1,532 research outputs found
Effects of radiation forces upon the attitude of an artificial earth satellite
Solar radiation effects on attitude of satellit
Suppression of the commensurate spin-Peierls state in Sc-doped TiOCl
We have performed x-ray scattering measurements on single crystals of the
doped spin-Peierls compound Ti(1-x)Sc(x)OCl (x = 0, 0.01, 0.03). These
measurements reveal that the presence of non-magnetic dopants has a profound
effect on the unconventional spin-Peierls behavior of this system, even at
concentrations as low as 1%. Sc-doping suppresses commensurate fluctuations in
the pseudogap and incommensurate spin-Peierls phases of TiOCl, and prevents the
formation of a long-range ordered spin-Peierls state. Broad incommensurate
scattering develops in the doped compounds near Tc2 ~ 93 K, and persists down
to base temperature (~ 7 K) with no evidence of a lock-in transition. The width
of the incommensurate dimerization peaks indicates short correlation lengths on
the order of ~ 12 angstroms below Tc2. The intensity of the incommensurate
scattering is significantly reduced at higher Sc concentrations, indicating
that the size of the associated lattice displacement decreases rapidly as a
function of doping.Comment: 7 pages, 5 figure
Recommended from our members
Serving GODAE Data and Products to the Ocean Community
The Global Ocean Data Assimilation Experiment (GODAE [http://
www.godae.org]) has spanned a decade of rapid technological development. The ever-increasing volume and diversity of oceanographic data produced by in situ instruments, remote-sensing platforms, and computer simulations have driven
the development of a number of innovative technologies that are essential for connecting scientists with the data that they need. This paper gives an overview of the technologies that have been developed and applied in the course of GODAE, which now provide users of oceanographic data with the capability to discover, evaluate, visualize, download, and analyze data from all over the world. The key to this
capability is the ability to reduce the inherent complexity of oceanographic data by providing a consistent, harmonized view of the various data products. The challenges of data serving have been addressed over the last 10 years through the cooperative skills and energies of many individuals
Singlet-Triplet Excitations in the Unconventional Spin-Peierls System TiOBr
We have performed time-of-flight neutron scattering measurements on powder
samples of the unconventional spin-Peierls compound TiOBr using the
fine-resolution Fermi chopper spectrometer (SEQUOIA) at the SNS. These
measurements reveal two branches of magnetic excitations within the
commensurate and incommensurate spin-Peierls phases, which we associate with n
= 1 and n = 2 triplet excitations out of the singlet ground state. These
measurements represent the first direct measure of the singlet-triplet energy
gap in TiOBr, which is determined to be Eg = 21.2 +/- 1.0 meV.Comment: 5 pages, 4 figures, submitted for publicatio
Spin-Orbit Coupling in Iridium-Based 5d Compounds Probed by X-ray Absorption Spectroscopy
We have performed x-ray absorption spectroscopy (XAS) measurements on a
series of Ir-based 5d transition metal compounds, including Ir, IrCl3, IrO2,
Na2IrO3, Sr2IrO4, and Y2Ir2O7. By comparing the intensity of the "white-line"
features observed at the Ir L2 and L3 absorption edges, it is possible to
extract valuable information about the strength of the spin-orbit coupling in
these systems. We observe remarkably large, non-statistical branching ratios in
all Ir compounds studied, with little or no dependence on chemical composition,
crystal structure, or electronic state. This result confirms the presence of
strong spin-orbit coupling effects in novel iridates such as Sr2IrO4, Na2IrO3,
and Y2Ir2O7, and suggests that even simple Ir-based compounds such as IrO2 and
IrCl3 may warrant further study. In contrast, XAS measurements on Re-based 5d
compounds, such as Re, ReO2, ReO3, and Ba2FeReO6, reveal statistical branching
ratios and negligible spin-orbit coupling effects.Comment: 9 pages, 4 figure
Weak Interactions in Dimethyl Sulfoxide (DMSO)-Tertiary Amide Solutions: The Versatility of DMSO as a Solvent
The structures of equimolar mixtures of the commonly used polar aprotic solvents dimethylformamide (DMF) and dimethylacetamide (DMAc) in dimethyl sulfoxide (DMSO) have been investigated via neutron diffraction augmented by extensive hydrogen/deuterium isotopic substitution. Detailed 3-dimensional structural models of these solutions have been derived from the neutron data via Empirical Potential Structure Refinement (EPSR). The intermolecular center-of-mass (CoM) distributions show that the first coordination shell of the amides comprises ∼13-14 neighbors, of which approximately half are DMSO. In spite of this near ideal coordination shell mixing, the changes to the amide-amide structure are found to be relatively subtle when compared to the pure liquids. Analysis of specific intermolecular atom-atom correlations allows quantitative interpretation of the competition between weak interactions in the solution. We find a hierarchy of formic and methyl C-H···O hydrogen bonds forms the dominant local motifs, with peak positions in the range of 2.5-3.0 Å. We also observe a rich variety of steric and dispersion interactions, including those involving the O═C-N amide π-backbones. This detailed insight into the structural landscape of these important liquids demonstrates the versatility of DMSO as a solvent and the remarkable sensitivity of neutron diffraction, which is critical for understanding weak intermolecular interactions at the nanoscale and thereby tailoring solvent properties to specific applications
Asymptotic Behaviour of Inhomogeneous String Cosmologies
The asymptotic behaviour at late times of inhomogeneous axion-dilaton
cosmologies is investigated. The space-times considered here admit two abelian
space-like Killing vectors. These space-times evolve towards an anisotropic
universe containing gravitational radiation. Furthermore, a peeling-off
behaviour of the Weyl tensor and the antisymmetric tensor field strength is
found. The relation to the pre-big-bang scenario is briefly discussed.Comment: 15 pages, Late
Strong structuring arising from weak cooperative O-H···π and C-H···O hydrogen bonding in benzene-methanol solution
Weak hydrogen bonds, such as O-H···π and C-H···O, are thought to direct biochemical assembly, molecular recognition, and chemical selectivity but are seldom observed in solution. We have used neutron diffraction combined with H/D isotopic substitution to obtain a detailed spatial and orientational picture of the structure of benzene-methanol mixtures. Our analysis reveals that methanol fully solvates and surrounds each benzene molecule. The expected O-H···π interaction is highly localised and directional, with the methanol hydroxyl bond aligned normal to the aromatic plane and the hydrogen at a distance of 2.30 Å from the ring centroid. Simultaneously, the tendency of methanol to form chain and cyclic motifs in the bulk liquid is manifest in a highly templated solvation structure in the plane of the ring. The methanol molecules surround the benzene so that the O-H bonds are coplanar with the aromatic ring while the oxygens interact with C-H groups through simultaneous bifurcated hydrogen bonds. This demonstrates that weak hydrogen bonding can modulate existing stronger interactions to give rise to highly ordered cooperative structural motifs that persist in the liquid phase
Aquaporin-like water transport in nanoporous crystalline layered carbon nitride
Designing next-generation fuel cell and filtration devices requires the development of nanoporous materials that allow rapid and reversible uptake and directed transport of water molecules. Here, we combine neutron spectroscopy and first-principles calculations to demonstrate rapid transport of molecular H2O through nanometer-sized voids ordered within the layers of crystalline carbon nitride with a polytriazine imide structure. The transport mechanism involves a sequence of molecular orientation reversals directed by hydrogen-bonding interactions as the neutral molecules traverse the interlayer gap and pass through the intralayer voids that show similarities with the transport of water through transmembrane aquaporin channels in biological systems. The results suggest that nanoporous layered carbon nitrides can be useful for developing high-performance membranes
- …