Earth's middle age

This research was funded through Natural Environment Research Council (grant NE/J021822/1) and the APC was paid through the RCUK OA block grant.Earth's middle age, extending from 1.7 to 0.75 Ga, was characterized by environmental, evolutionary, and lithospheric stability that contrasts with the dramatic changes in preceding and succeeding eras. The period is marked by a paucity of preserved passive margins, an absence of a significant Sr anomaly in the paleoseawater record and in the εHf(t) in detrital zircon, a lack of orogenic gold and volcanic-hosted massive sulfide deposits, and an absence of glacial deposits and iron formations. In contrast, anorthosites and kindred bodies are well developed and major pulses of Mo and Cu mineralization, including the world's largest examples of these deposits, are features of this period. These trends are attributed to a relatively stable continental assemblage that was initiated during assembly of the Nuna supercontinent by ca. 1.7 Ga and continued until breakup of its closely related successor, Rodinia, ca. 0.75 Ga. The overall low abundance of passive margins is consistent with a stable continental configuration, which also provided a framework for environmental and evolutionary stability. A series of convergent margin accretionary orogens developed along the edge of the supercontinent. Abundant anorthosites and related rocks developed inboard of the plate margin. Their temporal distribution appears to link with the secular cooling of the mantle, at which time the overlying continental lithosphere was strong enough to be thickened and to support the emplacement of large plutons into the crust, yet the underlying mantle was still warm enough to result in widespread melting of the lower thickened crust.Publisher PDFPeer reviewe

Temporal relations between mineral deposits and global tectonic cycles

Natural Environment Research Council (grant NE/J021822/1) supported this research.Mineral deposits are heterogeneously distributed in both space and time, with variations reflecting tectonic setting, evolving environmental conditions, as in the atmosphere and hydrosphere, and secular changes in the Earth’s thermal history. The distribution of deposit types whose settings are tied to plate margin processes (e.g. orogenic gold, volcanic-hosted massive sulphide, Mississippi valley type Pb–Zn deposits) correlates well with the supercontinent cycle, whereas deposits related to intra-cratonic settings and mantle-driven igneous events, such as Ni–Cu–PGE deposits, lack a clear association. The episodic distribution of deposits tied to the supercontinent cycle is accentuated by selective preservation and biasing of rock units and events during supercontinent assembly, a process that encases the deposit within the assembled supercontinent and isolates it from subsequent removal and recycling at plate margins.Publisher PD

Using perovskite to determine the pre-shallow level contamination magma characteristics of kimberlite

It remains difficult to obtain reliable geochemical signatures of uncontaminated kimberlite magma from bulk rock studies due to the combined effects of crustal assimilation and element mobility during post-emplacement alteration processes. Groundmass perovskite (CaTiO3), a typical accessory phase, from Orapa (Botswana) and Wesselton (South Africa) kimberlites has been used to evaluate the isotope and trace element composition of the pre-contamination magmas and the effects of shallow level contamination. In-situ trace element signatures of Orapa and Wesselton perovskite grains are broadly similar and unaffected by crustal contamination. Single grain Sr-87/Sr-86 isotope ratios of perovskite from Orapa (0.7030-0.7036) are less scattered than bulk rock analyses (0.7063-0.7156), which are variably affected by contamination and late stage alteration. Initial Sr-87/Sr-86 isotope ratios of perovskite (0.7044-0.7049) from Wesselton overlap with published whole rock studies on fresh hypabyssal kimberlites (0.7042-0.7047). The limited intra-kimberlite variation in Sr isotope ratios recorded by the perovskite are unlikely to be due to crustal contamination as the calculated liquid compositions in equilibrium with the perovskite analysed typically have &gt;1500 ppmSr, and most common crustal lithologies underlying these kimberlites have relatively low Sr contents and are not highly radiogenic. Calculated pre-shallow level contamination magma compositions for Orapa and Wesselton have significantly fractionated LREE and highly variable non-smooth trace element patterns. Initial Sr and Nd isotope ratios of both kimberlites fall on the mantle Nd-Sr array with enriched Sr and slightly depleted Nd signatures, similar to Group I kimberlites. Overall, the trace element and isotopic composition of Orapa and Wesselton kimberlites are similar to the reported Group I kimberlites from southern Africa, which are derived by very low degrees of partial melting from a LREE depleted metasomatised sub-continental lithospheric mantle (SCLM) source. (C) 2013 Elsevier B.V. All rights reserved.</p

Tectonics and crustal evolution

We thank the Natural Environment Research Council (grants NE/J021822/1 and NE/K008862/1) for funding.The continental crust is the archive of Earth's history. Its rock units record events that are heterogeneous in time with distinctive peaks and troughs of ages for igneous crystallization, metamorphism, continental margins, and mineralization. This temporal distribution is argued largely to reflect the different preservation potential of rocks generated in different tectonic settings, rather than fundamental pulses of activity, and the peaks of ages are linked to the timing of supercontinent assembly. Isotopic and elemental data from zircons and whole rock crustal compositions suggest that the overall growth of continental crust (crustal addition from the mantle minus recycling of material to the mantle) has been continuous throughout Earth's history. A decrease in the rate of crustal growth ca. 3.0 Ga is related to increased recycling associated with the onset of plate tectonics. We recognize five stages of Earth's evolution: (1) initial accretion and differentiation of the core/mantle system within the first few tens of millions of years; (2) generation of crust in a pre-plate tectonic regime in the period prior to 3.0 Ga; (3) early plate tectonics involving hot subduction with shallow slab breakoff over the period from 3.0 to 1.7 Ga; (4) Earth's middle age from 1.7 to 0.75 Ga, characterized by environmental, evolutionary, and lithospheric stability; (5) modern cold subduction, which has existed for the past 0.75 b.y. Cycles of supercontinent formation and breakup have operated during the last three stages. This evolving tectonic character has likely been controlled by secular changes in mantle temperature and how that impacts on lithospheric behavior. Crustal volumes, reflecting the interplay of crust generation and recycling, increased until Earth's middle age, and they may have decreased in the past ∼1 b.y.Publisher PDFPeer reviewe

Continental materials on Earth by 4.5Ga from Hf-Pb isotope systematics of the Jack Hills zircons, Western Australia

[Extract] There is mounting radiogenic isotope evidence for wholesale differentiation of the terrestrial planets within the first few million years of accretion, as seen for example in the formation of feldspathic meteorite suits and samples from the moon and probably mars

Continental growth seen through the sedimentary record

This work was supported by the Natural Environment Research Council [NERC grant NE/K008862/1], the Leverhulme Trust [grant RPG-2015–422], and the Australian Research Council [grant FL160100168].Sedimentary rocks and detrital minerals sample large areas of the continental crust, and they are increasingly seen as a reliable archive for its global evolution. This study presents two approaches to model the growth of the continental crust through the sedimentary archive. The first builds on the variations in U-Pb, Hf and O isotopes in global databases of detrital zircons. We show that uncertainty in the Hf isotope composition of the mantle reservoir from which new crust separated, in the 176Lu/177Hf ratio of that new crust, and in the contribution in the databases of zircons that experienced ancient Pb loss(es), adds some uncertainty to the individual Hf model ages, but not to the overall shape of the calculated continental growth curves. The second approach is based on the variation of Nd isotopes in 645 worldwide fine-grained continental sedimentary rocks with different deposition ages, which requires a correction of the bias induced by preferential erosion of younger rocks through an erosion parameter referred to as K. This dimensionless parameter relates the proportions of younger to older source rocks in the sediment, to the proportions of younger to older source rocks present in the crust from which the sediment was derived. We suggest that a Hadean/Archaean value of K = 1 (i.e., no preferential erosion), and that post-Archaean values of K = 4–6, may be reasonable for the global Earth system. Models built on the detrital zircon and the fine-grained sediment records independently suggest that at least 65% of the present volume of continental crust was established by 3 Ga. The continental crust has been generated continuously, but with a marked decrease in the growth rate at ~ 3 Ga. The period from > 4 Ga to ~ 3 Ga is characterised by relatively high net rates of continental growth (2.9–3.4 km3 yr−1 on average), which are similar to the rates at which new crust is generated (and destroyed) at the present time. Net growth rates are much lower since 3 Ga (0.6–0.9 km3 yr−1 on average), which can be attributed to higher rates of destruction of continental crust. The change in slope in the continental growth curve at ~ 3 Ga is taken to indicate a global change in the way bulk crust was generated and preserved, and this change has been linked to the onset of subduction-driven plate tectonics. At least 100% of the present volume of the continental crust has been destroyed and recycled back into the mantle since ~ 3 Ga, and this time marks a transition in the average composition of new continental crust. Continental crust generated before 3 Ga was on average mafic, dense, relatively thin (< 20 km) and therefore different from the calc-alkaline andesitic crust that dominates the continental record today. Continental crust that formed after 3 Ga gradually became more intermediate in composition, buoyant and thicker. The increase in crustal thickness is accompanied by increasing rates of crustal reworking and increasing input of sediment to the ocean. These changes may have been accommodated by a change in lithospheric strength at around 3 Ga, as it became strong enough to support high-relief crust. This time period therefore indicates when significant volumes of continental crust started to become emergent and were available for erosion and weathering, thus impacting on the composition of the atmosphere and the oceans.PostprintPeer reviewe

Re-partitioning of Cu and Zn isotopes by modified protein expression

Cu and Zn have naturally occurring non radioactive isotopes, and their isotopic systematics in a biological context are poorly understood. In this study we used double focussing mass spectroscopy to determine the ratios for these isotopes for the first time in mouse brain. The Cu and Zn isotope ratios for four strains of wild-type mice showed no significant difference (δ65Cu -0.12 to -0.78 permil; δ66Zn -0.23 to -0.48 permil). We also looked at how altering the expression of a single copper binding protein, the prion protein (PrP), alters the isotope ratios. Both knockout and overexpression of PrP had no significant effect on the ratio of Cu isotopes. Mice brains expressing mutant PrP lacking the known metal binding domain have δ65Cu isotope values of on average 0.57 permil higher than wild-type mouse brains. This implies that loss of the copper binding domain of PrP increases the level of 65Cu in the brain. δ66Zn isotope values of the transgenic mouse brains are enriched for 66Zn to the wild-type mouse brains. Here we show for the first time that the expression of a single protein can alter the partitioning of metal isotopes in mouse brains. The results imply that the expression of the prion protein can alter cellular Cu isotope content

Continental crustal volume, thickness and area, and their geodynamic implications

We appreciate support from Australian Research Council grant FL160100168 and Leverhulme Trust grants RPG-2015-422 and EM-2017-047\4.Models of the volume of continental crust through Earth history vary significantly due to a range of assumptions and data sets; estimates for 3 Ga range from 120% of present day volume. We argue that continental area and thickness varied independently and increased at different rates and over different periods, in response to different tectonic processes, through Earth history. Crustal area increased steadily on a pre-plate tectonic Earth, prior to ca. 3 Ga. By 3 Ga the area of continental crust appears to have reached a dynamic equilibrium of around 40% of the Earth's surface, and this was maintained in the plate tectonic world throughout the last 3 billion years. New continental crust was relatively thin and mafic from ca. 4–3 Ga but started to increase substantially with the inferred onset of plate tectonics at ca. 3 Ga, which also led to the sustained development of Earth's bimodal hypsometry. Integration of thickness and area data suggests continental volume increased from 4.5 Ga to 1.8 Ga, and that it remained relatively constant through Earth's middle age (1.8–0.8 Ga). Since the Neoproterozoic, the estimated crustal thickness, and by implication the volume of the continental crust, appears to have decreased by as much as 15%. This decrease indicates that crust was destroyed more rapidly than it was generated. This is perhaps associated with the commencement of cold subduction, represented by low dT/dP metamorphic assemblages, resulting in higher rates of destruction of the continental crust through increased sediment subduction and subduction erosion.PostprintPeer reviewe

Rates of generation and growth of the continental crust

Models for when and how the continental crust was formed are constrained by estimates in the rates of crustal growth. The record of events preserved in the continental crust is heterogeneous in time with distinctive peaks and troughs of ages for igneous crystallisation, metamorphism, continental margins and mineralisation. For the most part these are global signatures, and the peaks of ages tend to be associated with periods of increased reworking of pre-existing crust, reflected in the Hf isotope ratios of zircons and their elevated oxygen isotope ratios. Increased crustal reworking is attributed to periods of crustal thickening associated with compressional tectonics and the development of supercontinents. Magma types similar to those from recent within-plate and subduction related settings appear to have been generated in different areas at broadly similar times before ∼3.0 Ga. It can be difficult to put the results of such detailed case studies into a more global context, but one approach is to consider when plate tectonics became the dominant mechanism involved in the generation of juvenile continental crust. The development of crustal growth models for the continental crust are discussed, and a number of models based on different data sets indicate that 65%–70% of the present volume of the continental crust was generated by 3 Ga. Such estimates may represent minimum values, but since ∼3 Ga there has been a reduction in the rates of growth of the continental crust. This reduction is linked to an increase in the rates at which continental crust is recycled back into the mantle, and not to a reduction in the rates at which continental crust was generated. Plate tectonics results in both the generation of new crust and its destruction along destructive plate margins. Thus, the reduction in the rate of continental crustal growth at ∼3 Ga is taken to reflect the period in which plate tectonics became the dominant mechanism by which new continental crust was generated.</p