided a stepwise increase of the load (N) starting at 250 N and increasing by 50 N after every 10 000 cycles to a maximum of 1150 N. Failures were detected by a displacement sensor and defined by chipping of restorative material or catastrophic failure. Results: On dentin, composite resin showed a significantly higher fatigue resistance than glass-ceramic. On enamel, no significant difference was found between the 2 materials. Conclusions: When bonded to dentin, thin direct composite resin restorations were more durable than glass-ceramics. When bonded to enamel, no difference was found

Wear of direct resin composites and teeth : considerations for oral rehabilitation

Little is known about the wear rate of enamel and dentin opposing resin composite following restoration of the occlusal surface in patients with tooth wear. Hence, the aim of this in vitro study was to evaluate the wear of enamel and dentin surfaces when opposing each of three resin composites in a two-body and three-body wear test. The two-body and three-body wear of dentin, enamel, and three resin composites (Clearfil AP-X, Filtek Z250, and Filtek Supreme) opposing four antagonists (stainless steel and three resin composites) were evaluated using the ACTA wear machine. In addition, all the surfaces were evaluated with scanning electron microscopy. The results showed the lowest wear rate in enamel and the highest in dentine, with the composite showing intermediate wear rates. The three-body wear results were not affected by the antagonist and showed pure wear caused by the abrasive food medium. The in vitro enamel/composite wear ratio was 2.5. The results show that tooth wear accelerates as soon as enamel disappears and dentin is exposed to composite resin. Therefore, it is important to protect dentin with a restorative material