Life cycle and environmental assessment of calcium looping (CaL) in solar thermochemical energy storage

Calcium looping is a promising thermochemical energy storage process to be integrated into concentrating solar power plants. This work develops for the first time a comprehensive life cycle assessment of the calcium looping integration in solar plants to assess the potential of the technology from an environmental perspective. Two representative integrations are analysed, representing daily (hot) and seasonal (cold) storage designs. Similar performance environmental impacts are observed in both, with slightly better results for the seasonal storage case due to the simplified energy storage integration. The results show the moderate environmental impact of calcium looping thermochemical energy storage technology, resulting in lower equivalent carbon dioxide emissions 24 kg/MWh) than other energy storage options such as molten salt-based solar facilities (40 kg/MWh). Plant construction involves a higher energy demand for the process, whilst the operation and maintenance on the plant represent a moderate impact due to the low environmental impact of limestone, the unique raw material of the process, and the lower water consumption compared to typical concentrating solar power plants. Besides, the energy required for the system is first time analysed, obtaining an energy payback time of 2.2 years and 2.5 years depending on the storage strategy design.Unión Europea - Horizonte 2020 No 727348Junta de Andalucía PY20 RE00

Influence of quality attributes of early, intermediate and late peach varieties on suitability for fresh-convenience products

Fresh convenience products represent a category of minimally processed fruit and vegetables (chunks, mousse, smoothies) that respond to the changes in consumer attitudes. Thanks to the image of convenience (time-saving, snack sizes, no waste, smart packaging) and healthiness their sales are steadily increasing. In this study 26 varieties (including peach, nectarines, and clingstone peaches) from Apulian production were divided into three groups according to harvest dates in early (A), middle (B) and late (C) maturing. Physical, chemical and sensorial analyses were performed in order to select high quality fruits for minimal processing according to the harvesting season. A multivariate Principal Component Analysis was applied to discriminate different varieties for quality attributes. Within Group A, ‘Honey Kist’ showed the lowest acidity and intermediate susceptibility to mechanical damage. For Group B, ‘Stark Red Gold’, ‘Zee Glo’ and ‘Venus’ resulted different in sensorial evaluation, while ‘Loadel’ and ‘Eolia’ were more susceptible to browning. For Group C, ‘Tardi Belle’ and ‘Baby Gold7’, although more sensitive to mechanical damage, were differentiated for flavor. Results of this work confirm the extreme variability among varieties in terms of sensorial quality, susceptibility to browning and to mechanical damage, and the importance of assessing varietal screening for selection of most suitable varieties for minimal processing

Effect of type of fertilization and maturity on quality of fresh-cut red and yellow peppers (Capsicum annuum L.)

The aim of this work was to evaluate the effect of the type of fertilization (mineral and combined fertilization with compost in pre-transplant plus mineral addition during cultivation) and stage of maturity at harvest (mature-green and full-colored) on post-cutting quality of red and yellow ‘Cazzone’ peppers. Peppers were cut into strips, and air-stored for 8 days at 5°C. During storage, color, appearance score, firmness, respiration rate, soluble solids, acidity, pH, vitamin C, total phenols, and antioxidant activity were measured. The maturity stage influenced color parameters and soluble solids, acidity and pH for both yellow and red types. Full-colored peppers showed a lower respiration rate, and higher SSC than mature-green peppers; for the yellow type, a lower firmness value was observed for full-colored fruits compared to the mature-green ones. A lower antioxidant activity was also observed in the yellow type fertilized with the combined treatment, while phenol content in full-colored peppers was higher than in mature-green ones. Fresh-cut yellow peppers showed higher susceptibility to decay compared to red types: after 8 days of storage, the appearance score in mineral fertilized full-colored yellow peppers dramatically decreased below the limit of marketability. The results of this experiment show that the type of fertilization and maturity stage can have varying impact on the quality of yellow and red peppers

Comparison performance of visible-nir and near-infrared hyperspectral imaging for prediction of nutritional quality of goji berry (Lycium barbarum l.)

The potential of hyperspectral imaging for the prediction of the internal composition of goji berries was investigated. The prediction performances of models obtained in the Visible-Near Infrared (VIS-NIR) (400–1000 nm) and in the Near Infrared (NIR) (900–1700 nm) regions were compared. Analyzed constituents included Vitamin C, total antioxidant, phenols, anthocyanin, soluble solids content (SSC), and total acidity (TA). For vitamin C and AA, partial least square regression (PLSR) combined with different data pretreatments and wavelength selection resulted in a satisfactory prediction in the NIR region obtaining the R2pred value of 0.91. As for phenols, SSC, and TA, a better performance was obtained in the VIS-NIR region yielding the R2pred values of 0.62, 0.94, and 0.84, respectively. However, the prediction of total antioxidant and anthocyanin content did not give satisfactory results. Conclusively, hyperspectral imaging can be a useful tool for the prediction of the main constituents of the goji berry (Lycium barbarum L.)

Detection and enumeration of Listeria monocytogenes in fresh cut vegetables using MPN-Real-Time PCR

Listeria monocytogenes is a gram positive, rod shaped, pathogenic bacterium, causative agent of a severe infection generally known as listeriosis. Packaging and storage conditions of fresh cut vegetables may favour the growth of this psychrotrophic pathogen leading to potential health threat. Detection and enumeration of L. monocytogenes in concentrations up to 103 CFU/g, usually implies use of the most-probable-number technique (MPN) which may take up to seven days for verified identification of the pathogen. We developed a fast and reliable protocol combining MPN with a Real-Time quantitative PCR (qPCR) approach. Samples of fresh cut salads (25 g) purchased at local shops were spiked with 1 to 105 CFU/g of L. monocytogenes. Samples were homogenized, and triplicate series of tubes containing 10-5 to 10 g of food were incubated in Fraser broth at 30\ub0C for 48 h for standard MPN analysis. After incubation, broth samples were taken from each tube and DNA was extracted. DNA from enrichment tubes was used as template in a qPCR assay targeting a 64 bp hlyA gene sequence of L. monocytogenes. Results of this assay were than compared with those of standard MPN analysis and a complete accordance was observed. Furthermore, we tested an enrichment free approach using the same qPCR assay. Samples were prepared as described for MPN-qPCR while DNA extraction was performed prior to enrichment of inoculated salads. This approach allowed us to identify L. monocytogenes in samples spiked with 10-105 CFU/g. The whole process, including DNA extraction, required less than four hours, thus providing a fast and reliable tool for detection of L. monocytogenes in fresh cut vegetables

Hybrid topoisomerase i and HDAC inhibitors as dual action anticancer agents

Recent studies have shown that HDAC inhibitors act synergistically with camptothecin derivatives in combination therapies. To exploit this synergy, new hybrid molecules targeting simultaneously topoisomerase I and HDAC were designed. In particular, a selected multivalent agent containing a camptothecin and a SAHA-like template showed a broad spectrum of antiproliferative activity, with IC50 values in the nanomolar range. Preliminary in vivo results indicated a strong antitumor activity on human mesothelioma primary cell line MM473 orthotopically xenografted in CD-1 nude mice and very high tolerability