Avoided crossing resonances: structural and dynamical aspects

We examine structural and dynamical properties of quantum resonances associated with an avoided crossing and identify the parameter shifts where these properties attain maximal or extreme values, first at a general level, and then for a two-level system coupled to a harmonic oscillator, of the type commonly found in quantum optics. Finally the results obtained are exemplified and applied to optimize the fidelity and speed of quantum gates in trapped ions.Comment: 4 pages, 1 figur

Population Pressure and Migration: Implications for Upland Development in the Philippines

This paper is based largely on the integrated summary report entitled “Population Pressure and Migration: Implications for Upland Development,” PIDS Working Paper 86-02. It discusses the role of population pressure and migration in Philippine upland development. It employs three levels of analysis using combined macro and micro data: identification of upland sites using topographic maps and serial photographs, identification of major migration streams and analysis of upland migration from the perspective of micro, village-level information.population and family relation, uplands, migration

Population Pressure and Migration: Implications for Upland Development in the Philippines

This paper is based largely on the integrated summary report entitled “Population Pressure and Migration: Implications for Upland Development,” PIDS Working Paper 86-02. It discusses the role of population pressure and migration in Philippine upland development. It employs three levels of analysis using combined macro and micro data: identification of upland sites using topographic maps and serial photographs, identification of major migration streams and analysis of upland migration from the perspective of micro, village-level information.population and family relation, uplands, migration

Integrated Summary Report-Population Pressure and Migration: Implications for Upland Development

population and family relation, uplands, migration, urban development

Differential medial temporal lobe morphometric predictors of item- and relational-encoded memories in healthy individuals and in individuals with mild cognitive impairment and Alzheimer's disease.

INTRODUCTION:Episodic memory processes are supported by different subregions of the medial temporal lobe (MTL). In contrast to a unitary model of memory recognition supported solely by the hippocampus, a current model suggests that item encoding engages perirhinal cortex, whereas relational encoding engages parahippocampal cortex and the hippocampus. However, this model has not been examined in the context of aging, neurodegeneration, and MTL morphometrics. METHODS:Forty-four healthy subjects (HSs) and 18 cognitively impaired subjects (nine mild cognitive impairment [MCI] and nine Alzheimer's disease [AD] patients) were assessed with the relational and item-specific encoding task (RISE) and underwent 3T magnetic resonance imaging. The RISE assessed the differential contribution of relational and item-specific memory. FreeSurfer was used to obtain measures of cortical thickness of MTL regions and hippocampus volume. RESULTS:Memory accuracies for both item and relational memory were significantly better in the HS group than in the MCI/AD group. In MCI/AD group, relational memory was disproportionately impaired. In HSs, hierarchical regressions demonstrated that memory was predicted by perirhinal thickness after item encoding, and by hippocampus volume after relational encoding (both at trend level) and significantly by parahippocampal thickness at associative recognition. The same brain morphometry profiles predicted memory accuracy in MCI/AD, although more robustly perirhinal thickness for item encoding (R2 = 0.31) and hippocampal volume and parahippocampal thickness for relational encoding (R2 = 0.31). DISCUSSION:Our results supported a model of episodic memory in which item-specific encoding was associated with greater perirhinal cortical thickness, while relational encoding was associated with parahippocampal thickness and hippocampus volume. We identified these relationships not only in HSs but also in individuals with MCI and AD. In the subjects with cognitive impairment, reductions in hippocampal volume and impairments in relational memory were especially prominent

Mechanism of Catalytic Water Oxidation by the Ruthenium Blue Dimer Catalyst: Comparative Study in D2O versus H2O

Water oxidation is critically important for the development of energy solutions based on the concept of artificial photosynthesis. In order to gain deeper insight into the mechanism of water oxidation, the catalytic cycle for the first designed water oxidation catalyst, cis,cis-[(bpy)2(H2O)RuIIIORuIII(OH2)(bpy)2]4+ (bpy is 2,2-bipyridine) known as the blue dimer (BD), is monitored in D2O by combined application of stopped flow UV-Vis, electron paramagnetic resonance (EPR) and resonance Raman spectroscopy on freeze quenched samples. The results of these studies show that the rate of formation of BD[4,5] by Ce(IV) oxidation of BD[3,4] (numbers in square bracket denote oxidation states of the ruthenium (Ru) centers) in 0.1 M HNO3, as well as further oxidation of BD[4,5] are slower in D2O by 2.1–2.5. Ce(IV) oxidation of BD[4,5] and reaction with H2O result in formation of an intermediate, BD[3,4]′, which builds up in reaction mixtures on the minute time scale. Combined results under the conditions of these experiments at pH 1 indicate that oxidation of BD[3,4]′ is a rate limiting step in water oxidation with the BD catalyst

The mechanism of silver(I) oxide formation on polycrystalline silver in alkaline solution. Determination of nucleation and growth rates

The nucleation and growth of Ag(I) oxide layers on polycrystalline Ag electrodes is studied by potentiodynamic and potentiostatic current transients in 0.1 M NaOH. A model involving the diffusion controlled growth of a basal layer followed by the nucleation and growth of a secondary layer is proposed. Various nucleation parameters are estimated by comparing experimental data with simulated transients, and the results are discussed in terms of the atomistic theory of electrochemical phase formation. The influence of the nucleation parameters on the shape of the current transients is analysed and some controversial results in the literature are explained.Instituto de Investigaciones Fisicoquímicas Teóricas y AplicadasFacultad de Ciencias Exacta

The mechanism of silver(I) oxide formation on polycrystalline silver in alkaline solution. Determination of nucleation and growth rates

The nucleation and growth of Ag(I) oxide layers on polycrystalline Ag electrodes is studied by potentiodynamic and potentiostatic current transients in 0.1 M NaOH. A model involving the diffusion controlled growth of a basal layer followed by the nucleation and growth of a secondary layer is proposed. Various nucleation parameters are estimated by comparing experimental data with simulated transients, and the results are discussed in terms of the atomistic theory of electrochemical phase formation. The influence of the nucleation parameters on the shape of the current transients is analysed and some controversial results in the literature are explained.Instituto de Investigaciones Fisicoquímicas Teóricas y AplicadasFacultad de Ciencias Exacta