7,563 research outputs found

    Organic Applications Of Carbon-13 And Deuterium Nmr Spectroscopy

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    The Sender-Excited Secret Key Agreement Model: Capacity, Reliability and Secrecy Exponents

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    We consider the secret key generation problem when sources are randomly excited by the sender and there is a noiseless public discussion channel. Our setting is thus similar to recent works on channels with action-dependent states where the channel state may be influenced by some of the parties involved. We derive single-letter expressions for the secret key capacity through a type of source emulation analysis. We also derive lower bounds on the achievable reliability and secrecy exponents, i.e., the exponential rates of decay of the probability of decoding error and of the information leakage. These exponents allow us to determine a set of strongly-achievable secret key rates. For degraded eavesdroppers the maximum strongly-achievable rate equals the secret key capacity; our exponents can also be specialized to previously known results. In deriving our strong achievability results we introduce a coding scheme that combines wiretap coding (to excite the channel) and key extraction (to distill keys from residual randomness). The secret key capacity is naturally seen to be a combination of both source- and channel-type randomness. Through examples we illustrate a fundamental interplay between the portion of the secret key rate due to each type of randomness. We also illustrate inherent tradeoffs between the achievable reliability and secrecy exponents. Our new scheme also naturally accommodates rate limits on the public discussion. We show that under rate constraints we are able to achieve larger rates than those that can be attained through a pure source emulation strategy.Comment: 18 pages, 8 figures; Submitted to the IEEE Transactions on Information Theory; Revised in Oct 201

    As Low Birth Weight Babies Grow, Can 'Good' Parents Buffer this Adverse Factor? A Research Note.

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    This research note combines two national Taiwanese datasets to investigate the relationship between low birth weight (LBW) babies, their family background and their future academic outcomes. We find that LBW is negatively correlated with the probability of such children attending university at the age of 18; however, when both parents are college or senior high school graduates, such negative effects may be partially offset. We also show that discrimination against daughters does occur, but only in those cases where the daughters were LBW babies. Moreover, high parental education (HPE) can only buffer the LBW shock among moderately-LBW children (as compared to very-LBW children) and full term-LBW children (as compared to preterm-LBW children).

    Statistical Estimation of Combinational and Sequential CMOS Digital Circuit Activity Considering Uncertainty of Gate Delay Models

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    While estimating glitches or spurious transitions is challenge due to signal correlations, the random behavior of logic gate delays makes the estimation problem even more clifficult. In this paper, we present statistical estimation of signal activity at the internal and output nodes of combini3tional and sequential CMOS logic circuits considering uncertainty of gate delay models. The methodology is based on the stochastic models of logic signals and the probabilistic behavior of gate delays due to process variations, interconnect parmitics, etc. We propose a statistical technique of estimating average-case activity, which is flexible in adopting different delay models and variations and can be integrated with worst-case analysis into statistical logic design process. Experimental results show that the uncertainty of gate delay makes a great impact on activity at individual nodes (more than 100%) and total power dissipation as well

    Parental Education and Child Health: Evidence from a Natural Experiment in Taiwan

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    This paper exploits a natural experiment to estimate the causal impact of parental education on child health in Taiwan. In 1968, the Taiwanese government extended compulsory education from six to nine years. From that year through 1973, the government opened 254 new junior high schools, an 80 percent increase, at a differential rate among regions. We form treatment and control groups of women or men who were age 12 or under on the one hand and between the ages of 13 and 20 or 25 on the other hand in 1968. Within each region, we exploit variations across cohorts in new junior high school openings to construct an instrument for schooling. We employ this instrument to estimate the causal effects of mother's or father's schooling on the incidence of low birthweight and mortality of infants born to women in the treatment and control groups or the wives of men in these groups in the period from 1978 through 1999. Parents' schooling, especially mother's schooling, does indeed cause favorable infant health outcomes. The increase in schooling associated with the reform saved almost 1 infant life in 1,000 live births, resulting in a decline in infant mortality of approximately 11 percent.

    Rootstock and seasonal variations affect anthocyanin accumulation and quality traits of ‘Kyoho’ grape berries in subtropical double cropping system

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    The double cropping system has been commercially adopted in subtropical viticulture regions. However, very limited information about rootstock and seasonal effects on berry quality traits are available for this unique production system. Developing ‘Kyoho’ berries from own-rooted vines and from vines on 5C and 1202C rootstocks were periodically sampled from veraison until harvest in two consecutive cropping cycles to document the potential seasonal influence on rootstock effects. Anthocyanin concentration in berry skin, total soluble solids content (TSS), and titratable acidity (TA) were analyzed. In both cropping cycles, own-rooted vines produced berries with the highest anthocyanin concentration while vines on 1202C produced berries with the lowest anthocyanin concentration among the three scion/rootstocks. Anthocyanin concentrations were not differentiated by the differential climate pattern between the summer and the winter cropping cycles. Berries of own-rooted ‘Kyoho’ and ‘Kyoho’/5C vines accumulated satisfactory and equal amount of TSS in both cropping cycles. 1202C rootstocks did not affect berry TSS in the summer cropping cycle but reduced TSS in the winter cropping cycle. Significant rootstock and seasonal effects on berry TA were detected. Own-rooted vines produced berries with the lowest TA while vines on 1202C produced berries with the highest TA among the three scion/rootstock combinations. TA of berries from the winter cropping cycle was significantly higher than that from the summer cropping cycle especially in ‘Kyoho’/1202C. Relationships between anthocyanins and TSS of developing berries after veraison properly fitted into a sigmoidal function regardless of rootstocks and cropping cycles. However, the duration of the initial lag phase, the onset and the trend of both quality triats in the increasing phase, and the presence and degree of the final lag phase in the relationship were all modulated by rootstocks and by seasonal variations.

    Influence of Annealing on Properties of Spray Deposited ZnO Thin Films

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    Zinc Oxide (ZnO) thin films were deposited on glass substrates via the spray pyrolysis technique. The films were subsequently annealed in ambient air from 300°C to 500°C. The morphology and structural properties of the thin films were studied by field emission scanning electron microscope (FESEM), atomic force microscopy (AFM), and X-ray diffractometry (XRD) techniques. Electrical resistivity of the thin films was measured using a data acquisition unit. The optical properties of the films were characterized by UV-vis spectroscopy and photoluminescence (PL) technique. X-ray diffraction data showed that the films were grown in the (002) direction with a hexagonal wurtzite structure. The average grain size ranged from 15 to 27 nm. Increasing annealing temperatures resulted in larger grain sizes and higher crystallinity, with the surface roughness of annealed films being more than twice if compared to unannealed film. The electrical resistivity of the films decreased with the increasing annealing temperature. The UV and visible band emissions were observed in the photoluminescence spectra, due to exciton and defect-related emissions, respectively. The transmission values of the films were as high as 90% within the visible range (400–700 nm)

    Consolidation of calcium phosphate powder through microwave sintering / Natasha Ahmad Nawawi, Ramesh Singh and Tan Chou Yong

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    In the last 50 years, the major drawback of HA ceramic usage in clinical applications is its inherent brittleness and lower mechanical strength than those of cortical bone. This is turn calls for the development of dense nanostructured HA with the major concern is to enhance densification while limiting its grain growth. Hence, a promising way to obtain this could be a fabrication of fully dense nanostructured materials through sintering process. In this work, eggshell derived hydroxyapatite (HA-Es) powder has been prepared via solid state sintering and its sinterability was investigated through microwave sintering at various sintering temperatures (950-1250 °C). The phase stability, microstructural evolution and relative density of HA-Es were deliberated. The results indicate that microwave sintering regime has been successfully employed and this short sintering regime did not promote extensive grain growth even when sintered at high temperature

    A Tree-based Federated Learning Approach for Personalized Treatment Effect Estimation from Heterogeneous Data Sources

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    Federated learning is an appealing framework for analyzing sensitive data from distributed health data networks due to its protection of data privacy. Under this framework, data partners at local sites collaboratively build an analytical model under the orchestration of a coordinating site, while keeping the data decentralized. However, existing federated learning methods mainly assume data across sites are homogeneous samples of the global population, hence failing to properly account for the extra variability across sites in estimation and inference. Drawing on a multi-hospital electronic health records network, we develop an efficient and interpretable tree-based ensemble of personalized treatment effect estimators to join results across hospital sites, while actively modeling for the heterogeneity in data sources through site partitioning. The efficiency of our method is demonstrated by a study of causal effects of oxygen saturation on hospital mortality and backed up by comprehensive numerical results
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