Detailed analysis of transitions in the CO oxidation on Palladium(111) under noisy conditions

It has been shown that CO oxidation on Pd(111) under ultra-high vacuum conditions can suffer rare transitions between two stable states triggered by weak intrinsic perturbations. Here we study the effects of adding controlled noise by varying the concentrations of O2 and CO that feed the vacuum chamber, while the total flux stays constant. In addition to the regime of rare transitions between states of different CO2 reaction rate induced by intrinsic fluctuations, we found three distinct effects of external noise depending on its strength: small noise suppresses transitions and stabilizes the upper rate state; medium noise induces bursting; and large noise gives rise to reversible transitions in both directions. To explain some of the features present in the dynamics, we propose an extended stochastic model that includes a global coupling through the gas phase to account for the removal of CO gas caused by the adsorption of the Pd surface. The numerical simulations based in the model show a qualitative agreement with the noise-induced transitions found in experiments, but suggest that more complex spatial phenomena are present in the observed fluctuations

Ab-initio analysis of superstructures revealed by STM on bilayer graphene

In this work we performed density functional theory calculations for a twisted bilayer graphene (BLG). Several conmensurable rotation angles were analyzed and for each one a constant height mode STM image was obtained. These STM images, calculated under the Tersoff-Hamman theory, reproduce the main features experimentally observed, paticularly superstructures and giant corrugations. In this way we confirm that STM characterization of twisted BLG can produce superstructures whose tunneling current intensity maxima occur over regions with $AA$ stacking. Additionally we give new evidence in favour of an electronic origin for the superstructures instead another physical grounds

Normal and anomalous random walks of 2-d solitons

Solitons, which describe the propagation of concentrated beams of light through nonlinear media, can exhibit a variety of behaviors as a result of the intrinsic dissipation, diffraction, and the nonlinear effects. One of these phenomena, modeled by the complex Ginzburg-Landau equation, are chaotic explosions, transient enlargements of the soliton that may induce random transversal displacements, which in the long run lead to a random walk of the soliton center. As we show in this work, the transition from non-moving to moving solitons is not a simple bifurcation but includes a sequence of normal and anomalous random walks. We analyze their statistics with the distribution of generalized diffusivities, a novel approach that has been used successfully for characterizing anomalous diffusion.Comment: 10 pages, 5 figure

El pozo de Juan Carlos Onetti

Indexación: Revista UNA