27,418 research outputs found
Hadamard States and Two-dimensional Gravity
We have used a two-dimensional analog of the Hadamard state-condition to
study the local constraints on the two-point function of a linear quantum field
conformally coupled to a two-dimensional gravitational background. We develop a
dynamical model in which the determination of the state of the quantum field is
essentially related to the determination of a conformal frame. A particular
conformal frame is then introduced in which a two-dimensional gravitational
equation is established.Comment: 7 pages, no figur
Frequency Dependent Specific Heat from Thermal Effusion in Spherical Geometry
We present a novel method of measuring the frequency dependent specific heat
at the glass transition applied to 5-polyphenyl-4-ether. The method employs
thermal waves effusing radially out from the surface of a spherical thermistor
that acts as both a heat generator and thermometer. It is a merit of the method
compared to planar effusion methods that the influence of the mechanical
boundary conditions are analytically known. This implies that it is the
longitudinal rather than the isobaric specific heat that is measured. As
another merit the thermal conductivity and specific heat can be found
independently. The method has highest sensitivity at a frequency where the
thermal diffusion length is comparable to the radius of the heat generator.
This limits in practise the frequency range to 2-3 decades. An account of the
3omega-technique used including higher order terms in the temperature
dependency of the thermistor and in the power generated is furthermore given.Comment: 17 pages, 15 figures, Substantially revised versio
Hybrid RHF/MP2 geometry optimizations with the Effective Fragment Molecular Orbital Method
The frozen domain effective fragment molecular orbital method is extended to
allow for the treatment of a single fragment at the MP2 level of theory. The
approach is applied to the conversion of chorismate to prephenate by chorismate
mutase, where the substrate is treated at the MP2 level of theory while the
rest of the system is treated at the RHF level. MP2 geometry optimization is
found to lower the barrier by up to 3.5 kcal/mol compared to RHF optimzations
and ONIOM energy refinement and leads to a smoother convergence with respect to
the basis set for the reaction profile. For double zeta basis sets the increase
in CPU time relative to RHF is roughly a factor of two.Comment: 11 pages, 3 figure
The Top Triangle Moose
We introduce a deconstructed model that incorporates both Higgsless and
top-color mechanisms. The model alleviates the typical tension in Higgsless
models between obtaining the correct top quark mass and keeping delta-rho
small. It does so by singling out the top quark mass generation as arising from
a Yukawa coupling to an effective top-Higgs which develops a small vacuum
expectation value, while electroweak symmetry breaking results largely from a
Higgsless mechanism. As a result, the heavy partners of the SM fermions can be
light enough to be seen at the LHC.Comment: To appear in proceedings of SCGT09, Nagoya, Japan. 5 page
SPECS - an embedded platform, speech-driven environmental control system evaluated in a virtuous circle framework
Lattice vibrations and structural instability in Cesium near the cubic to tetragonal transition
Under pressure cesium undergoes a transition from a high-pressure fcc phase
(Cs-II) to a collapsed fcc phase (Cs-III) near 4.2GPa. At 4.4GPa there follows
a transition to the tetragonal Cs-IV phase. In order to investigate the lattice
vibrations in the fcc phase and seek a possible dynamical instability of the
lattice, the phonon spectra of fcc-Cs at volumes near the III-IV transition are
calculated using Savrasov's density functional linear-response LMTO method.
Compared with quasiharmonic model calculations including non-central
interatomic forces up to second neighbours, at the volume (
is the experimental volume of bcc-Cs with =6.048{\AA}), the
linear-response calculations show soft intermediate wavelength
phonons. Similar softening is also observed for
short wavelength and phonons and intermediate
wavelength phonons. The Born-von K\'{a}rm\'{a}n analysis of
dispersion curves indicates that the interplanar force constants exhibit
oscillating behaviours against plane spacing and the large softening of
intermediate wavelength phonons results from a
negative (110)-interplanar force-constant . The frequencies of the
phonons with around 1/3 become imaginary
and the fcc structure becomes dynamically unstable for volumes below .
It is suggested that superstructures corresponding to the
soft mode should be present as a precursor of tetragonal Cs-IV structure.Comment: 12 pages, 5 figure
Generation and detection of a sub-Poissonian atom number distribution in a one-dimensional optical lattice
We demonstrate preparation and detection of an atom number distribution in a
one-dimensional atomic lattice with the variance dB below the Poissonian
noise level. A mesoscopic ensemble containing a few thousand atoms is trapped
in the evanescent field of a nanofiber. The atom number is measured through
dual-color homodyne interferometry with a pW-power shot noise limited probe.
Strong coupling of the evanescent probe guided by the nanofiber allows for a
real-time measurement with a precision of atoms on an ensemble of some
atoms in a one-dimensional trap. The method is very well suited for
generating collective atomic entangled or spin-squeezed states via a quantum
non-demolition measurement as well as for tomography of exotic atomic states in
a one-dimensional lattice
Stochastics theory of log-periodic patterns
We introduce an analytical model based on birth-death clustering processes to
help understanding the empirical log-periodic corrections to power-law scaling
and the finite-time singularity as reported in several domains including
rupture, earthquakes, world population and financial systems. In our
stochastics theory log-periodicities are a consequence of transient clusters
induced by an entropy-like term that may reflect the amount of cooperative
information carried by the state of a large system of different species. The
clustering completion rates for the system are assumed to be given by a simple
linear death process. The singularity at t_{o} is derived in terms of
birth-death clustering coefficients.Comment: LaTeX, 1 ps figure - To appear J. Phys. A: Math & Ge
Application of processed organic municipal solid waste on agricultural land - a scenario analysis
Source separation, composting and anaerobic digestion, with associated land application, are increasingly being considered as alternative waste management strategies to landfilling and incineration of municipal solid waste (MSW). Environmental life cycle
assessments are a useful tool in political decision-making about waste management strategies. However, due to the diversity of processed organic MSW and the situations in which it can be applied, the environmental impacts of land application are very hard to determine by experimental means. In the current study, we used the agroecosystem model Daisy to simulate a range of different scenarios representing different geographical areas, farm and soil types under Danish conditions and legislation. Generally, the application of processed organic MSW resulted in increased emissions compared with the corresponding standard scenarios, but with large differences between scenarios.
Emission coefficients for nitrogen leaching to the groundwater ranged from 0.03 to 0.87, while those for nitrogen lost to surface waters through tile drains ranged from 0 to 0.30. Emission coefficients for N2O formation ranged from 0.013 to 0.022 and for ammonia
volatilization from 0.016 to 0.11. These estimates are within reasonable range of observed values under similar conditions. Furthermore, a sensitivity analysis showed that the estimates were not very sensitive to the mineralization dynamics of the processed organic MSW. The results show that agroecosystem models can be powerful tools to estimate the environmental impacts of land application of processed MSW under different conditions. Despite this, agroecosystem models have only been used to a very limited degree for this purpose
Interface of the polarizable continuum model of solvation with semi-empirical methods in the GAMESS program
An interface between semi-empirical methods and the polarized continuum model
(PCM) of solvation successfully implemented into GAMESS following the approach
by Chudinov et al (Chem. Phys. 1992, 160, 41). The interface includes energy
gradients and is parallelized. For large molecules such as ubiquitin a
reasonable speedup (up to a factor of six) is observed for up to 16 cores. The
SCF convergence is greatly improved by PCM for proteins compared to the gas
phase
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