6,029 research outputs found
Mode-coupling theory for structural and conformational dynamics of polymer melts
A mode-coupling theory for dense polymeric systems is developed which
unifyingly incorporates the segmental cage effect relevant for structural
slowing down and polymer chain conformational degrees of freedom. An ideal
glass transition of polymer melts is predicted which becomes molecular-weight
independent for large molecules. The theory provides a microscopic
justification for the use of the Rouse theory in polymer melts, and the results
for Rouse-mode correlators and mean-squared displacements are in good agreement
with computer simulation results.Comment: 4 pages, 3 figures, Phys. Rev. Lett. in pres
Structural relaxation in a system of dumbbell molecules
The interaction-site-density-fluctuation correlators, the dipole-relaxation
functions, and the mean-squared displacements of a system of symmetric
dumbbells of fused hard spheres are calculated for two representative
elongations of the molecules within the mode-coupling theory for the evolution
of glassy dynamics. For large elongations, universal relaxation laws for states
near the glass transition are valid for parameters and time intervals similar
to the ones found for the hard-sphere system. Rotation-translation coupling
leads to an enlarged crossover interval for the mean-squared displacement of
the constituent atoms between the end of the von Schweidler regime and the
beginning of the diffusion process. For small elongations, the superposition
principle for the reorientational -process is violated for parameters
and time intervals of interest for data analysis, and there is a strong
breaking of the coupling of the -relaxation scale for the diffusion
process with that for representative density fluctuations and for dipole
reorientations.Comment: 15 pages, 14 figures, Phys. Rev. E in pres
A mode-coupling theory for the glassy dynamics of a diatomic probe molecule immersed in a simple liquid
Generalizing the mode-coupling theory for ideal liquid-glass transitions,
equations of motion are derived for the correlation functions describing the
glassy dynamics of a diatomic probe molecule immersed in a simple glass-forming
system. The molecule is described in the interaction-site representation and
the equations are solved for a dumbbell molecule consisting of two fused hard
spheres in a hard-sphere system. The results for the molecule's arrested
position in the glass state and the reorientational correlators for
angular-momentum index and near the glass transition are
compared with those obtained previously within a theory based on a
tensor-density description of the molecule in order to demonstrate that the two
approaches yield equivalent results. For strongly hindered reorientational
motion, the dipole-relaxation spectra for the -process can be mapped on
the dielectric-loss spectra of glycerol if a rescaling is performed according
to a suggestion by Dixon et al. [Phys. Rev. Lett. {\bf 65}, 1108 (1990)]. It is
demonstrated that the glassy dynamics is independent of the molecule's inertia
parameters.Comment: 19 pages, 10 figures, Phys. Rev. E, in prin
ROSAT HRI Observations of the Crab Pulsar: An Improved Temperature upper limit for PSR 0531+21
ROSAT HRI observations have been used to determine an upper limit of the Crab
pulsar surface temperature from the off-pulse count rate. For a neutron star
mass of 1.4 \Mo and a radius of 10 km as well as the standard distance and
interstellar column density, the redshifted temperature upper limit is\/
K . This is the lowest temperature
upper limit obtained for the Crab pulsar so far. Slightly different values for
are computed for the various neutron star models available in the
literature, reflecting the difference in the equation of state.Comment: 5 pages, uuencoded postscript, to be published in the Proceedings of
the NATO Advanced Study Insitute on "Lives of the Neutron Stars", ed. A.
Alpar, U. Kiziloglu and J. van Paradijs ( Kluwer, Dordrecht, 1995 )
Influence of link spacing on concrete shear capacity:Experimental investigations and finite element studies
The mean-squared displacement of a molecule moving in a glassy system
The mean-squared displacement (MSD) of a hard sphere and of a dumbbell
molecule consisting of two fused hard spheres immersed in a dense hard-sphere
system is calculated within the mode-coupling theory for ideal liquid-glass
transitions. It is proven that the velocity correlator, which is the second
time derivative of the MSD, is the negative of a completely monotone function
for times within the structural-relaxation regime. The MSD is found to exhibit
a large time interval for structural relaxation prior to the onset of the
-process which cannot be described by the asymptotic formulas for the
mode-coupling-theory-bifurcation dynamics. The -process for molecules
with a large elongation is shown to exhibit an anomalously wide cross-over
interval between the end of the von-Schweidler decay and the beginning of
normal diffusion. The diffusivity of the molecule is predicted to vary
non-monotonically as function of its elongation.Comment: 18 pages, 12 figures, Phys. Rev. E, in prin
Photon-induced production of the mirror quarks from the model at the
The photon-induced processes at the provide clean experimental
conditions due to absence of the proton remnants, which might produce
complementary and interesting results for tests of the standard model and for
searching of new physics. In the context of the littlest model with
T-parity, we consider the photon-induced production of the mirror quarks at the
. The cross sections for various production channels are calculated and a
simply phenomenology analysis is performed by assuming leptonic decays.Comment: 20 pages, 10 figure
Gaussian density fluctuations and Mode Coupling Theory for supercooled liquids
The equations of motion for the density modes of a fluid, derived from
Newton's equations, are written as a linear generalized Langevin equation. The
constraint imposed by the fluctuation-dissipation theorem is used to derive an
exact form for the memory function. The resulting equations, solved under the
assumption that the noise, and consequently density fluctuations, of the liquid
are gaussian distributed, are equivalent to the random-phase-approximation for
the static structure factor and to the well known ideal mode coupling theory
(MCT) equations for the dynamics. This finding suggests that MCT is the
canonical mean-field theory of the fluid dynamics.Comment: 4 pages, REVTE
E2F1 Orchestrates Transcriptomics and Oxidative Metabolism in Wharton's Jelly-Derived Mesenchymal Stem Cells from Growth-Restricted Infants
10.1371/journal.pone.0163035PloS one119e0163035GUSTO (Growing up towards Healthy Outcomes
Time series aggregation, disaggregation and long memory
We study the aggregation/disaggregation problem of random parameter AR(1)
processes and its relation to the long memory phenomenon. We give a
characterization of a subclass of aggregated processes which can be obtained
from simpler, "elementary", cases. In particular cases of the mixture
densities, the structure (moving average representation) of the aggregated
process is investigated
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