1,143 research outputs found
Enhanced reverse saturable absorption and optical limiting in heavy-atom-substituted phthalocyanines
The reverse saturable absorption and the optical-limiting response of metal phthalocyanines can be enhanced by use of the heavy-atom effect. Phthalocyanines containing heavy-metal atoms, such as In, Sn, and Pb, show a nearly factor-of-2 enhancement in the ratio of effective excited-state to ground-state absorption cross sections compared with those containing lighter atoms, such as Al and Si. In an f/8 optical geometry, homogeneous solutions of heavy-metal phthalocyanines, at 30% linear transmission, limit 8-ns 532-nm laser pulses to ≤ 3 µJ the energy for 50% probability of eye damage) for incident energies as high as 800 µJ
Removal of Chromium (III) from Aqueous Solution by Coconut Husk and Rice Straw
Coconut husk fibre and rice straw were found to be able to remove significant amount of Cr (III) ions from aqueous solutions. Its removal is a function of pH
and concentration. The optimum pH range for maximum uptake is between 4 and 6 for both substrates. The adsorption capacity was found to be 0.55 and
0.30 millimole Cr (III) / g substrate for coconut husk and rice straw respectively. The adsorption kinetic studies show that the removal process follows a first order rate expression. The breakthrough curves and adsorption efficiency of various columns containing mixed media of coconut husk/rice straw, soil and sand have been obtained. The results demonstrate that these agricultural
residues could be used as barriers in a landfill to maximize immobilization of toxic metal ions such as Cr (III) in leachates
Bioinformatics for Membrane Lipid Simulations: Models, Computational Methods, and Web Server Tools
Biological membranes are complex environments consisting of different types of lipids and membrane proteins. The structure of a lipid bilayer is typically difficult to study because the membrane liquid crystalline state is made up of multiple disordered lipid molecules. This complicates the description of the lipid membrane properties by the conformation of any single lipid molecule. Molecular dynamics (MD) simulations have been used extensively to investigate properties of membrane lipids, lipid vesicles, and membrane protein systems. All-atom membrane models can elucidate detailed contacts between membrane proteins and its surrounding lipids, while united-atom and coarse-grained description have allowed larger models and longer timescales up to microsecond mark to be probed. Additionally, membrane models with mixed phospholipids and lipopolysaccharide content have made it possible to model improved views of biological membranes. Here, we present an overview of commonly used lipid force fields by the biosimulation community, useful tools for membrane MD simulations, and recent advances in membrane simulations
Microscopic Theory of Rashba Interaction in Magnetic Metal
Theory of Rashba spin-orbit coupling in magnetic metals is worked out from
microscopic Hamiltonian describing d-orbitals. When structural inversion
symmetry is broken, electron hopping between -orbitals generates chiral
ordering of orbital angular momentum, which combines with atomic spin-orbit
coupling to result in the Rashba interaction. Rashba parameter characterizing
the interaction is band-specific, even reversing its sign from band to band.
Large enhancement of the Rashba parameter found in recent experiments is
attributed to the orbital mixing of 3d magnetic atoms with non-magnetic heavy
elements as we demonstrate by first-principles and tight-binding calculations.Comment: 5 pages, 2 figure
Immunogenicity of a truncated enterovirus 71 VP1 protein fused to a Newcastle disease virus nucleocapsid protein fragment in mice.
Enterovirus 71 (EV71) is one of the viruses that cause hand, foot and mouth disease. Its viral capsid protein 1 (VP1), which contains many neutralization epitopes, is an ideal target for vaccine development. Recently, we reported the induction of a strong immune response in rabbits to a truncated VP1 fragment (Nt-VP1t) displayed on a recombinant Newcastle disease virus (NDV) capsid protein. Protective efficacy of this vaccine, however, can only be tested in mice, since all EV71 animal models thus far were developed in mouse systems. In this study, we evaluated the type of immune responses against the protein developed by adult BALB/c mice. Nt-VP1t protein induced high levels of VP1 IgG antibody production in mice. Purified VP1 antigen stimulated activation, proliferation and differentiation of splenocytes harvested from these mice. They also produced significant levels of IFN-γ, a Th1-related cytokine. Taken together, Nt-VP1t protein is a potent immunogen in adult mice and our findings provide the data needed for testing of its protective efficacy in mouse models of EV71 infections
The Full Range of Predictions for B Physics From Iso-singlet Down Quark Mixing
We extend the range of predictions of the isosinglet (or vector) down quark
model to the fully allowed physical ranges, and also update this with the
effect of new physics constraints. We constrain the present allowed ranges of
sin(2*beta) and sin(2*alpha), gamma, x_s, and A_{B_s}. In models allowing
mixing to a new isosinglet down quark (as in E_6) flavor changing neutral
currents are induced that allow a Z^0 mediated contribution to B-Bbar mixing
and which bring in new phases. In (rho, eta), (x_s, sin(gamma)), and (x_s,
A_{B_s}) plots for the extra isosinglet down quark model which are herein
extended to the full physical range, we find new allowed regions that will
require experiments on sin(gamma) and/or x_s to verify or to rule out an extra
down quark contribution.Comment: 13 pages in RevTeX, 7 postscript figure
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